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化学进展 2014, Vol. 26 Issue (04): 560-571 DOI: 10.7536/PC130923 前一篇   后一篇

• 综述与评论 •

石墨烯及其聚合物纳米复合材料

张力1, 吴俊涛*1, 江雷1,2   

  1. 1. 北京航空航天大学化学与环境学院 仿生智能界面科学与技术教育部重点实验室 北京 100191;
    2. 中国科学院化学研究所 北京 100190
  • 收稿日期:2013-09-01 修回日期:2013-11-01 出版日期:2014-04-15 发布日期:2014-01-20
  • 通讯作者: 吴俊涛，e-mail：wjt@buaa.edu.cn E-mail:wjt@buaa.edu.cn
  • 基金资助:

    国家自然科学基金项目（No.51003004，51373007）、北京市自然科学基金项目（No.2142019）、国家重点基础研究发展计划（973）项目（No. 2010CB934700，2012CB933200）及中央高校基本科研业务费专项资金和教育部留学回国人员科研启动基金资助

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Graphene and Its Polymer Nanocomposites

Zhang Li1, Wu Juntao*1, Jiang Lei1,2   

  1. 1. Key Laboratory of Bio-Inspired Smart Interfacial Science and Technology of Ministry of Education, College of Chemistry and Environment, Beihang University, Beijing 100191, China;
    2. Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
  • Received:2013-09-01 Revised:2013-11-01 Online:2014-04-15 Published:2014-01-20
  • Supported by:

    The work was supported by the National Natural Science Foundation of China (No. 51003004, 51373007), the Beijing Natural Science Foundation (No.2142019), the National Basic Research Program of China (No. 2010CB934700, 2012CB933200), the Fundamental Research Funds for the Central Universities, and the SRF for ROCS, SEM

石墨烯是一种新型的二维纳米碳材料，具有优异的机械性能、电性能和热性能等，是聚合物纳米复合材料的理想填料。近年来，石墨烯/聚合物纳米复合材料成为聚合物基纳米复合材料的研究热点。本文对石墨烯及其聚合物纳米复合材料的研究进展进行了综述。首先概述了石墨烯的不同制备方法及石墨烯的共价与非共价改性途径。然后重点总结了石墨烯/聚合物纳米复合材料的常用制备方法及其机械性能、导电性、导热性、耐热性及阻隔性能。最后，对该领域所存在的问题进行了总结，并展望了其发展趋势。

关键词： 石墨烯, 聚合物, 纳米复合材料

Graphene is a new nanomaterial with strict two-dimensional layers structure. With excellent mechanical, high electrical and thermal properties, graphene is the ideal filler for polymer-based nanocomposites. Graphene/polymer nanocomposites greatly draw researchers’ attentions in recent years. In this review, we presented and discussed the current development of graphene/polymer nanocomposites. After introducing various methods to synthesize graphene, covalent and noncovalent functionalization of graphene are briefly summarized. Particular emphasis is placed on general methods used to fabricate graphene/polymer nanocomposites and mechanical, electrical, thermal, and gas barrier properties of graphene/polymer nanocomposites. Finally, the challenge of this research area was summarized and its future outlook was prospected.

Contents
1 Introduction
2 Synthesis methods and surface modification of graphene
2.1 Synthesis methods of grapheme
2.2 Surface modification of graphene
3 Graphene-based polymer nanocomposites
3.1 Fabrication approaches to graphene-based polymer nanocomposites
3.2 Properties of graphene-based polymer nano-composites
4 Conclusions and application outlook

Key words: graphene, polymer, nanocomposite

中图分类号: 

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摘要

石墨烯及其聚合物纳米复合材料