English
往期目录
新闻公告
More
化学进展 2014, Vol. 26 Issue (05): 737-748 DOI: 10.7536/PC130941 前一篇   后一篇

• 综述与评论 •

茂金属催化剂的负载化

齐美洲, 傅智盛, 范志强*   

  1. 高分子合成与功能构造教育部重点实验室 浙江大学高分子科学与工程学系 杭州 310027
  • 收稿日期:2013-09-01 修回日期:2013-11-01 出版日期:2014-05-15 发布日期:2014-03-13
  • 通讯作者: 范志强，e-mail：fanzq@zju.edu.cn E-mail:fanzq@zju.edu.cn
  • 基金资助:

    国家高技术研究发展计划（863）项目（No. 2012AA040305）资助

下载PDF ( 2300 ) 引用
导出 被引次数 ( 2 )

Immobilization of Metallocene Catalysts

Qi Meizhou, Fu Zhisheng, Fan Zhiqiang*   

  1. MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China
  • Received:2013-09-01 Revised:2013-11-01 Online:2014-05-15 Published:2014-03-13
  • Supported by:

    The work was supported by the National High Technology Research and Development Program of China (No. 2012AA040305)

茂金属催化剂是继齐格勒-纳塔催化剂之后的新一代烯烃聚合催化剂，与多活性中心催化剂相比，这种单一活性中心类型的催化剂具有聚合活性较高、聚合物分子量分布较窄等特点。其中，负载化是茂金属催化剂实用化的重要课题，它克服了均相催化体系中聚合物形貌不可控的缺点，降低了助催化剂的用量。近些年来茂金属负载化的研究仍很活跃。本文总结了近十年来茂金属负载化的研究进展，主要对载体的形貌、载体的改性处理、茂金属催化剂的负载方法和负载化茂金属催化剂的应用进行了评述并展望了茂金属催化剂负载化的发展趋势。

关键词： 茂金属, 负载化, 载体, 聚烯烃, 纳米复合物

Metallocene catalysts form a new generation of catalysts for olefin polymerization after Ziegler-Natta catalysts. Compared with multi-active site catalysts, this kind of single-site catalysts has higher polymerization activity and produces polyolefin with narrower molecular weight distribution and composition distribution. Immobilization of metallocene catalysts on solid supports is an important step toward its industrial application, as it can largely overcome the drawbacks of homogeneous catalysts in controlling nascent polymer morphology. The amount of alkylaluminoxane cocatalyst can also be reduced after immobilization. Thus, research on immobilization of metallocene catalysts is still active in recent years. This paper reviews the progress in immobilization of metallocene cataylsts in recent ten years with emphasis on the morphologies and modifications of supports, immobilization methods of metallocene catalysts, and applications of supported metallocene catalysts. The prospects and development trends on immobilization of metallocene catalysts are also discussed.

Contents
1 Introduction
2 Morphologies of supports
2.1 Spherical supports
2.2 Tubular supports
2.3 Rodlike supports
2.4 Sheet supports
2.5 Irregular supports
3 Modifications of supports
3.1 Treatment with alkylaluminoxanes
3.2 Treatment with aluminum alkyls
3.3 Treatment with oxides
3.4 Treatment with chlorides
3.5 Treatment with silane compounds
3.6 Treatment with other modifiers
4 Immobilization methods of metallocene catalysts
4.1 Immobilization of bi-components
4.2 Immobilization of single components
5 Applications of supported metallocene catalysts
5.1 Polyethylene composites
5.2 Polypropylene composites
6 Conclusion and outlook

Key words: metallocene, immobilization, supports, polyolefin, nanocomposites

中图分类号: 

()

[1] Resconi L, Cavallo L, Fait A, Piemontesi F. Chem. Rev., 2000, 100(4): 1253.
[2] Chen E Y X, Marks T J. Chem. Rev., 2000, 100(4): 1391.
[3] Coates G W. Chem. Rev., 2000, 100(4): 1223.
[4] De Rosa C, Auriemma F. Prog. Polym. Sci., 2006, 31(2): 145.
[5] Alt H G, Koppl A. Chem. Rev., 2000, 100(4): 1205.
[6] Wang B Q. Coord. Chem. Rev., 2006, 250(1): 242.
[7] Atiqullah M, Tinkl M, Pfaendner R, Akhtar M N, Hussain I. Polym. Rev., 2010, 50(2): 178.
[8] Tynys A, Saarinen T, Bartke M, Lofgren B. Polymer, 2007, 48(7): 1893.
[9] Bastos Q C, Marques M D F V. J. Polym. Sci. Part A: Pol. Chem., 2004, 43(2): 263.
[10] Hong S C, Mihan S, Lilge D, Delux L, Rief U. Polym. Eng. Sci., 2007, 47(2): 131.
[11] Hong D S, Lee K S, Cho J H, Song E K, Lee Y H, Lee B R, Kim S K. EP 2374822, 2011.
[12] Ahmadi M, Jamjah R, Nekoomanesh M, Zohuri G H, Arabi H. Macromol. React. Eng., 2007, 1(6): 604.
[13] Lu L, Fan H, Li B G, Zhu S. Ind. Eng. Chem. Res., 2009, 48(18): 8349.
[14] Yamamoto K, Ishihama Y, Sakata K. J. Polym. Sci. Part A: Pol. Chem., 2010, 48(17): 3722.
[15] Alt H G. Dalton Trans., 2005, (20): 3271.
[16] De Freitas A J D, Dos Santos J H Z, Meneghetti S M P, Meneghetti M R. J. Appl. Polym. Sci., 2011, 119(5): 3051.
[17] Shan C L P, Soares J B P, Penlidis A. J. Polym. Sci. Part A: Pol. Chem., 2002, 40(24): 4426.
[18] Kumkaew P, Wu L, Praserthdam P, Wanke S. Polymer, 2003, 44(17): 4791.
[19] Kwon H J, Hwang S A, Lee D G, Park C Y. WO 2011111980, 2011.
[20] Tioni E, Monteil V, McKenna T. Macromolecules, 2012, 46(2): 335.
[21] Marques M D V, De Alcantara M. J. Polym. Sci. Part A: Pol. Chem., 2004, 42(1): 9.
[22] Czaja K, Bialek M, Utrata A. J. Polym. Sci. Part A: Pol. Chem., 2004, 42(10): 2512.
[23] Pothirat T, Jongsomjit B, Praserthdam P. Catal. Commun., 2008, 9(6): 1426.
[24] Covarrubias C, Quijada R, Rojas R. Appl. Catal. A: Gen., 2008, 347(2): 223.
[25] Campos J M, Lourenço J P, Fernandes A, Rego A M, Ribeiro M R. J. Mol. Catal. A: Chem., 2009, 310(1): 1.
[26] Hicks J C, Mullis B A, Jones C W. J. Am. Chem. Soc., 2007, 129(27): 8426.
[27] Jongsomjit B, Ngamposri S, Praserthdam P. Ind. Eng. Chem. Res., 2005, 44(24): 9059.
[28] Fisch A G, Cardozo N S M, Secchi A R, Stedile F C, Livotto P R, De Sá D S, Da Rocha Z N, Dos Santos J H Z. Appl. Catal. A: Gen., 2009, 354(1): 88.
[29] Brambilla R, Radtke C, Stedile F C, Dos Santos J H Z, Miranda M S L. Appl. Catal. A: Gen., 2010, 382(1): 106.
[30] Carrero A, Van Grieken R, Paredes B. J. Appl. Polym. Sci., 2011, 120(1): 599.
[31] Wang W Q, Wang L, Wang J F, Wang J J, Ma Z L. J. Polym. Sci. Part A: Pol. Chem., 2005, 43(12): 2650.
[32] Wang W Q, Wang L, Dong X C, Sun T X, Wang J F. J. Appl. Polym. Sci., 2006, 102(2): 1574.
[33] Chukanova O M, Saratovskikh S L, Babkina O N, Rishina L A, Nedorezova P M, Bravaya N M. Polym. Sci. Ser. A, 2003, 45(8): 747.
[34] Zhou J M, Li N H, Bu N Y, Lynch D T, Wanke S E. J. Appl. Polym. Sci., 2003, 90(5): 1319.
[35] Hammawa H, Mannan T M, Lynch D T, Wanke S E. J. Appl. Polym. Sci., 2004, 92(6): 3549.
[36] Wu L, Zhou J M, Lynch D T, Wanke S E. Appl. Catal. A: Gen., 2005, 293: 180.
[37] Hammawa H, Wanke S E. Polym. Int., 2006, 55(4): 426.
[38] Hammawa H, Wanke S E. J. Appl. Polym. Sci., 2007, 104(1): 514.
[39] Orass H, Akhlaq M, Atieh A R. US 7662894, 2010.
[40] Nenov N, Koch M, Klapper M, Müllen K. Polym. Bull., 2002, 47(5): 391.
[41] Lu J N, Toy P H. Chem. Rev., 2009, 109(2): 815.
[42] Schellenberg J. Prog. Polym. Sci., 2009, 34(8): 688.
[43] Choi Y, Soares J B P. Can. J. Chem. Eng., 2012, 90(3): 646.
[44] Kumkaew P, Wanke S, Praserthdam P, Danumah C, Kaliaguine S. J. Appl. Polym. Sci., 2003, 87(7): 1161.
[45] Silveira F, Petry C F, Pozebon D, Pergher S B, Detoni C, Stedile F C, Dos Santos J H Z. Appl. Catal. A: Gen., 2007, 333(1): 96.
[46] Li K T, Kao Y T. J. Appl. Polym. Sci., 2006, 101(4): 2573.
[47] Li K T, Dai C L, Kuo C W. Catal. Commun., 2007, 8(8): 1209.
[48] Li K T, Dai C L, Li C Y. Polym. Bull., 2010, 64(8): 749.
[49] Severn J R, Chadwick J C, Duchateau R, Friederichs N. Chem. Rev., 2005, 105(11): 4073.
[50] Campos J M, Lourenço J P, Cramail H, Ribeiro M R. Prog. Polym. Sci., 2012, 37(12): 1764.
[51] Dong X C, Wang L, Wang W Q, Yu H J, Wang J F, Chen T, Zhao Z R. Eur. Polym. J., 2005, 41(4): 797.
[52] Silveira F, Alves M D M, Stedile F C, Pergher S B, Dos Santos J H Z. J. Mol. Catal. A: Chem., 2010, 315(2): 213.
[53] Dong X C, Wang L, Jiang G H, Zhao Z R, Sun T X, Yu H J, Wang W Q. J. Mol. Catal. A: Chem., 2005, 240(1/2): 239.
[54] Knoke S, Korber F, Fink G, Tesche B. Macromol. Chem. Phys., 2003, 204(4): 607.
[55] Dong X C, Wang L, Zhou J F, Deng L B, Huo J, Zhang C L. J. Phys. Chem. B, 2006, 110(26): 13045.
[56] Horá D?ková B, Grof Z, Kosek J. Chem. Eng. Sci., 2007, 62(18): 5264.
[57] Tisse V F, Prades F, Briquel R, Boisson C, McKenna T F L. Macromol. Chem. Phys., 2010, 211(1): 91.
[58] Severn J R, Chadwick J C. Macromol. Rapid Commun., 2004, 25(10): 1024.
[59] Jang Y J, Naundorf C, Klapper M, Müllen K. Macromol. Chem. Phys., 2005, 206(20): 2027.
[60] Shi L, Qin Y, Cheng W, Chen H, Tang T. Polymer, 2007, 48(9): 2481.
[61] Liu C B, Tang T, Huang B T. J. Polym. Sci. Part A: Pol. Chem., 2003, 41(7): 873.
[62] Lei J, Li D, Wang H, Wang Z, Zhou G. J. Polym. Sci. Part A: Pol. Chem., 2011, 49(6): 1503.
[63] Liu J G, Dong J Y, Cui N N, Hu Y L. Macromolecules, 2004, 37(17): 6275.
[64] Chen J F, Song J R, Wen L X, Zou H K, Shao L. J. Non-Cryst. Solids, 2007, 353(11): 1030.
[65] Qin Y X, Tang T, Zhao Z F, Huang B T. J. Polym. Sci. Part A: Pol. Chem., 2003, 41(21): 3313.
[66] Tritto I, Boggioni L, Ravasio A, Zampa C, Hitzbleck J, Okuda J, Bredeau S, Dubois P. Macromol. Symp., 2007, 260(1): 114.
[67] Bredeau S, Boggioni L, Bertini F, Tritto I, Monteverde F, Alexandre M, Dubois P. Macromol. Rapid Commun., 2007, 28(7): 822.
[68] Li S Y, Chen H, Cui D M, Li J Z, Zhang Z J, Wang Y H, Tang T. Polym. Compos., 2010, 31(3): 507.
[69] Bonduel D, Bredeau S, Alexandre M, Monteverde F, Dubois P. J. Mater. Chem., 2007, 17(22): 2359.
[70] Hu Z, Liu C B, Wu Y L, Liu R H, He Y J, Luo S L. J. Polym. Sci. Part B: Pol. Phys., 2011, 49(11): 812.
[71] Zapata P A, Quijada R, Lieberwirth I, Palza H. Appl. Catal. A: Gen., 2011, 407(1/2): 181.
[72] Covarrubias C, Quijada R. Catal. Commun., 2009, 10(6): 995.
[73] Dong X C, Wang L, Wang W Q, Jiang G H, Chen Y, Zhao Z R, Wang J J. Macromol. Mater. Eng., 2005, 290(1): 31.
[74] Dong X C, Wang L, Wang J J, Zhou J F, Sun T X. J. Phys. Chem. B, 2006, 110(18): 9100.
[75] Silveira F, Martins Alves M d C, Stedile F C, Pergher S B, Rigacci A, Zimnoch dos Santos J H. J. Mol. Catal. A: Chem., 2009, 298(1/2): 40.
[76] Li W, Adams A, Wang J D, Blümich B, Yang Y R. Polymer, 2010, 51(21): 4686.
[77] Wang Q, Zhou Z Y, Song L X, Xu H, Wang L. J. Polym. Sci. Part A: Pol. Chem., 2004, 42(1): 38.
[78] Guo C Y, Ke Y C, Liu Y X, Mi X, Zhang M G, Hu Y L. Polym. Int., 2009, 58(11): 1319.
[79] Liu C B, Tang T, Wang D, Huang B T. J. Polym. Sci. Part A: Pol. Chem., 2003, 41(14): 2187.
[80] Usuki A, Hasegawa N, Kato M. Adv. Polym. Sci., 2005, 179: 135.
[81] Ren C Y, Du X H, Ma L, Wang Y H, Zheng J, Tang T. Polymer, 2010, 51(15): 3416.
[82] Lee S Y, Kim S K, Nguyen T M, Chung J S, Lee S B, Choi K Y. Macromolecules, 2011, 44(6): 1385.
[83] Stürzel M, Kempe F, Thomann Y, Mark S, Enders M, Mülhaupt R. Macromolecules, 2012, 45(17): 6878.
[84] Hu Z, Liu C B. J. Polym. Res., 2013, 20(1): 1.
[85] Rauscher D J, Gauthier W J. US 20060154809, 2006.
[86] Barrera E G, Stedile F C, de Souza M O, Miranda M S L, de Souza R F, Bernardo-Gusmo K. Appl. Catal. A: Gen., 2013, 462/463: 1.
[87] Han J J, Yoon W J, Lee H W, Choi K Y. Polymer, 2008, 49(19): 4141.
[88] Van Grieken R, Carrero A, Suarez I, Paredes B. Eur. Polym. J., 2007, 43(4): 1267.
[89] Bianchini D, Galland G B, Dos Santos J H Z, Williams R J J, Fasce D P, Dell'Erba I E, Quijada R, Perez M. J. Polym. Sci. Part A: Pol. Chem., 2005, 43(22): 5465.
[90] García-Orozco I, Velilla T, Galland G B, Dos Santos J H Z, Williams R J J, Quijada R. J. Polym. Sci. Part A: Pol. Chem., 2010, 48(24): 5938.
[91] Yim J H, Ihm S K. J. Appl. Polym. Sci., 2006, 102(3): 2293.
[92] Zapata P, Quijada R, Covarrubias C, Moncada E, Retuert J. J. Appl. Polym. Sci., 2009, 113(4): 2368.
[93] Chaichana E, Khaubunsongserm S, Praserthdam P, Jongsomjit B. Polym. Bull., 2011, 66(9): 1301.
[94] Fink G, Steinmetz B, Zechlin J, Przybyla C, Tesche B. Chem. Rev., 2000, 100(4): 1377.
[95] Haag M C, Dupont J, Stedile F C, dos Santos J H Z. J. Mol. Catal. A: Chem., 2003, 197(1/2): 223.
[96] Hlatky G G. Chem. Rev., 2000, 100(4): 1347.
[97] Paavola S, Saarinen T, Lofgren B, Pitkanen P. Polymer, 2004, 45(7): 2099.
[98] Tannous K, Soares J B P. Macromol. Chem. Phys., 2002, 203(13): 1895.
[99] Franceschini F C, Tavares T T D, Bianchini D, Alves M D M, Ferreira M L, dos Santos J H. J. Appl. Polym. Sci., 2009, 112(1): 563.
[100] Franceschini F C, Tavares T T D, Greco P P, Galland G B, Dos Santos J H Z, Soares J B P. J. Appl. Polym. Sci., 2005, 95(5): 1050.
[101] Franceschini F C, Tavares T T D, Greco P P, Bianchini D, Stedile F C, Galland G B, dos Santos J H Z, Soares J B P. J. Mol. Catal. A: Chem., 2003, 202(1/2): 127.
[102] Ochedzan-Siodak W, Nowakowska M. Eur. Polym. J., 2005, 41(5): 941.
[103] Cho H S, Lee W Y. J. Mol. Catal. A: Chem., 2003, 191(2): 155.
[104] Ochdzan-Siodak W, Nowakowska M. Eur. Polym. J., 2004, 40(4): 839.
[105] Babushkin D E, Panchenko V N, Timofeeva M N, Zakharov V A, Brintzinger H H. Macromol. Chem. Phys., 2008, 209(12): 1210.
[106] Prades F, Broyer J P, Belaid I, Boyron O, Miserque O, Spitz R, Boisson C. ACS Catal., 2013, 3: 2288.
[107] Kim H G, Lee K S, Hong D S, Song E K, Jeon M S. EP 2623522, 2013.
[108] Jiamwijitkul S, Jongsomjit B, Praserthdam P. Iran. Polym. J., 2007, 16(8): 549.
[109] Campos J M, Ribeiro M R, Lourenço J P, Fernandes A. J. Mol. Catal. A: Chem., 2007, 277(1): 93.
[110] Campos J M, Lourenço J P, Fernandes A, Ribeiro M R. Catal. Commun., 2008, 10(1): 71.
[111] Pothirat T, Jongsomjit B, Praserthdam P. Catal. Lett., 2008, 121(3/4): 266.
[112] Wannaborworn M, Praserthdam P, Jongsomjit B. J. Ind. Eng. Chem., 2011, 18(1): 373.
[113] Jongsomjit B, Ngamposri S, Praserthdam P. Catal. Lett., 2005, 100(3): 139.
[114] Chao C R, Pratchayawutthirat W, Praserthdam P, Shiono T, Rempel G L. Macromol. Rapid Commun., 2002, 23(12): 672.
[115] Jantasee S, Shiono T, Jongsomjit B. Polym. Bull., 2013, 70(6): 1753.
[116] Jongsomjit B, Kaewkrajang P, Praserthdam P. Eur. Polym. J., 2004, 40(12): 2813.
[117] Kaivalchatchawal P, Samingprai S, Shiono T, Praserthdam P, Jongsomjit B. Eur. Polym. J., 2012, 48(7): 1304.
[118] Alonso C, Antiolo A, Carrillo-Hermosilla F, Carrión P, Otero A, Sancho J, Villaseñor E. J. Mol. Catal. A: Chem., 2004, 220(2): 286.
[119] Pannier G, Boisson C, Spitz R. WO 2010127988, 2010
[120] Burkett S L, Soukasene S, Milton K L, Welch R, Little A J, Kasi R M, Coughlin E B. Chem. Mater., 2005, 17(10): 2716.
[121] Lee J S, Yim J H, Jeon J K, Ko Y S. Catal. Today, 2012, 185(1): 175.
[122] Britcher L, Rahiala H, Hakala K, Mikkola P, Rosenholm J B. Chem. Mater., 2004, 16(26): 5713.
[123] Liu C B, Tang T, Huang B T. J. Catal., 2004, 221(1): 162.
[124] Greco P P, Stedile F C, dos Santos J H Z. J. Mol. Catal. A: Chem., 2003, 197(1): 233.
[125] Atiqullah M, Moman A A, Akhtar M N, Al-Muallem H A, Abu-Raqabah A H, Ahmed N. J. Appl. Polym. Sci., 2007, 106(5): 3149.
[126] Akhtar M N, Atiqullah M, Moman A A, Abu-Raqabah A H, Ahmed N. Macromol. React. Eng., 2008, 2(4): 339.
[127] Turunen J P, Venlinen T, Suvanto S, Pakkanen T T. J. Polym. Sci. Part A: Pol. Chem., 2007, 45(17): 4002.
[128] Velilla T, Delgado K, Quijada R, Bianchini D, Galland G B, Dos Santos J H Z, Fasce D P, Williams R J J. J. Polym. Sci. Part A: Pol. Chem., 2007, 45(23): 5480.
[129] Heurtefeu B, Bouilhac C, Cloutet , Taton D, Deffieux A, Cramail H. Prog. Polym. Sci., 2011, 36(1): 89.
[130] Zheng X J, Smit M, Chadwick J C, Loos J. Macromolecules, 2005, 38(11): 4673.
[131] Simplício L M T, Costa F G, Boaventura J S, Sales E A, Brando S T. J. Mol. Catal. A: Chem., 2004, 216(1): 45.
[132] Makela-Vaarne N I, Nicholson D G, Ramstad A L. J. Mol. Catal. A: Chem., 2003, 200(1/2): 323.
[133] Jongsomjit B, Kaewkrajang P, Shiono T, Praserthdam P. Ind. Eng. Chem. Res., 2004, 43(24): 7959.
[134] Gauthier W, Rauscher D, Tian J, Williams N. US 20110112262, 2011.
[135] Bonduel D, Mainil M, Alexandre M, Monteverde F, Dubois P. Chem. Commun., 2005, (6): 781.
[136] Kaminsky W, Lemstra P J, Loos J, Muller F, Niemantsverdriet J W, Thune P C, Weingarten U. Israel. J. Chem., 2002, 42(4): 367.
[137] Shin D M, Pham V H, La K W, Song I K, Chung J S. Res. Chem. Intermediat., 2008, 34(8/9): 687.
[138] Carrero A, Van Grieken R, Suarez I, Paredes B. Polym. Eng. Sci., 2008, 48(3): 606.
[139] Smit M, Zheng X J, Loos J, Chadwick J C, Koning C E. J. Polym. Sci. Part A: Pol. Chem., 2006, 44(22): 6652.
[140] Zapata P A, Quijada R, Lieberwirth I, Benavente R. Macromol. React. Eng., 2011, 5(7/8): 294.
[141] Marques M D V, Conte A. J. Appl. Polym. Sci., 2002, 86(8): 2054.
[142] Marques M D V, Moreira S C. J. Mol. Catal. A: Chem., 2003, 192(1/2): 93.
[143] Marques M D V, Beatriz A, Marinha A S. J. Polym. Sci. Part A: Pol. Chem., 2004, 42(12): 3038.
[144] Ye Z B, Zhu S P, Wang W J, Alsyouri H, Lin Y S. J. Polym. Sci. Part B: Pol. Phys., 2003, 41(20): 2433.
[145] Fisch A G, Cardozo N S M, Secchi A R, Stedile F C, Da Silveira N P, Dos Santos J H Z. J. Non-Cryst. Solids, 2008, 354(33): 3973.
[146] Kasi R M, Coughlin E B. Organometallics, 2003, 22(7): 1534.
[147] Barrett A G M, de Miguel Y R. Tetrahedron, 2002, 58(19): 3785.
[148] Shearer A S, De Miguel Y R, Minich E A, Pochan D, Jenny C. Inorg. Chem. Commun., 2007, 10(3): 262.
[149] Turunen J P J, Pakkanen T T. J. Mol. Catal. A: Chem., 2007, 263(1/2): 1.
[150] Bortolussi F, Broyer J P, Spitz R, Boisson C. Macromol. Chem. Phys., 2002, 203(17): 2501.
[151] Zhang J, Jin G X. Inorg. Chem. Commun., 2006, 9(7): 683.
[152] Zhang J, Wang X, Jin G X. Coord. Chem. Rev., 2006, 250(1): 95.
[153] Wannaborworn M, Jongsomjit B. Iran. Polym. J., 2009, 18(12): 969.
[154] Trujillo M, Arnal M L, Müller A J, Laredo E, Bredeau S, Bonduel D, Dubois P. Macromolecules, 2007, 40(17): 6268.
[155] Schlögl M, Riethmueller S, Troll C, Möller M, Rieger B. Macromolecules, 2004, 37(11): 4004.
[156] Heurtefeu B, Merna J, Ibarboure E, Cloutet , Cramail H. Polym. Chem., 2010, 1(7): 1078.
[157] Choi Y Y, Lee K S, Lee S W, Chae H, Park C Y, Lee C H, Lee S J. WO 2006080817, 2006.
[158] Tullo A H. Chem. Eng. News, 2010, 88(42): 10.
[159] Yang K F, Huang Y J, Dong J Y. Polymer, 2007, 48(21): 6254.
[160] Fim F d C, Guterres J M, Basso N R S, Galland G B. J. Polym. Sci. Part A: Pol. Chem., 2010, 48(3): 692.
[161] Qin Y X, Tang T, Zhao Z F. Chem. Commun., 2004, (2): 222.
[162] Owpradit W, Jongsomjit B. Mater. Chem. Phys., 2008, 112(3): 954.
[163] Kaleel S H A, Bahuleyan B K, De S K, Khan M J, Sougrat R, Al-Harthi M A. J. Ind. Eng. Chem., 2012, 18(5): 1836.
[164] Jongsomjit B, Panpranot J, Okada M, Shiono T, Praserthdam P. Iran. Polym. J., 2006, 15(5): 433.
[165] Jongsomjit B, Panpranot J, Praserthdam P. Mater. Lett., 2007, 61(6): 1376.
[166] Desharun C, Jongsomjit B, Praserthdam P. Catal. Commun., 2008, 9(4): 522.
[167] Park S, Yoon S W, Choi H, Lee J S, Cho W K, Kim J, Park H J, Yun W S, Choi C H, Do Y. Chem. Mater., 2008, 20(14): 4588.
[168] Owpradit W, Mekasuwandumrong O, Panpranot J, Shotipruk A, Jongsomjit B. Polym. Bull., 2011, 66(4): 479.
[169] Hakim S, Safajou-Jahankhanemlou M, Zeynali M E. J. Polym. Res., 2013, 20(5): 1.
[170] Huang Y J, Yang K F, Dong J Y. Macromol. Rapid Commun., 2006, 27(15): 1278.
[171] Jongsomjit B, Chaichana E, Praserthdam P. J. Mater. Sci., 2005, 40(8): 2043.
[172] Chaichana E, Pathomsap S, Mekasuwandumrong O, Panpranot J, Shotipruk A, Jongsomjit B. Chinese Sci. Bull., 2012, 57(17): 2177.
[173] Kou B, McAuley K B, Hsu C C, Bacon D W, Yao K Z. Ind. Eng. Chem. Res., 2005, 44(8): 2443.
[174] Park H W, Chung J S, Baeck S H, Song I K. J. Mol. Catal. A: Chem., 2006, 255(1): 69.
[175] Chaichana E, Jongsomjit B, Praserthdam P. Chem. Eng. Sci., 2007, 62(3): 899.
[176] Park H W, La K W, Chung J S, Song I K. Eur. Polym. J., 2007, 43(3): 870.
[177] Park H W, Chung J S, Lim S S, Song I K. J. Mol. Catal. A: Chem., 2007, 264(1): 202.
[178] Jongsomjit B, Ngamposri S, Praserthdam P. Molecules, 2005, 10(6): 672.
[179] Ketloy C, Jongsomjit B, Praserthdam P. Appl. Catal. A: Gen., 2007, 327(2): 270.
[180] Wongwaiwattanakul P, Jongsomjit B. Catal. Commun., 2008, 10(1): 118.
[181] Bunchongturakarn S, Jongsomjit B, Praserthdam P. Catal. Commun., 2008, 9(5): 789.
[182] Guo N, DiBenedetto S A, Kwon D K, Wang L, Russell M T, Lanagan M T, Facchetti A, Marks T J. J. Am. Chem. Soc., 2007, 129(4): 766.
[183] Wiemann K, Kaminsky W, Gojny F H, Schulte K. Macromol. Chem. Phys., 2005, 206(15): 1472.
[184] Bikiaris D. Materials, 2010, 3(4): 2884.
[185] Koval'chuk A A, Shchegolikhin A N, Shevchenko V G, Nedorezova P M, Klyamkina A N, Aladyshev A M. Macromolecules, 2008, 41(9): 3149.
[186] Koval'chuk A A, Shevchenko V G, Shchegolikhin A N, Nedorezova P M, Klyamkina A N, Aladyshev A M. Macromolecules, 2008, 41(20): 7536.
[187] Hwu J M, Jiang G J. J. Appl. Polym. Sci., 2005, 95(5): 1228.hung J S, Lee S B, Choi K Y. Macromolecules, 2011, 44(6): 1385-1392
[83] Stürzel M, Kempe F, Thomann Y, Mark S, Enders M, Mülhaupt R. Macromolecules, 2012, 45(17): 6878-6887
[84] Hu Z, Liu C B. J. Polym. Res., 2013, 2Thomann Y, Mark S0(1): 1-8
[85] Rauscher D J, Gauthier W J. US 20060154809, 2006
[86] Barrera E G, Stedile F C, de Souza M O, Miranda M S L, de Souza R F, Bernardo-Gusmão K. Appl. Catal. A: Gen., 2013, 462-463: 1-7
[87] Han J J, Yoon W J, Lee H W, Choi K Y. Polymer, 2008, 49(19): 4141-4149
[88] Van Grieken R, Carrero A, Suarez I, Paredes B. Eur. Polym. J., 2007, 43(4): 1267-1277
[89] Bianchini D, Galland G B, Dos Santos J H Z, Williams R J J, Fasce D P, Dell'Erba I E, Quijada R, Perez M. J. Polym. Sci. Part A: Pol. Chem., 2005, 43(22): 5465-5476
[90] García‐Orozco I, Velilla T, Galland G B, Dos Santos J H Z, Williams R J J, Quijada R. J. Polym. Sci. Part A: Pol. Chem., 2010, 48(24): 5938-5944
[91] Yim J H, Ihm S K. J. Appl. Polym. Sci., 2006, 102(3): 2293-2298
[92] Zapata P, Quijada R, Covarrubias C, Moncada E, Retuert J. J. Appl. Polym. Sci., 2009, 113(4): 2368-2377
[93] Chaichana E, Khaubunsongserm S, Praserthdam P, Jongsomjit B. Polym. Bull., 2011, 66(9): 1301-1312
[94] Fink G, Steinmetz B, Zechlin J, Przybyla C, Tesche B. Chem. Rev., 2000, 100(4): 1377
[95] Haag M C, Dupont J, Stedile F C, dos Santos J H Z. J. Mol. Catal. A: Chem., 2003, 197(1-2): 223-232
[96] Hlatky G G. Chem. Rev., 2000, 100(4): 1347-1376
[97] Paavola S, Saarinen T, Lofgren B, Pitkanen P. Polymer, 2004, 45(7): 2099-2110
[98] Tannous K, Soares J B P. Macromol. Chem. Phys., 2002, 203(13): 1895-1905
[99] Franceschini F C, Tavares T T d R, Bianchini D, Alves M d C M, Ferreira M L, dos Santos J H. J. Appl. Polym. Sci., 2009, 112(1): 563-571
[100] Franceschini F C, Tavares T T D, Greco P P, Galland G B, dos Santos J H Z, Soares J B P. J. Appl. Polym. Sci., 2005, 95(5): 1050-1055
[101] Franceschini F C, Tavares T T D, Greco P P, Bianchini D, Stedile F C, Galland G B, dos Santos J H Z, Soares J B P. J. Mol. Catal. A: Chem., 2003, 202(1-2): 127-134
[102] Ochedzan-Siod?ak W, Nowakowska M. Eur. Polym. J., 2005, 41(5): 941-947
[103] Cho H S, Lee W Y. J. Mol. Catal. A: Chem., 2003, 191(2): 155-165
[104] Och?dzan-Siod?ak W, Nowakowska M. Eur. Polym. J., 2004, 40(4): 839-846
[105] Babushkin D E, Panchenko V N, Timofeeva M N, Zakharov V A, Brintzinger H H. Macromol. Chem. Phys., 2008, 209(12): 1210-1219
[106] Prades F, Broyer J P, Belaid I, Boyron O, Miserque O, Spitz R, Boisson C. ACS Catal., 2013, 3: 2288-2293
[107] Kim H G, Lee K S, Hong D S, Song E K, Jeon M S. EP 2623522, 2013
[108] Jiamwijitkul S, Jongsomjit B, Praserthdam P. Iran. Polym. J., 2007, 16(8): 549-559
[109] Campos J M, Ribeiro M R, Lourenço J P, Fernandes A. J. Mol. Catal. A: Chem., 2007, 277(1): 93-101
[110] Campos J M, Lourenço J P, Fernandes A, Ribeiro M R. Catal. Commun., 2008, 10(1): 71-73
[111] Pothirat T, Jongsomjit B, Praserthdam P. Catal. Lett., 2008, 121(3-4): 266-273
[112] Wannaborworn M, Praserthdam P, Jongsomjit B. J. Ind. Eng. Chem., 2011, 18(1): 373-377
[113] Jongsomjit B, Ngamposri S, Praserthdam P. Catal. Lett., 2005, 100(3): 139-146
[114] Chao C R, Pratchayawutthirat W, Praserthdam P, Shiono T, Rempel G L. Macromol. Rapid. Comm., 2002, 23(12): 672-675
[115] Jantasee S, Shiono T, Jongsomjit B. Polym. Bull., 2013, 70(6): 1753-1768
[116] Jongsomjit B, Kaewkrajang P, Praserthdam P. Eur. Polym. J., 2004, 40(12): 2813-2817
[117] Kaivalchatchawal P, Samingprai S, Shiono T, Praserthdam P, Jongsomjit B. Eur. Polym. J., 2012, 48(7): 1304-1312
[118] Alonso C, Antiñolo A, Carrillo-Hermosilla F, Carrión P, Otero A, Sancho J, Villaseñor E. J. Mol. Catal. A: Chem., 2004, 220(2): 286-296
[119] Pannier G, Boisson C, Spitz R. WO 2010127988, 2010
[120] Burkett S L, Soukasene S, Milton K L, Welch R, Little A J, Kasi R M, Coughlin E B. Chem. Mater., 2005, 17(10): 2716-2723
[121] Lee J S, Yim J H, Jeon J K, Ko Y S. Catal. Today, 2012, 185(1): 175-182
[122] Britcher L, Rahiala H, Hakala K, Mikkola P, Rosenholm J B. Chem. Mater., 2004, 16(26): 5713-5720
[123] Liu C B, Tang T, Huang B T. J. Catal., 2004, 221(1): 162-169
[124] Greco P P, Stedile F C, dos Santos J H Z. J. Mol. Catal. A: Chem., 2003, 197(1): 233-243
[125] Atiqullah M, Moman A A, Akhtar M N, Al‐Muallem H A, Abu‐Raqabah A H, Ahmed N. J. Appl. Polym. Sci., 2007, 106(5): 3149-3157
[126] Akhtar M N, Atiqullah M, Moman A A, Abu‐Raqabah A H, Ahmed N. Macromol. React. Eng., 2008, 2(4): 339-349
[127] Turunen J P, Venäläinen T, Suvanto S, Pakkanen T T. J. Polym. Sci. Part A: Pol. Chem., 2007, 45(17): 4002-4012
[128] Velilla T, Delgado K, Quijada R, Bianchini D, Galland G B, Dos Santos J H Z, Fasce D P, Williams R J J. J. Polym. Sci. Part A: Pol. Chem., 2007, 45(23): 5480-5486
[129] Heurtefeu B, Bouilhac C, Cloutet É, Taton D, Deffieux A, Cramail H. Prog. Polym. Sci., 2011, 36(1): 89-126
[130] Zheng X J, Smit M, Chadwick J C, Loos J. Macromolecules, 2005, 38(11): 4673-4678
[131] Simplício L l M T, Costa F G, Boaventura J S, Sales E A, Brandão S T. J. Mol. Catal. A: Chem., 2004, 216(1): 45-50
[132] Makela-Vaarne N I, Nicholson D G, Ramstad A L. J. Mol. Catal. A: Chem., 2003, 200(1-2): 323-332
[133] Jongsomjit B, Kaewkrajang P, Shiono T, Praserthdam P. Ind. Eng. Chem. Res., 2004, 43(24): 7959-7963
[134] Gauthier W, Rauscher D, Tian J, Williams N. US 20110112262, 2011
[135] Bonduel D, Mainil M, Alexandre M, Monteverde F, Dubois P. Chem. Commun., 2005, (6): 781-783
[136] Kaminsky W, Lemstra P J, Loos J, Muller F, Niemantsverdriet J W, Thune P C, Weingarten U. Israel. J. Chem., 2002, 42(4): 367-372
[137] Shin D M, Pham V H, La K W, Song I K, Chung J S. Res. Chem. Intermediat., 2008, 34(8-9): 687-691
[138] Carrero A, Van Grieken R, Suarez I, Paredes B. Polym. Eng. Sci., 2008, 48(3): 606-616
[139] Smit M, Zheng X J, Loos J, Chadwick J C, Koning C E. J. Polym. Sci. Part A: Pol. Chem., 2006, 44(22): 6652-6657
[140] Zapata P A, Quijada R, Lieberwirth I, Benavente R. Macromol. React. Eng., 2011, 5(7-8): 294-302
[141] De Fátima V Marques M, Conte A. J. Appl. Polym. Sci., 2002, 86(8): 2054-2061
[142] Marques M D V, Moreira S C. J. Mol. Catal. A: Chem., 2003, 192(1-2): 93-101
[143] Marques M D V, Beatriz A, Marinha A S. J. Polym. Sci. Part A: Pol. Chem., 2004, 42(12): 3038-3048
[144] Ye Z B, Zhu S P, Wang W J, Alsyouri H, Lin Y S. J. Polym. Sci. Part B: Pol. Phys., 2003, 41(20): 2433-2443
[145] Fisch A G, Cardozo N S M, Secchi A R, Stedile F C, Silveira N P d, Santos J H Z d. J. Non-Cryst. Solids, 2008, 354(33): 3973-3979
[146] Kasi R M, Coughlin E B. Organometallics, 2003, 22(7): 1534-1539
[147] Barrett A G M, de Miguel Y R. Tetrahedron, 2002, 58(19): 3785-3792
[148] Shearer A S, De Miguel Y R, Minich E A, Pochan D, Jenny C. Inorg. Chem. Commun., 2007, 10(3): 262-264
[149] Turunen J P J, Pakkanen T T. J. Mol. Catal. A: Chem., 2007, 263(1–2): 1-8
[150] Bortolussi F, Broyer J P, Spitz R, Boisson C. Macromol. Chem. Phys., 2002, 203(17): 2501-2507
[151] Zhang J, Jin G X. Inorg. Chem. Commun., 2006, 9(7): 683-686
[152] Zhang J, Wang X, Jin G X. Coordin. Chem. Rev., 2006, 250(1): 95-109
[153] Wannaborworn M, Jongsomjit B. Iran. Polym. J., 2009, 18(12): 969-979
[154] Trujillo M, Arnal M L, Müller A J, Laredo E, St. Bredeau, Bonduel D, Dubois P. Macromolecules, 2007, 40(17): 6268-6276
[155] Schlögl M, Riethmueller S, Troll C, Möller M, Rieger B. Macromolecules, 2004, 37(11): 4004-4007
[156] Heurtefeu B, Merna J, Ibarboure E, Cloutet é, Cramail H. Polym. Chem., 2010, 1(7): 1078-1085
[157] Choi Y Y, Lee K S, Lee S W, Chae H, Park C Y, Lee C H, Lee S J. WO 2006080817, 2006
[158] Tullo A H. Chem. Eng. News, 2010, 88(42): 10-16
[159] Yang K F, Huang Y J, Dong J Y. Polymer, 2007, 48(21): 6254-6261
[160] Fim F d C, Guterres J M, Basso N R, Galland G B. J. Polym. Sci. Part A: Pol. Chem., 2010, 48(3): 692-698
[161] Qin Y X, Tang T, Zhao Z F. Chem. Commun., 2004, (2): 222-223
[162] Owpradit W, Jongsomjit B. Mater. Chem. Phys., 2008, 112(3): 954-961
[163] SH A K, Bahuleyan B K, De S, Masihullah J, Sougrat R, Al-Harthi M A. J. Ind. Eng. Chem., 2012, 18(5): 1836-1840
[164] Jongsomjit B, Panpranot J, Okada M, Shiono T, Praserthdam P. Iran. Polym. J., 2006, 15(5): 433-439
[165] Jongsomjit B, Panpranot J, Praserthdam P. Mater. Lett., 2007, 61(6): 1376-1379
[166] Desharun C, Jongsomjit B, Praserthdam P. Catal. Commun., 2008, 9(4): 522-528
[167] Park S, Yoon S W, Choi H, Lee J S, Cho W K, Kim J, Park H J, Yun W S, Choi C H, Do Y. Chem. Mater., 2008, 20(14): 4588-4594
[168] Owpradit W, Mekasuwandumrong O, Panpranot J, Shotipruk A, Jongsomjit B. Polym. Bull., 2011, 66(4): 479-490
[169] Hakim S, Safajou-Jahankhanemlou M, Zeynali M E. J. Polym. Res., 2013, 20(5): 1-10
[170] Huang Y J, Yang K F, Dong J Y. Macromol. Rapid. Comm., 2006, 27(15): 1278-1283
[171] Jongsomjit B, Chaichana E, Praserthdam P. J. Mater. Sci., 2005, 40(8): 2043-2045
[172] Chaichana E, Pathomsap S, Mekasuwandumrong O, Panpranot J, Shotipruk A, Jongsomjit B. Chinese. Sci. Bull., 2012, 57(17): 2177-2184
[173] Kou B, McAuley K B, Hsu C C, Bacon D W, Yao K Z. Ind. Eng. Chem. Res., 2005, 44(8): 2443-2450
[174] Park H W, Chung J S, Baeck S H, Song I K. J. Mol. Catal. A: Chem., 2006, 255(1): 69-73
[175] Chaichana E, Jongsomjit B, Praserthdam P. Chem. Eng. Sci., 2007, 62(3): 899-905
[176] Park H W, La K W, Chung J S, Song I K. Eur. Polym. J., 2007, 43(3): 870-876
[177] Park H W, Chung J S, Lim S S, Song I K. J. Mol. Catal. A: Chem., 2007, 264(1): 202-207
[178] Jongsomjit B, Ngamposri S, Praserthdam P. Molecules, 2005, 10(6): 672-678
[179] Ketloy C, Jongsomjit B, Praserthdam P. Appl. Catal. A: Gen., 2007, 327(2): 270-277
[180] Wongwaiwattanakul P, Jongsomjit B. Catal. Commun., 2008, 10(1): 118-122
[181] Bunchongturakarn S, Jongsomjit B, Praserthdam P. Catal. Commun., 2008, 9(5): 789-795
[182] Guo N, DiBenedetto S A, Kwon D K, Wang L, Russell M T, Lanagan M T, Facchetti A, Marks T J. J. Am. Chem. Soc., 2007, 129(4): 766-767
[183] Wiemann K, Kaminsky W, Gojny F H, Schulte K. Macromol. Chem. Phys., 2005, 206(15): 1472-1478
[184] Bikiaris D. Materials, 2010, 3(4): 2884-2946
[185] Koval’chuk A A, Shchegolikhin A N, Shevchenko V G, Nedorezova P M, Klyamkina A N, Aladyshev A M. Macromolecules, 2008, 41(9): 3149-3156
[186] Koval’chuk A A, Shevchenko V G, Shchegolikhin A N, Nedorezova P M, Klyamkina A N, Aladyshev A M. Macromolecules, 2008, 41(20): 7536-7542
[187] Hwu J M, Jiang G J. J. Appl. Polym. Sci., 2005, 95(5): 1228-1236

 
[1] 宝利军, 危俊吾, 钱杨杨, 王雨佳, 宋文杰, 毕韵梅. 酶响应性线形-树枝状嵌段共聚物的合成、性能及应用[J]. 化学进展, 2022, 34(8): 1723-1733.
[2] 陈晓峰, 王开元, 梁芳铭, 姜睿祺, 孙进. 外泌体递药系统及其在肿瘤治疗中的应用[J]. 化学进展, 2022, 34(4): 773-786.
[3] 刘洋洋, 赵子刚, 孙浩, 孟祥辉, 邵光杰, 王振波. 后处理技术提升燃料电池催化剂稳定性[J]. 化学进展, 2022, 34(4): 973-982.
[4] 杨林颜, 郭宇鹏, 李正甲, 岑洁, 姚楠, 李小年. 钴基费托合成催化剂的表界面性质调控[J]. 化学进展, 2022, 34(10): 2254-2266.
[5] 宋路杰, 吴友平, 邓建平. 手性药物的对映体选择性释放[J]. 化学进展, 2021, 33(9): 1550-1559.
[6] 荆晓东, 孙莹, 于冰, 申有青, 胡浩, 丛海林. 肿瘤微环境响应药物递送系统的设计[J]. 化学进展, 2021, 33(6): 926-941.
[7] 杨强强, 李川, 于淑娴, 范书华, 王月霞, 洪敏. 纳米载体在共负载siRNA及化疗药物对逆转肿瘤多药耐药性方面的应用[J]. 化学进展, 2021, 33(10): 1900-1916.
[8] 官启潇, 郭和泽, 窦红静. 细胞膜修饰的纳米载体与肿瘤免疫治疗[J]. 化学进展, 2021, 33(10): 1823-1840.
[9] 康美荣, 金福祥, 李臻, 宋河远, 陈静. 离子液体固载化及应用研究[J]. 化学进展, 2020, 32(9): 1274-1293.
[10] 张芬铭, 田语舒, 郑绩, 陈堃, 冯岸超, 张立群. 基于PHPMA的生物医用功能高分子[J]. 化学进展, 2020, 32(2/3): 331-343.
[11] 张勇杰, 樊明帅, 李晓佩, 李化毅, 王书唯, 祝文亲. 含硅功能化聚烯烃:合成及应用[J]. 化学进展, 2020, 32(1): 84-92.
[12] 王惠亚, 赵立敏, 张芳, 何丹农. 高性能锂离子二次电池隔膜[J]. 化学进展, 2019, 31(9): 1251-1262.
[13] 曲树璋, 张韬毅, 王伟. 氮配位单茂金属烯烃聚合催化剂[J]. 化学进展, 2019, 31(7): 929-938.
[14] 英启炜, 廖建国, 吴民行, 翟智皓, 刘欣茹. 球形生物活性玻璃作为运输载体的研究[J]. 化学进展, 2019, 31(5): 773-782.
[15] 白凌闯, 赵静, 冯亚凯. 多功能基因递送系统促进内皮细胞增殖[J]. 化学进展, 2019, 31(2/3): 300-310.
阅读次数
全文


摘要

茂金属催化剂的负载化