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化学进展 2014, Vol. 26 Issue (07): 1214-1222 DOI: 10.7536/PC131208 前一篇   后一篇

• 综述与评论 •

自具微孔高分子气体分离膜的结构调控与改性研究

吴新妹, 张秋根*, 朱爱梅, 刘庆林   

  1. 厦门大学化学化工学院 厦门 361005
  • 收稿日期:2013-12-01 修回日期:2014-03-01 出版日期:2014-07-15 发布日期:2014-05-22
  • 通讯作者: 张秋根 E-mail:qgzhang@xmu.edu.cn
  • 基金资助:

    国家自然科学基金项目（No.21306155）、高等学校博士点专项科研基金（No.20120121120013）、中央高校科研业务费项目（No.2012121029）资助

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导出 被引次数 ( 7 | 3 )

Advances in Structure Controls and Modifications of PIMs Membranes for Gas Separation

Wu Xinmei, Zhang Qiugen*, Zhu Aimei, Liu Qinglin   

  1. College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China
  • Received:2013-12-01 Revised:2014-03-01 Online:2014-07-15 Published:2014-05-22
  • Supported by:

    The work was supported by the National Natural Science Foundation of China(No. 21306155), the Research Fund for the Doctoral Program of Higher Education (No. 20120121120013) and the Fundamental Research Funds for the Central Universities (No. 2012121029)

自具微孔高分子（polymers of intrinsic microporosity， PIMs）是近年来出现的一种新型有机微孔材料，由含有扭曲结构的刚性单体聚合而成，具有比表面积高、化学和物理性质稳定、微孔结构可控等优点，在均相催化、氢气储存等方面表现出巨大的应用潜力。因其优越的气体分离性能，PIMs气体分离膜更是吸引了众多研究者的关注，发展迅速。本文总结了PIMs的分类及其在气体分离膜中的应用，重点介绍了PIMs气体分离膜的结构调控与改性方面的研究进展，分析了PIMs的分子结构与气体分离性能间的内在关联，最后提出了目前研究中存在的一些问题并对其发展做出了简要的评述。

关键词： 自具微孔高分子, 气体分离膜, 高分子膜, 有机微孔材料

Polymers of intrinsic microporosity (PIMs), as novel microporous organic polymers polymerized by rigid monomers that have sites of contortion, have great application potential in homogeneous catalysis and hydrogen storage due to their high specific surface, chemical and physical stability and pore size controllability. Particularly, PIMs composed of polymer chains attract more attention in gas separation membranes due to their superior gas separation properties and good solubility. Here, the classification and applications of PIMs as well as the properties including stability, gas permeability and gas selectivity of PIMs gas membrane are introduced. The structure controls and modifications of PIMs gas membrane and the relationship between molecular structures and gas separation properties are described in detail. Finally, the problems existed in the present research are pointed out and a brief comment on the development is given.

Contents
1 Introduction
2 Summary of PIMs gas separation membranes
2.1 Classification of PIMs
2.2 Properties of PIMs gas separation membranes
3 Structure controls of PIMs gas separation membranes
3.1 Change of the rigidity of linking groups between benzene rings
3.2 Adjustment of the angles of spiro or twist centers and the lengths between the spirocentres
3.3 Introduce of different pendant substituents
4 Modifications of PIMs gas separation membranes
4.1 Cross-linking
4.2 Blending
5 Conclusions and outlook

Key words: PIMs, gas separation, polymer membrane, microporous organic materials

中图分类号: 

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