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化学进展 2014, Vol. 26 Issue (09): 1570-1585 DOI: 10.7536/PC140420 前一篇   后一篇

• 综述与评论 •

原子尺度研究固体氧化物池氧电极中氧迁移规律

刘少名1,2, 于波*2, 张文强2, 朱建新3, 翟玉春1, 陈靖2   

  1. 1. 东北大学材料与冶金学院 沈阳 110819;
    2. 清华大学核能与新能源技术研究院 北京 100084;
    3. 中国科学院生态环境研究中心 北京 100085
  • 收稿日期:2014-04-01 修回日期:2014-06-01 出版日期:2014-09-15 发布日期:2014-07-09
  • 通讯作者: 于波 E-mail:cassy_yu@tsinghua.edu.cn
  • 基金资助:

    “清华大学-剑桥大学-麻省理工学院”低碳能源大学联盟种子基金项目（No.2011LC004），国家科技重大专项 （No. ZX06901），国家自然科学基金项目 （No. 21273128，51202123）和教育部长江学者和创新团队发展计划（No. IRT13026）资助

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Atomic-Scale Insights into the Oxygen Ionic Transport Mechanisms of Oxygen Electrode in Solid Oxide Cells：A Review

Liu Shaoming1,2, Yu Bo*2, Zhang Wenqiang2, Zhu Jianxin3, Zhai Yuchun1, Chen Jing2   

  1. 1. School of Materials and Metallurgy, Northeastern University, Shenyang 110819, China;
    2. Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084, China;
    3. Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China
  • Received:2014-04-01 Revised:2014-06-01 Online:2014-09-15 Published:2014-07-09
  • Supported by:

    The work was supported by the“Tsinghua-MIT-Cambridge” Low Carbon Energy University Alliance Seed Fund Program (No.2011LC004), the National Science and Technology Major Project of the Ministry of Science and Technology of China (No. ZX06901), the National Natural Science Foundation of China (No. 21273128, 51202123) and the Program for Changjiang Scholars and Innovative Research Team in University (No. IRT13026)

固体氧化物燃料电池（SOFC）和固体氧化物燃料电解池（SOEC）作为新一代的能源转化装置，凭借其清洁、高效的能源转化优势，非常具有技术吸引力。为了将SOFC和SOEC商业化，操作更加持久、高效和经济，中低温的运行温度成为当前国际上研究的主要方向，其中提高氧电极材料的氧还原反应/氧析出反应（ORR/OER）活性是研究的关键。本文主要阐述了原子尺度分子模拟分析和原位实验测试表征对混合离子电子导体氧电极材料中氧迁移规律和传输机理研究的重要作用，推进传统材料向新型氧电极材料和结构的发展；归纳和综述了近期热点的混合离子电子导体（MIEC）氧电极材料、相应的离子传输路径、各向异性结构及晶格动力学；介绍了当前采用的先进研究手段和方法，并重点介绍了原位X射线光电子能谱（XPS）和俄歇电子光谱（AES）探测材料的表面化学组成和结构，原位的方式可以将致密薄膜中几纳米到十几纳米的结构可视化，在原子层面上研究氧电极材料中带电缺陷的形成和迁移；并基于原子尺度的密度泛函理论（DFT）计算和近期分子动力学模拟（MD）的研究进展对传统材料和新型材料中的氧迁移机理进行解释和分析。最后，简要综述了清华大学核研院在固体氧化物池氧电极方面的研究进展。

关键词： 固体氧化物燃料电池, 固体氧化物燃料电解池, 中低温, 氧电极, 密度泛函理论, 分子动力学

As a new generation of energy conversion devices, solid oxide fuel cells (SOFC) and solid oxide electrolysis cells (SOEC) are of great importance with the advantage of highly efficient energy conversion in a clean way. For the commercialization of SOFC and SOEC technologies, operation at the intermediate-low temperature (IT) is the current major research direction all over the world, which are beneficial for the operation of SOFC and SOEC more durably and economically. The key point is how to improve the oxygen reduction reaction (ORR) or oxygen evolution reaction (OER) activity of oxygen electrodes. In this review, the important roles of atomic-scale molecular simulation and in-situ experimental characterization are mainly illustrated to provide insight and understanding on the oxygen transport mechanism analysis. These fundamental studies could put forward the progress from traditional materials and structures to novel designs and concepts. The recent R&D oxygen electrodes of mixed ionic electronic conducting (MIEC) materials, the corresponding ion migration paths, anisotropic structures and lattice dynamics are summarized in detail. The current advanced research methods and characterizations are introduced focusing on the in-situ X-ray photoelectron spectroscopy (XPS) and Auger electron spectroscopy (AES) for probing the surface chemical composition and structure of materials. With in-situ methods, a several nanometers to tens of nanometers structure of the dense film could be visualized that made the study of the formation and migration of charged defects of oxygen electrode material feasible. Oxygen transport mechanisms in the traditional materials and novel materials at atomic scale are analyzed by the results of density functional theory (DFT) calculations and molecular dynamics (MD) simulations. Furthermore, the research progress of oxygen electrodes at INET in Tsinghua University is briefly introduced.

Contents
1 Introduction
2 Oxygen electrode materials
2.1 Mixed ionic electronic conductor (MIEC) oxygen electrode
2.2 Perovskite oxides
2.3 Ruddlesden-popper series of layered oxides
2.4 Layered double perovskites oxides
3 The current research methods
3.1 Pulsed laser deposition (PLD)
3.2 Thin film characterization
3.3 Computational methods
4 Oxygen transport mechanisms in oxygen electrode
4.1 Oxygen bulk diffusion in oxygen electrode
4.2 Oxygen surface exchange in oxygen electrode
5 The research progress of INET in Tsinghua University on the oxygen electrode of the solid oxide cells
6 Conclusions

Key words: solid oxide fuel cell(SOFC), solid oxide electrolysis cell(SOEC), intermediate-low temperature, oxygen electrode, density functional theory(DFT), molecular dynamics(MD)

中图分类号: 

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