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化学进展 DOI: 10.7536/PC121241 前一篇   后一篇

• 综述与评论 •

1,8-位修饰杂芴类有机光电功能材料的合成与应用

曹锦珠1, 王志祥1, 陈润锋*1,2, 李欢欢1, 郑超1, 黄维*2   

  1. 1. 南京邮电大学信息材料与纳米技术研究院 有机电子与信息显示国家 重点实验室培育基地 南京 210023;
    2. 南京工业大学 江苏-新加坡有机 电子与信息显示联合实验室 南京 211816
  • 收稿日期:2012-12-01 修回日期:2013-03-01 出版日期:2013-08-25 发布日期:2013-06-13
  • 通讯作者: 陈润锋,黄维 E-mail:iamrfchen@njupt.edu.cn;wei-huang@njupt.edu.cn
  • 基金资助:

    国家重点基础研究发展计划(973)项目(No.2009CB930601);国家自然科学基金项目(No.20804020,21274065);江苏省自然科学基金项目(No.BK2011751)和南京邮电大学攀登计划(NY210017)资助

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Synthesis and Applications of 1,8-Functionalized Heterofluorenes for Organic Electronics

Cao Jinzhu1, Wang Zhixiang1, Chen Runfeng*1,2, Li Huanhuan1, Zheng Chao1, Huang Wei*2   

  1. 1. Key Laboratory for Organic Electronics & Information Displays and Institute of Advanced Materials, Nanjing University of Posts & Telecommunications, Nanjing 210023, China;
    2. Jiangsu-Singapore Joint Research Center for Organic/Bio- Electronics & Information Displays and Institute of Advanced Materials, Nanjing University of Technology, Nanjing 211816, China
  • Received:2012-12-01 Revised:2013-03-01 Online:2013-08-25 Published:2013-06-13

以氧、硫、硅、氮、磷等杂原子取代芴中sp3杂化的碳原子所形成的杂芴,不仅可以通过杂原子和π共轭体系间的相互作用有效地调控材料的电子结构,而且可以影响芴不同位置的修饰,从而得到了广泛关注。本文详细分析了1,8-位修饰杂芴的分子结构特点和光电特性,根据不同的杂原子分类论述了相关材料的合成方法和原理,综述了1,8-位修饰杂芴类材料在磷光主体材料、电致发光材料、太阳能电池材料以及有机配体材料等方面的应用进展,展望了其在有机光电材料方面的应用前景和发展趋势。

关键词： 芴, 杂芴, 1,8-位修饰, 合成, 有机光电功能材料

Heterofluorenes, achieved by substituting the sp3-hybridized carbon of fluorene with oxygen, sulfur, silicon, nitrogen, phosphor etc., are a series of very interesting optoelectronic materials. They have not only many highly effective ways to modify the electronic structures and properties through the particular interactions between the heteroatom and the π-conjugated system, but also show different modification properties at different substitution positions due to the influence of the heteroatoms. 1,8-Functionalization inspires new properties from widely used materials although the synthesis is always difficult. Owing to the wide spread progress of heterofluorenes and the 1,8-functionalization strategy, 1,8-functionalized heterofluorenes have received increasing attention in organic optical and electronic materials and devices recently. Herein, we summarized the basic principles of the molecular design, material synthesis, structure-property relations, and optoelectronic device applications of 1,8-functionalized heterofluorenes. The different synthetic methods of various 1,8-functionalized heterofluorenes are reviewed and presented according to different effects of different heteroatoms. Besides, the applications of 1,8-functionalized heterofluorenes as host materials for phosphorescent organic light emitting diodes, as electroluminescent materials for organic light emitting diodes, as photovoltaic materials for solar cells, and as functional ligands for organic metals are discussed in detail. Finally, the existing key problems and the future development of 1,8-functionalized heterofluorenes are also outlined and suggested. Contents
1 Introduction
2 Synthesis of 1,8-functionalized heterofluorenes
2.1 Direct synthetic methods
2.2 Indirect synthetic methods
3 Applications of 1,8-functionalized heterofluorenes
3.1 Organic electroluminescent materials
3.2 Photovoltaic materials
3.3 Ligands
4 Conclusion and outlook

Key words: fluorene, heterofluorene, 1,8-functionalization, synthesis, organic optoelectronic materials

中图分类号: 

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