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化学进展 2014, Vol. 26 Issue (01): 75-86 DOI: 10.7536/PC130647 前一篇   后一篇

• 综述与评论 •

介晶的制备、性能与应用研究

卜凡兴, 都晨杰, 姜继森*   

  1. 华东师范大学物理系 纳米功能材料与器件应用研究中心 上海 200241
  • 收稿日期:2013-06-01 修回日期:2013-09-01 出版日期:2014-01-15 发布日期:2013-11-08
  • 通讯作者: 姜继森，e-mail：jsjiang@phy.ecnu.edu.cn E-mail:jsjiang@phy.ecnu.edu.cn
  • 基金资助:

    国家自然科学基金项目（No. 21173084）资助

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导出 被引次数 ( 3 | 2 )

Synthesis, Properties and Applications of Mesocrystals

Bu Fanxing, Du Chenjie, Jiang Jisen*   

  1. Department of Physics, Center for Functional Nanomaterials and Devices, East China Normal University, Shanghai 200241, China
  • Received:2013-06-01 Revised:2013-09-01 Online:2014-01-15 Published:2013-11-08
  • Supported by:

    The work was supported by the National Natural Science Foundation of China (No. 21173084)

介晶（mesocrystal）是一类由纳米晶以结晶学有序的方式自组装而成的纳米粒子超结构，通常可以显示类单晶的电子衍射行为。介晶形成过程对经典结晶的挑战及其颗粒聚集体的独特结构特色具有的潜在应用促使人们对其广泛的研究。本文主要综述了介晶的制备方法、性能和应用研究的最新进展，其中合成方法主要包括共沉淀法、水热法、溶剂热法、拓扑转变法、电化学法和溶解再结晶方法，性能和应用方面主要介绍了介晶的催化性能、电化学性能、光电性能和生物医学应用。本文着重讨论了介晶的形成过程和介晶的结构-性能关系，指出了目前介晶的制备、性能和应用研究中存在的科学问题，并展望了其发展方向。

关键词： 介晶, 自组装, 超结构, 集合性能

Mesocrystals are one kind of self-assembled superstructures from nanocrystals in crystallographic ordered way, often showing single-crystal-like electron diffraction behaviors. The formation process of mesocrystals imposes a great challenge to classic crystallization theory and their unique structural features of nanocrystals aggregations may create enhanced and new properties, which drive researchers to make extensive studies. This paper reviews the latest progress in the preparation methods, properties and applications of mesocrystals. The synthesis methods of mesocrystals mainly include coprecipitation, hydrothermal, solvothermal, topological conversion, electrochemical, dissolution and recrystallization methods. And catalytic, electrochemical, optical and electrical properties as well as biomedical applications of mesocrystals are exhibited. The formation process and structure-property relationships of mesocrystals are emphasized. Besides, some scientific issues about the preparations, properties and applications of mesocrystals are pointed out, and the outlook of further development in the field of mesocrystals is also given.

Contents
1 Introduction
2 Synthesis of mesocrystals
2.1 Coprecipitation methods
2.2 Hydrothermal methods
2.3 Solvothermal methods
2.4 Topological conversion methods
2.5 Electrochemical methods
2.6 Dissolution and recrystallization methods
3 Properties and applications of mesocrystals
3.1 Catalytic properties
3.2 Electrochemical properties
3.3 Optical and electrical properties
3.4 Biomedical applications
4 Conclusion and outlook

Key words: mesocrystals, self-assembly, superstructures, collective properties

中图分类号: 

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摘要

介晶的制备、性能与应用研究