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化学进展 2014, Vol. 26 Issue (0203): 293-302 DOI: 10.7536/PC130806 前一篇   后一篇

• 综述与评论 •

非线性光学晶体LiBX2（B=Ga, In; X=S, Se, Te）的研究

孙亮*1, 杨春晖*2, 马天慧3, 朱崇强2   

  1. 1. 宜宾学院物理与电子工程学院 宜宾 644000;
    2. 哈尔滨工业大学化工学院 哈尔滨 150001;
    3. 黑龙江工程学院材料与化学工程学院 哈尔滨 150001
  • 收稿日期:2013-08-01 修回日期:2013-09-01 出版日期:2014-02-15 发布日期:2013-12-18
  • 通讯作者: 孙亮，e-mail：liangsunchina@126.com；杨春晖，e-mail：yangchh@hit.edu.cn E-mail:liangsunchina@126.com；yangchh@hit.edu.cn
  • 基金资助:

    国家自然科学基金项目（No. 50902027，51102061）和黑龙江省教育厅青年学术骨干项目（No.1252G061）资助

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Nonlinear Optical Crystals LiBX2(B=Ga, In; X=S, Se, Te)

Sun Liang*1, Yang Chunhui*2, Ma Tianhui3, Zhu Chongqiang2   

  1. 1. School of Physics and Electronic Engineering, Yibin University, Yibin 644000, China;
    2. School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin 150001, China;
    3. College of Materials and Chemical Engineering, Heilongjiang Institute of Technology, Harbin 150001, China
  • Received:2013-08-01 Revised:2013-09-01 Online:2014-02-15 Published:2013-12-18
  • Supported by:

    The work was supported by the National Natural Science Fundation of China (No. 50902027, 51102061) and the Education Department Youth Scholar Fundation of Heilongjiang Province(No.1252G061)

LiBX2（B=Ga，In；X=S，Se，Te）晶体具有宽的透光波段、足够大的双折射率、高的激光损伤阈值和小的双光子吸收系数等特性，是目前最具发展前景的中红外波段频率转换材料之一。本文从晶体结构入手，重点介绍了LiBX2晶体的光学性能、缺陷结构及晶体应用的最新研究成果。LiBX2晶体在二次谐波（SHG）相位匹配、差频产生（DFG）、光学参量放大（OPA）和光学参量振荡（OPO）等方面具有重要的应用前景。通过对晶体的透过光谱、吸收光谱、光致发光光谱和电子辐照的研究可以确定缺陷类型、缺陷浓度及最佳退火温度，分析晶体颜色与晶体组成和缺陷的关系。最后，提出LiBX2晶体今后应重点开展的研究方向，即获得更高光学质量的大尺寸晶体、降低晶体残余吸收和设计性能优良的抗反射膜（AR）。

关键词： 非线性光学材料, 光学性质, 点缺陷, 锂化合物, 光学参量放大

LiBX2(B=Ga, In; X=S, Se,Te) crystal is one of the most promising frequency converters materials for IR due to extended transparency range, sufficiently large birefringence, high laser induced damage thresholds and small two-photon absorption coefficient. This article focuses on the optical properties, defect structures and applications of these crystals reported in the past few years. The promising applications on the phase-matched second harmonic generation (SHG), continuous-wave (cw) difference-frequency generation (DFG), optical parametric amplifier (OPA) and optical parametric oscillator (OPO) are summarized. The major native defects, defect concentration and optimal annealing temperature can be indicated by the transmission, absorption and photoluminescence (PL) spectra and irradiation with fast electrons. The relationship between color and composition and crystal defects is analyzed. Finally, the trends in the investigation on crystal growth, reduction of the residual losses and optimization of the antireflection (AR)-coating process are prospected.

Contents
1 Introduction
2 Structural characteristics
3 Polycrystalline synthesis and crystal growth
4 Optical properties and defect structures
4.1 LiInS2 crystal
4.2 LiInSe2 crystal
4.3 LiGaS2 crystal
4.4 LiGaTe2 and LiGaSe2 crystal
5 Crystal applications
6 Conclusions and Outlook

Key words: nonlinear optical materials, optical properties, point defects, lithium compounds, optical parametric oscillator(OPO)

中图分类号: 

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