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化学进展 2014, Vol. 26 Issue (06): 961-975 DOI: 10.7536/PC131207 前一篇   后一篇

• 综述与评论 •

铁基无机介孔材料

黎飞虎*1,2, 聂东阳1   

  1. 1. 南京信息工程大学环境科学与工程学院 江苏省环境净化材料工程技术研究中心 江苏省大气环境监测与污染控制重点实验室 南京 210044;
    2. Earth Science Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720
  • 收稿日期:2013-11-01 修回日期:2014-01-01 出版日期:2014-06-15 发布日期:2014-03-10
  • 通讯作者: 黎飞虎 E-mail:fhli@nuist.edu.cn
  • 基金资助:

    国家自然科学基金项目（No. 51002080，51310105009）、国家留学基金委项目（No. 2011832032）和江苏高校优势学科建设工程项目资助

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Iron-Based Inorganic Mesoporous Materials

Li Feihu*1,2, Nie Dongyang1   

  1. 1. School of Environmental Science and Engineering, Nanjing University of Information Science & Technology, Jiangsu Engineering Technology Center for Environmental Purification Materials Research, Jiangsu Key Lab of Atmospheric Environment Monitor and Pollution Control, Nanjing 210044, China;
    2. Earth Science Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, U. S. A.
  • Received:2013-11-01 Revised:2014-01-01 Online:2014-06-15 Published:2014-03-10
  • Supported by:

    The work was supported by the National Natural Science Foundation of China (No. 51002080, 51310105009), the China Scholorship Council(CSC) program(No.2011832032) and the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)

铁基无机介孔材料因其环境友好、成本低廉及独特磁性与化学活性等优点而备受关注，并在众多领域展现出巨大的应用前景。本文综述了近年来铁基无机介孔材料的合成及其应用研究，重点归纳评述了各类铁基无机介孔材料（如介孔水合氧化铁、介孔氧化铁、介孔硅酸铁、介孔磷酸铁、铁基介观晶体、Fe/Si（C、Al、Ti）复合物等）的制备技术和结构特性；概括并讨论了铁基无机介孔材料在催化、吸附、气体传感、锂离子电池、医药、主客体合成等领域的应用技术；分析了目前铁基无机介孔材料研究存在的问题并总结了未来的研究方向。

关键词： 介孔, 氧化铁, 硅酸铁, 磷酸铁, 铁基介观晶体

Iron-base inorganic mesoporous materials have attracted a lot of attentions recently due to their environmental-benignancy, cost-efficiency, and unique properties of magnetism and chemical activity, which allow them to find potential applications in different areas. In this paper, the recent progress in synthesis of iron-based inorganic mesoporous materials as well as their applications has been reviewed, with an emphasis on the synthetic routes and structural properties of various iron-based inorganic mesoporous materials (i.e., mesoporous iron oxyhydroxides, mesoporous iron oxides, mesoporous ferrosilicates, mesoporous iron phosphates, iron-based mesocrystals, mesoporous Fe/Si (C, Al, Ti) composites, etc.). In addition, their applications in catalysis, adsorption, gas-sensing, lithium-ion batteries, pharmacies, host-guest synthesis and other fields have been summarized and discussed. The current research problems of iron-based inorganic mesoporous materials and several future research directions have also been addressed.

Contents
1 Introduction
2 Synthesis of iron-based mesoporous materials
2.1 Mesoporous iron oxyhydroxides (MIHs)
2.2 Mesoporous iron oxides (MIOs)
2.3 Mesoporous ferrosilicates (MFSs)
2.4 Mesoporous iron phosphates (MIPs)
2.5 Iron-based mesocrytals (IMCs)
2.6 Mesoporous Fe/Si (C, Al, Ti) composites
2.7 Other iron-based mesoporous materials
3 Applications of iron-based mesoporous materials
3.1 Catalysis
3.2 Adsorption
3.3 Gas-sensing
3.4 Li-ion batteries
3.5 Pharmacies
3.6 Host-guest synthesis
3.7 Other applications
4 Summary

Key words: mesoporous, iron oxides, ferrosilicates, iron phosphate, iron-based mesocrystals

中图分类号: 

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铁基无机介孔材料