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化学进展 2014, Vol. 26 Issue (06): 1005-1020 DOI: 10.7536/PC131233 前一篇   后一篇

• 综述与评论 •

锂单离子导电固态聚合物电解质

张恒1, 郑丽萍1, 聂进1, 黄学杰2, 周志彬*1   

  1. 1. 大型电池关键材料与系统教育部重点实验室 华中科技大学化学与化工学院 武汉 430074;
    2. 中国科学院物理研究所 北京 100190
  • 收稿日期:2013-12-01 修回日期:2014-02-01 出版日期:2014-06-15 发布日期:2014-03-31
  • 通讯作者: 周志彬 E-mail:zb-zhou@mail.hust.edu.cn
  • 基金资助:

    国家自然科学基金项目（No. 51172083）资助

下载PDF ( 2253 ) 引用
导出 被引次数 ( 7 | 3 )

Single Lithium-Ion Conducting Solid Polymer Electrolytes

Zhang Heng1, Zheng Liping1, Nie Jin1, Huang Xuejie2, Zhou Zhibin*1   

  1. 1. Key Laboratory for Large-Format Battery Materials and System-Ministry of Education, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, China;
    2. Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China
  • Received:2013-12-01 Revised:2014-02-01 Online:2014-06-15 Published:2014-03-31
  • Supported by:

    The work was supported by the National Natural Science Foundation of China(No. 51172083)

锂单离子导电固态聚合物电解质是一类锂离子迁移数接近1的锂离子导体，可以有效避免阴离子移动产生浓差极化，从而提高锂电池的容量以及循环性能，成为近年来固态聚合物电解质的研究热点。本文综述了锂单离子导电固态聚合物电解质的研究进展，重点关注了电导率和锂离子迁移数较高的体系，并简要评述了锂单离子导电固态聚合物电解质所面临的挑战以及发展前景。

关键词： 锂电池, 固态聚合物电解质, 锂单离子导体, 锂离子迁移数

Single lithium-ion conductors (SLICs), which have anions covalently bonded to polymers or immobilized by anion acceptors, have been intensively studied. SLICs are generally accepted to have advantages over conventional salt-in-polymer electrolytes for application in lithium batteries due to the unity transference number and the absence of detrimental effect of anion polarization. By now, many types of SLICs have been reported, including organic polymers, organic-inorganic hybrid polymers and anion acceptors. In this paper, progresses in SLICs are reviewed, which mainly focused on their electrochemical properties, especially those with high ionic conductivity and high lithium-ion transference number. The current challenges and future perspectives in this field are also prospected.

Contents
1 Introduction
2 Organic polymer-based single lithium-ion con-ductors
2.1 Single lithium-ion conductors based on lithium salts of ionomer without ion conduction matrix
2.2 Single lithium-ion conductors based on lithium salts of ionomer with ion conduction matrix
3 Organic-inorganic hybrid polymers
3.1 The siloxane-based single lithium-ion conductors
3.2 The aluminate and borate-based hybrid polymers
4 Anion acceptor
4.1 Lewis acid-based anion acceptor
4.2 Calixarene and their derivatives
5 Conclusions and outlook

Key words: lithium battery, solid polymer electrolyte, single lithium-ion conductor, lithium-ion transference number

中图分类号: 

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摘要

锂单离子导电固态聚合物电解质