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化学进展 2014, Vol. 26 Issue (05): 898-908 DOI: 10.7536/PC130952 前一篇   

• 综述与评论 •

活化过硫酸盐原位化学氧化修复有机污染土壤和地下水

龙安华1,2, 雷洋1, 张晖*1   

  1. 1. 武汉大学环境工程系 湖北省生物质资源化学与环境生物技术重点实验室(武汉大学) 武汉 430079;
    2. 江西科技师范大学 南昌 330013
  • 收稿日期:2013-09-01 修回日期:2013-12-01 出版日期:2014-05-15 发布日期:2014-03-13
  • 通讯作者: 张晖，e-mail：eeng@whu.edu.cn E-mail:eeng@whu.edu.cn
  • 基金资助:

    国家自然科学基金项目（No. 20107005）；江西省教育厅科技项目（No. GJJ13557）；生物质资源化学与环境生物技术湖北省重点实验室（武汉大学）开放基金项目（No. HBRCEBL2012-2013004）和江西科技师范大学博士科研启动基金项目（No. 3000990115）资助

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In Situ Chemical Oxidation of Organic Contaminated Soil and Groundwater Using Activated Persulfate Process

Long Anhua1,2, Lei Yang1, Zhang Hui*1   

  1. 1. Department of Environmental Engineering, Hubei Biomass-Resource Chemistry and Environmental Biotechnology Key Laboratory, Wuhan University, Wuhan 430079, China;
    2. Jiangxi Science and Technology Normal University, Nanchang 330013, China
  • Received:2013-09-01 Revised:2013-12-01 Online:2014-05-15 Published:2014-03-13
  • Supported by:

    The work was supported by the National Natural Science Foundation of China (No. 20107005), Research Fund of Jiangxi Provincial Education Department (No. GJJ13557), the Opening Foundation of Hubei Biomass-Resource Chemistry and Environmental Biotechnology Key Laboratory(Wuhan University)(No. HBRCEBL2012-2013004) and Ph.D. Research Startup Foundation of Jiangxi Science and Technology Normal University (No. 3000990115)

原位化学氧化 （ISCO）是近些年来国内外较为推崇的一种土壤和地下水修复技术。过硫酸盐（PS，S2O82-）具有易运输、较稳定、易溶于水和易传质等性质，能很好地适应ISCO的发展要求。它在光、热、过渡金属离子、强氧化剂和强碱性环境等活化条件下，能产生强氧化性的硫酸根自由基SO4·-，适用于氧化降解各种有机污染物。本文在分析活化过硫酸盐（activated persulfate，APS）氧化机理的基础上，综述了不同方式活化过硫酸盐原位修复有机污染土壤和地下水及APS协同、联用技术的应用，并就值得深入研究的问题和热点趋势进行了展望。

关键词： 活化过硫酸盐, 原位化学氧化修复(ISCO), 硫酸根自由基, 有机污染物, 土壤和地下水修复

In-situ chemical oxidation (ISCO) is an effective technology for the remediation of organic contaminated soils and groundwater, as it has high contaminants removal rates and offers the possibility of fast treatment. As an in-situ remediation technology, ISCO can be also used for minimizing contaminants dispersion and lowering the overall treatment cost. Persulfate (PS) is an emerging and promising oxidant for in-situ soil and groundwater remediations due to its high redox potential (E0=2.01 V), long-term stability, high-water solubility, easy transport and wide operative pH range. It can be thermally or chemically activated by initiators to form sulfate radical (SO4·-), a strong oxidant (E0 =2.60 V) which has been successfully used for environmental applications in the remediation of aqueous and sediment systems. The activation methods include UV, heat, transition metals ions, alkaline condition and PS combined with other oxidants. Therefore, the application of activated persulfate (APS) oxidation has emerged as a novel ISCO. This paper provides an overview of mechanism and research progress of APS oxidation. It also reviews the engineering application of APS oxidation technology such as synergistic and hyphenated action for remediation of organic contaminated soils and groundwater, and points out the prospects of the research areas meriting further investigation and development trends.

Contents
1 Introduction
2 Mechanism and research progress of activation oxidation
2.1 Methods of activation and reaction mechanism
2.2 Heat activation
2.3 Transition metals activation
2.4 Alkaline activation
2.5 Combination of other oxidants
2.6 Research areas meriting further investigation and development trends
3 Engineering application of APS
3.1 Synergistic activation of PS
3.2 Integration of APS with other processes
4 Conclusion and perspective

Key words: activated persulfate, in-situ chemical oxidation, sulfate radicals, organic contaminants, soil and groundwater remediation

中图分类号: 

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