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化学进展 2014, Vol. 26 Issue (0203): 277-292 DOI: 10.7536/PC130646 前一篇   后一篇

• 综述与评论 •

卟啉金属有机骨架材料的合成及其在催化反应

庄长福1,2,4, 刘建路2, 戴文1,3, 吴中平2, 王瑛4, 高爽*1   

  1. 1. 中国科学院大连化学物理研究所 大连 116023;
    2. 山东海化集团有限公司 潍坊 262737;
    3. 中国科学院大学 北京 100039;
    4. 西南林业大学材料工程学院 昆明 650224
  • 收稿日期:2013-06-01 修回日期:2013-10-01 出版日期:2014-02-15 发布日期:2013-12-18
  • 通讯作者: 高爽，e-mail：sgao@dicp.ac.cn E-mail:sgao@dicp.ac.cn
  • 基金资助:

    国家重点基础研究发展计划（973）项目（No.2009CB623505）、国家自然科学基金项目（No.21273225）和中国博士后科学基金项目（No.2013M541257）资助

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Synthesis and Applications in Catalysis of Porphyrinic Metal-Organic Frameworks

Zhuang Changfu1,2,4, Liu Jianlu2, Dai Wen1,3, Wu Zhongping2, Wang Ying4, Gao Shuang*1   

  1. 1. Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China;
    2. Shandong Haihua Group Corporation Ltd., Weifang 262737, China;
    3. University of the Chinese Academy of Sciences, Beijing 100039, China;
    4. Faculty of Materials Engineering, Southwest Forestry University, Kunming 650224, China
  • Received:2013-06-01 Revised:2013-10-01 Online:2014-02-15 Published:2013-12-18
  • Supported by:

    This work was supported by the State Key Development Program for Basic Research of China (No.2009CB623505), the National Natural Science Foundation of China (No.21273225), and the China Postdoctoral Science Foundation (No.2013M541257)

金属有机骨架（metal-organic frameworks，MOFs）材料不仅具有非常高的孔隙率和表面积，而且其骨架结构可调控性强，容易实现功能化。功能性MOFs材料是近年发展起来的均相催化剂多相化的有效方法之一。均相催化剂金属卟啉具有很好的催化活性，卟啉构建功能性MOFs材料主要通过两种方式：一种是卟啉作为有机构筑模块制备MOFs材料，另一种是将金属卟啉封装到MOFs内部。卟啉MOFs材料因集合了MOFs的微观结构可调控性和仿酶催化剂金属卟啉的特殊催化活性而引起广泛关注。本文介绍了卟啉MOFs材料的设计合成策略及近年来卟啉MOFs材料在催化领域中的应用，并对其催化应用趋势作了展望，以期对卟啉MOFs材料的设计合成及其催化性能有比较全面的认识。

关键词： 卟啉, 金属有机骨架, 非均相催化, 合成

Heterogeneous catalysis is one of the promising applications for metal-organic frameworks (MOFs) materials because of their high porosity, large surface areas and their flexible tailoring. An attractive approach to design MOFs-based catalysts is to heterogenize them by employing known homogeneous molecular catalysts as struts. In view of the enormous utility as active sites in metallo-enzymes, metalloporphyrin is obvious candidates for incorporation into MOFs as catalytically functional struts. Many efficient strategies have been established for the rational design and synthesis of catalytically functional porphyrinic MOFs. This review is aimed to summarize recent progress on porphyrinic MOFs, including new synthesis strategies and applications in catalysis. The development trends of porphyrinic MOFs are also prospected.

Contents
1 Introduction
2 Synthesis strategies for porphyrinic MOFs
2.1 Utility of extendable porphyrinic ligands in generating secondary building units (SBUs)
2.2 Using specially designed spacers to stabilize secondary building units (SBUs)
2.3 Combination of mixed-ligands
2.4 Template-directed synthesis
3 Heterogeneous catalytic performances of porphyrinic MOFs
3.1 MOFs-based catalysts constructed by porphyrinic ligands
3.2 Catalytic reactions of MOFs-encapsulated porphyrinic catalysts
4 Conclusions and outlook

Key words: porphyrin, metal-organic frameworks, heterogeneous catalysis, synthesis

中图分类号: 

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