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化学进展 2013, Vol. 25 Issue (11): 1805-1820 DOI: 10.7536/PC130329 前一篇   后一篇

• 综述与评论 •

压致变色聚集诱导发光材料

彭邦银, 许适当, 池振国*, 张锡奇, 张艺, 许家瑞*   

  1. 中山大学化学与化学工程学院 光电材料与技术国家重点实验室 聚合物复合材料及功能材料教育部重点实验室 广州 510275
  • 收稿日期:2013-03-01 修回日期:2013-06-01 出版日期:2013-11-15 发布日期:2013-09-12
  • 通讯作者: 池振国, 许家瑞 E-mail:chizhg@mail.sysu.edu.cn;xjr@mail.sysu.edu.cn
  • 基金资助:

    国家自然科学基金项目(No. 51173210, 51073177)资助

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导出 被引次数 ( 23 | 3 )

Piezochromic Aggregation-Induced Emission Materials

Peng Bangyin, Xu Shidang, Chi Zhenguo*, Zhang Xiqi, Zhang Yi, Xu Jiarui*   

  1. Key Laboratory for Polymeric Composite and Functional Materials of Ministry of Education, State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-sen University, Guangzhou 510275, China
  • Received:2013-03-01 Revised:2013-06-01 Online:2013-11-15 Published:2013-09-12

压致发光变色材料是在外力作用下,发光颜色发生明显改变的一类智能材料,包括压致荧光变色材料和压致磷光变色材料。压致发光变色材料在应力传感、信息存储、商品防伪和发光器件等领域具有重要的潜在应用前景,近年来,受到了人们极大的关注。但是,已经报道的压致发光变色材料非常稀少。可能的原因有两个,一是没有分子结构与压致发光变色性能关系的规律来指导压致发光变色化合物的合成;二是一般的发光化合物由于具有聚集发光猝灭效应导致在固体状态下很难观察到压致发光变色现象。直到近两年我们发现聚集诱导发光化合物与压致发光变色化合物之间具有结构上的关联性并提出压致变色聚集诱导发光材料的概念之后,许多压致变色聚集诱导发光材料被陆续报道。聚集诱导发光材料成为压致发光变色材料一个非常重要的来源。本文总结了近年来关于压致变色聚集诱导发光材料的研究进展情况,对聚集诱导发光材料的压致变色机理、结构与性能关系以及潜在的应用进行了阐述。

关键词： 压致发光变色, 聚集诱导发光, 分子堆砌

Piezochromic (machanochromic) luminescent materials are a class of "smart" materials with luminescent properties that change in response to external force stimuli. These materials are widely used in many fields such as mechanosensors, memory chips, security inks and optoelectronic devices, and have attracted considerable interest in recent years. However, the piezochromic luminescent materials that are dependent on changes in physical molecular packing modes are extremely rare. This rarity may be attributed to two major issues. First, a common method for piezochromic luminescent compound synthesis is not to be realized. Each identified compound is an isolated event, rendering difficulty in the identification of a general characteristic. Second, the fluorescence efficiency of organic luminescent materials often becomes very weak while in solid state because of the aggregation-caused quenching effect. Consequently, the piezochromic luminescent phenomenon becomes difficult to observe. Until the last two years, we recognized the existence of a structural relationship between the aggregation-induced emission compound and the piezochromic luminescent nature, and put forward the concept of "piezochromic aggregation-induced emission materials", many piezochromic aggregation-induced emission materials have been reported one after another. Aggregation-induced emission compounds can be expected to become an important source of piezochromic luminescent materials, and in other words piezochromic luminescent materials would no longer be rare in the future. In this review, recent progress in the area of piezochromic aggregation-induced emission materials is summarized, and majority of the reported piezochromic aggregation-induced emission systems are discussed, including concept, mechanism, structure-property relationship, application, and so on.

Contents
1 Introduction
2 Piezochromic aggregation-induced emission (PAIE) concept and mechanism
3 Relationship between crystallinity and piezo-chromism
4 Relationship between alkyl (alkoxy) length and piezochromism
5 PAIE metal complexes
6 PAIE ionic compound
7 Applications of PAIE materials
7.1 Stress sensors
7.2 Anti-counterfeiting
7.3 Optical data recording and storage
7.4 Ink-free environment-friendly paper
7.5 Luminescent device
7.6 Other sensors
8 Conclusion and outlook

Key words: piezochromic luminescence, aggregation-induced emission, molecular packing

中图分类号: 

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压致变色聚集诱导发光材料