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化学进展 2014, Vol. 26 Issue (01): 87-99 DOI: 10.7536/PC130638 前一篇   后一篇

• 综述与评论 •

磷酸锆及其衍生物的制备与应用

周贵凤1, 王勤1, 曾仁权*1,2, 傅相锴2, 杨新斌1   

  1. 1. 西南大学荣昌校区 重庆 402460;
    2. 西南大学化学化工学院 重庆 400715
  • 收稿日期:2013-06-01 修回日期:2013-09-01 出版日期:2014-01-15 发布日期:2013-11-08
  • 通讯作者: 曾仁权，e-mail：zrq313@163.com E-mail:zrq313@163.com
  • 基金资助:

    国家自然科学基金项目（No.21172182）；重庆市自然科学基金项目（No.CSTC2009BB5300）和西南大学博士基金项目（No.08BSr01）资助

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Preparation and Application of Zirconium Phosphate and Its Derivatives

Zhou Guifeng1, Wang Qin1, Zeng Renquan*1,2, Fu Xiangkai2, Yang Xinbin1   

  1. 1. Rongchang Campus, Southwest University, Chongqing 402460, China;
    2. School of Chemistry and Chemical Engineering, Southwest University, Chongqing 400715, China
  • Received:2013-06-01 Revised:2013-09-01 Online:2014-01-15 Published:2013-11-08
  • Supported by:

    The work was supported by the National Natural Science Foundation of China (No. 21172182), the Natural Science Foundation Project CQ CSTC (No. 2009BB5300) and the Doctoral Programme of Southwest University (No. 08BSr01)

磷酸锆类物质热稳定性、化学稳定性较高，耐酸碱性较强，广泛应用于离子交换、插层、催化及吸附等领域。本文综述了磷酸锆及其衍生物的回流法、溶胶-凝胶法、沉淀法、水热、溶剂热和薄膜化等制备方法，介绍了其在环境、安全、电学、光学、生物医药领域中的应用，最后展望了在储氢材料、生物纳米复合材料的研究前景。

关键词： 磷酸锆及其衍生物, 制备, 环境及安全, 电学, 光学, 生物医药

Zirconium phosphates have been extensively applied in the fields of ion exchange, intercalation, catalysis and adsorption due to the high thermal and chemical stability, strongly acid and alkali resistance. Preparation of zirconium phosphate and its derivatives are discussed by reflux, sol-gel, precipitation, hydrothermal and solvothermal methods. Zirconium phosphate films and other applications in the fields of environment-safety, electrics, optics, biomedicine and hydrogen storage are also reviewed in the article.

Contents
1 Introduction
2 Preparation of zirconium phosphate and its derivatives
2.1 Reflux method
2.2 Sol-gel method
2.3 Precipitation method
2.4 Hydrothermal and solvothermal methods
2.5 Other methods
3 Application of zirconium phosphate and its derivatives
3.1 Environment-safety
3.2 Electrics
3.3 Optics
3.4 Biomedicine
4 Outlook

Key words: zirconium phosphate and its derivatives, preparation, environment-safety, electrics, optics, biomedicine

中图分类号: 

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磷酸锆及其衍生物的制备与应用