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化学进展 2014, Vol. 26 Issue (05): 749-755 DOI: 10.7536/PC131128 前一篇   后一篇

• 综述与评论 •

氨硼烷释氢纳米金属催化剂的研究

张磊1, 涂倩1, 陈学年2, 刘蒲*1   

  1. 1. 郑州大学化学与分子工程学院 郑州 450001;
    2. 河南师范大学化学化工学院 新乡 453007
  • 收稿日期:2013-11-01 修回日期:2014-02-01 出版日期:2014-05-15 发布日期:2014-03-13
  • 通讯作者: 刘蒲，e-mail：liupu@zzu.edu.cn E-mail:liupu@zzu.edu.cn
  • 基金资助:

    国家自然科学基金项目（No. J1210060）资助

下载PDF ( 2001 ) 引用
导出 被引次数 ( 2 | 3 )

Nano Metal Catalysts in Dehydrogenation of Ammonia Borane

Zhang Lei1, Tu Qian1, Chen Xuenian2, Liu Pu*1   

  1. 1. College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, China;
    2. School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang 453007, China
  • Received:2013-11-01 Revised:2014-02-01 Online:2014-05-15 Published:2014-03-13
  • Supported by:

    The work was supported by the National Natural Science Foundation of China (No. J1210060)

化学储氢材料要求具有高的氢存储容量。氨硼烷（NH3BH3，AB）的氢含量高达19.6 wt%，是一种具有潜在应用前景的氢存储介质。AB的水解释氢容量高达7.8 wt %，热解释氢则可释放出19.6 wt %的氢，显示出其在化学储氢方面的巨大潜力。在AB释氢研究中，催化剂是研究的核心技术和重要方向。由于纳米催化剂在AB释氢中所表现出的优良催化性能，本文将对氨硼烷释氢纳米金属催化剂及其性能的研究进行全面的总结和展望。

关键词： 氨硼烷, 释氢, 纳米粒子, 催化剂, 金属

As the chemical hydrogen storage material, it must have a high hydrogen storage capacity. Ammonia borane (NH3BH3, AB), whose hydrogen content is as high as 19.6 wt%, is regarded as a potential hydrogen storage medium with the bright future. The capacity of AB hydrolysis dehydrogenation is up to 7.8 wt%. The capacity of AB pyrolysis dehydrogenation can release 19.6 wt% of hydrogen. Both the hydrolysis dehydrogenation and the pyrolysis dehydrogenation have shown its great potential in the chemical hydrogen storage. In the study of AB dehydrogenation, catalyst is the key technology and the important research direction. Among all the catalysts about AB dehydrogenation, nano metal catalysts have been investigated for their excellent performance. In this paper, the nano catalysts and their performance about the dehydrogenation of ammonia borane are reviewed.

Contents
1 Introduction
2 One-component nano metal catalysts
2.1 Nano rhodium catalysts
2.2 Nano palladium catalysts
2.3 Nano ruthenium catalysts
2.4 Nano nickel catalysts
2.5 Other nano metals catalysts
3 Two-components nano metal catalysts
3.1 The supported bimetal catalysts
3.2 The alloy bimetal catalysts
3.3 The core-shell bimetal catalysts
4 Three-components nano metal nanoparticles
5 Conclusions and outlook

Key words: ammonia borane, dehydrogenation, nanoparticles, catalyst, metal

中图分类号: 

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