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化学进展 2014, Vol. 26 Issue (09): 1562-1569 DOI: 10.7536/PC140347 前一篇   后一篇

所属专题： 电化学有机合成

• 综述与评论 •

碳纳米管/石墨烯复合结构及其电化学电容行为

康怡然1,2, 蔡锋2,3, 陈宏源2, 陈名海*2, 张锐1,4, 李清文2   

  1. 1. 郑州大学材料科学与工程学院 郑州 450001;
    2. 中国科学院苏州纳米技术与纳米仿生研究所 苏州 215123;
    3. 中国科学技术大学纳米科学技术学院 苏州 215123;
    4. 郑州航空工业管理学院 郑州 450046
  • 收稿日期:2014-03-01 修回日期:2014-05-01 出版日期:2014-09-15 发布日期:2014-07-09
  • 通讯作者: 陈名海 E-mail:mhchen2008@sinano.ac.cn
  • 基金资助:

    国家自然科学基金项目（No. 21203238）资助

下载PDF ( 2590 ) 引用
导出 被引次数 ( 3 | 4 )

Carbon Nanotube/Graphene Hybrid Nanostructures and Their Application in Supercapacitors

Kang Yiran1,2, Cai Feng2,3, Chen Hongyuan2, Chen Minghai*2, Zhang Rui1,4, Li Qingwen2   

  1. 1. School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, China;
    2. Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences, Suzhou 215123;
    3. School of Nano Science and Technology, University of Science and Technology of China, Suzhou, 215123, China;
    4. Zhengzhou Institute of Aeronautical Industry Management, Zhengzhou 450046, China
  • Received:2014-03-01 Revised:2014-05-01 Online:2014-09-15 Published:2014-07-09
  • Supported by:

    The work was supported by the National Natural Science Foundation of China (No. 21203238)

本文综述了超级电容器电极材料碳纳米管/石墨烯复合结构的制备方法，以及由该结构和赝电容活性物质形成的三元复合体系的电化学电容行为研究进展，并提出合理设计的碳纳米管和石墨烯复合结构可以有效发挥其高电导率、高比表面积和合理孔隙结构的优势，实现活性物质的高密度负载，从而获得具有高容量、良好倍率特性和长寿命的电化学超级电容器电极材料。

关键词： 碳纳米管, 石墨烯, 复合材料, 超级电容器

In this paper, we review the preparation methods of carbon nanotube (CNT)/graphene composite materials for the electrode of supercapacitors, and introduce the developments of CNT/graphene/pseudo-capacitive material ternary composite materials with highly electrochemical performance. The rational designed CNT/graphene composite nanostructures could largely utilize the characteristics of carbon nanomaterials for electrochemical double-large supercapacitors, such as large specific area, high conductivity and befitting porous structure, and also achieve large mass loading of pseudo-capacitive materials with high dispersion for pseudo-capacitors. As a result, these composite materials are promising candidates for the electrode materials of high-performance supercapacitors with high capacitance, excellent rate performance and long lifetime.

Contents
1 Introduction
2 The preparation strategies of carbon nanotube/graphene composites
2.1 The assembling based on π-π interaction
2.2 The assembling based on electrostatic attraction
2.3 In-situ growth
2.4 Other methods
3 Ternary composite electrodes based on graphene, carbon nanotube and pseudo-capacitive materials
3.1 Carbon nanotube/graphene/conductive polymer
3.2 Carbon nanotube/graphene/metallic oxides (hydroxides)
4 Conclusion

Key words: carbon nanotube, graphene, composite, supercapacitor

中图分类号: 

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