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化学进展 2013, Vol. 25 Issue (10): 1795-1804 DOI: 10.7536/PC130201 前一篇   

• 综述与评论 •

支撑型离子液体膜的制备、表征及稳定性评价

刘一凡, 马玉玲, 徐琴琴, 银建中   

  1. 大连理工大学化工机械学院 大连116024
  • 收稿日期:2013-02-01 修回日期:2013-04-01 出版日期:2013-11-12 发布日期:2013-07-18
  • 通讯作者: 银建中 E-mail:jzyin@dlut.edu.cn
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Supported Ionic Liquid Membrane: Preparation, Characterization and Stability

Liu Yifan, Ma Yuling, Xu Qinqin, Yin Jianzhong   

  1. School of Chemical Machinery, Dalian University of Technology, Dalian 116024, China
  • Received:2013-02-01 Revised:2013-04-01 Online:2013-11-12 Published:2013-07-18

支撑型离子液体膜是将离子液体负载于基膜孔道内形成的复合型液体膜。它同时具备了离子液体优良的溶剂特性以及膜分离高效率的优势,加之分离过程简单、经济性好,成为研究CO2捕捉的热点课题。将这种膜分离技术用于天然气和烟道气脱硫脱碳,关键取决于膜的稳定性和质量。优质基膜、功能化离子液体以及科学的制备方法是保证支撑型离子液体膜性能的重要因素。首先,本文总结了已发展的各种制备支撑型离子液体膜的方法、主要表征手段,分析比较了其优缺点。其次,对于影响其稳定性和使用寿命的主要因素进行了分析评价。在此基础上,指出了控制膜质量需要重视的关键科学问题和今后应该重点发展的研究方向,旨在推动该技术的应用基础研究和工业化开发。

关键词： 离子液体, 支撑型液膜, 二氧化碳捕捉, 制备工艺, 稳定性

Supported ionic liquid membrane(SILM) is a kind of composite membrane, which is prepared by immobilizing ionic liquids(ILs) into the porous membrane. It combines the excellent solvent properties of ILs and high efficiency of membrane separation, and also has the advantages of simplified separation processes and economical operating cost, which all make SILM become one of the academic focal points of CO2 capture. It depends on the stability and quality of SILM for applying this kind of membrane separation in desulfuration and decarbonization of natural gases and flue gases. High-quality porous membranes, task-specific ILs and scientific preparation methods are of importance in guaranteeing the performances of SILMs. Preparation methods and typical characterization methods of SILMs are summarized in this work, So are the relative merits of different preparation methods. In addition, the factors affecting the stability and life time of SILM are analyzed and evaluated. On the basis of the comments above, the key scientific problems of SILM-quality control and future research direction for further development are proposed, for the purpose of promoting the basic studies of SILM technologies to guide industrialized applications and development.

Contents
1 Introduction
2 Preparation methods of SILM and their features
2.1 Conventional preparation methods of SILM
2.2 Preparation of SILM by reducing viscosity
2.3 Novel ionic liquid membrane and their preparation
3 Characterization methods of SILM
4 Stability and uniformity of SILM
4.1 Stability
4.2 Uniformity
5 Conclusion and outlook

 

Key words: ionic liquid, supported liquid membrane, carbon dioxide capture, preparation, stability

中图分类号: 

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