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化学进展 DOI: 10.7536/PC121223 前一篇   后一篇

• 综述与评论 •

室温铝二次电池及其关键材料

王华丽, 白莹*, 陈实, 吴锋, 吴川*   

  1. 北京理工大学化工与环境学院 环境科学与工程北京市重点实验室 北京 100081
  • 收稿日期:2012-12-01 修回日期:2013-01-01 出版日期:2013-08-25 发布日期:2013-06-13
  • 通讯作者: 白莹,吴川 E-mail:membrane@bit.edu.cn;chuanwu@bit.edu.cn
  • 基金资助:

    国家重点基础研究发展计划(973)项目(No.2009CB220100)和教育部“新世纪优秀人才支持计划”项目(No.NCET-12-0047)资助

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Ambient Temperature Rechargeable Aluminum Batteries and Their Key Materials

Wang Huali, Bai Ying*, Chen Shi, Wu Feng, Wu Chuan*   

  1. Beijing Key Laboratory of Environmental Science and Engineering, School of Chemical Engineering and the Environment, Beijing Institute of Technology, Beijing 100081, China
  • Received:2012-12-01 Revised:2013-01-01 Online:2013-08-25 Published:2013-06-13

金属铝是一种很高的能量载体, 是开发电池的理想电极材料。由于铝在二次电池中的应用体系主要集中在高温熔盐铝二次电池,其熔盐电解质需要高温,对环境要求苛刻,成本较高难于维护,限制了铝二次电池的发展。近年来,室温离子液体作为二次电池的电解液的研究,使得室温铝二次电池的开发与应用成为可能,人们开始研究基于离子液体电解液的室温有机熔盐二次电池,采用铝或者嵌铝化合物作为电极材料,离子液体作为电解液,与传统的二次电池相比具有很多优点。本文介绍了近年来室温铝二次电池相关的研究和应用新进展,包括金属铝负极的优化和铝枝晶的抑制,可嵌脱铝负极材料的设计,可用于铝二次电池的过渡金属氧化物和导电聚合物正极材料及其性能,以及电解液的要求和离子液体作电解液的优势,并指出了可能存在的问题以及相应的解决办法。

关键词： 铝二次电池, 离子液体电解液, 铝负极, 过渡金属氧化物正极

Aluminum is a high energy carrier and an ideal electrode material for batteries. At present, the application of aluminum in rechargeable batteries are mainly high temperature molten salt batteries, all these rechargeable aluminum batteries use molten salt electrolyte, which must work at high temperature. The use of high temperature molten salt electrolyte limited the development of rechargeable aluminum batteries. Recently, researchers begin to use ambient temperature ionic liquids as electrolyte of rechargeable aluminum batteries, which can prevent the formation of oxide films on the aluminum surface as well as eliminate H2 evolution. This new battery system working at mild condition, which adopts aluminum or aluminum intercalation compounds as electrodes and ionic liquids as electrolytes, has many advantages compared to conventional rechargeable batteries. This paper introduces related researches and applications of ambient temperature rechargeable aluminum batteries in recent years, including the optimizing of aluminum anode and inhibition of dendrite, the design of aluminum anode materials that can intercalate and release aluminum ion, the performance of polymer cathode materials and transition metal oxide cathode materials, the request of electrolytes, and advantages of ionic liquid used as electrolyte. Furthermore, possible existent problems and corresponding solutions are proposed. Contents
1 Introduction
2 Optimize and design of anode material in ambient temperature rechargeable aluminum batteries
2.1 Activation and anti-corroding of the aluminum anode
2.2 Dendrite formation and inhibition
2.3 Aluminum anode materials that can intercalate and deintercalate aluminum ion
3 Electrolyte for ambient temperature rechargeable aluminum batteries
3.1 The request of electrolytes
3.2 The advantages of ionic liquids used as electrolyte
3.3 The application of ionic liquids
4 Cathode materials used in ambient temperature rechargeable aluminum batteries
4.1 Polymer cathode materials
4.2 Transition metal oxide cathode materials
5 Conclusion

Key words: rechargeable aluminum batteries, ionic liquid electrolyte, aluminum anode, transition metal oxide cathode

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[1] 李庆峰(Li Q F), 邱竹贤(Qiu Z X). 东北大学学报: 自然科学版(Journal of Northeastern University (Natural Science Edition)), 2001, 22(2): 130-132
[2] 王兆文(Wang Z W), 李延祥(Li Y X), 李庆峰(Li Q F), 高炳亮(Gao B L), 邱竹贤(Qiu Z X). 有色金属(Non-Ferrous Metal), 2002, 54 (1): 19-23
[3] Hulot M. Compt. Rend., 1855, 40: 148-152
[4] Sargent D E. US 2554447, 1951
[5] Zaromb S. J. Electrochem. Soc., 1962, 109: 1125-1137
[6] Trevethan L, Bockstie D, Zaromb S. J. Electrochem. Soc., 1963, 110: 267-271
[7] Miller S E. 国外舰船技术(船电类)(Foreign Ship Technology (Marine Electric Class)), 1980, 4: 39-40
[8] Giner J, Holleck G. Aluminum-Chlorine Battery. Final Report by Tyco Laboratories Inc., On contract No. NAS 12-688, March 1970 (NASA-CR-1541)
[9] Knutz B C, Hjuler H A, Berg R W. J. Electrochem. Soc., 1993, 140(12): 3380-3390
[10] Takami N, Koura N. J. Electrochem. Soc., 1989, 136: 730-740
[11] Gifford P R, Palmisano J B. J. Electrochem. Soc., 1988, 135: 650-654
[12] Gifford P R, Palmisano J B. J. Electrochem. Soc., 1987, 134: 610-614
[13] 李庆峰(Li Q F), 邱竹贤(Qiu Z X). 有色矿冶(Non-Ferrous Mining and Metallurgy), 1994, 2: 25-31
[14] 陈建华(Chen J H). 表面技术(Surface Technology), 1994, 23(4): 159-165
[15] Hasvold O, Johnsen K H, Mollestad O. J. Power Sources, 1999, 80: 254-260
[16] Anderson G E, Middletown R I. US 3953239, 1976
[17] Hunter J A, Scamans G M, O'Callaghan W B. US 4942100, 1990
[18] Hunter J A, Hamlen R P. US 5376471, 1994
[19] 蔡年生(Cai N S). 舰船科学技术(Ship Science and Technology), 2003, 25(1): 58-62
[20] 奚碚华(Xi P H), 夏天(Xia T). 鱼雷技术(Torpedo Technology), 2005, 13(2): 7-13
[21] 李学海(Li X H), 王为(Wang W), 吕霖娜(Lv L N), 伊宇(Yi Y). 电源技术(Chinese Journal of Power Sources), 2006, 30(9): 760-763
[22] Stokes J J. US 2838591, 1958
[23] 杨林(Yang L). 四川日化(Sichuan Chemical), 1991, 2: 62-67
[24] Takami N. US 20030219650, 2003
[25] Hidesato S, Takami N. US 20030219650A1, 2003
[26] Hasvold Q, Størkersen N. J. Power Sources, 2001, 96: 252-258
[27] Zaromb S. US 3554810, 1967
[28] Marsh C L, Seebach G L, VanZee J W, Bessette R R, Meunier H G, Medeiros M G. US 5296429, 1994
[29] 温兆银(Wen Z Y). 上海节能(Shanghai Energy Conservation), 2007, 2: 7-11
[30] Licht S L. US 5431881, 1995
[31] Licht S L. US 4828492, 1989
[32] Licht S L, Peramunage D. US 5648183, 1997
[33] Peramunage D, Dillon R, Licht S L. J. Power Sources, 1993, 3(45): 311-323
[34] Licht S L. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 1998, 134: 241-248
[35] Licht S L, Marsh C L. US 5472807, 1995
[36] Licht S L. US 6387569 B1, 2002
[37] Hjuler H A, Berg R W, Bierrum N J. Secondary Aluminium-Metal Sulfide Batteries with Molten NaAlCl4 Electrolyte, Proceedings of the 14th International Power Sources Symposium, 1985. 1-21
[38] Brown G M, US 12/895487, 2010
[39] Jayaprakash N, Das S K, Archer L A. Chem. Commun., 2011, 47: 12610-12612
[40] Li Q F, Bjerrum N J. J. Power Sources, 2002, l10: 1-10
[41] Albert I J, Kulandainathan M A, Ganesan M. J. Appl. Electrochem., 1989, 19: 547-559
[42] Despic A, Radosevic J, Dabic P. Electrochem. Acta, 1990, 35: 1743-1746
[43] Tuck C D S, Hunter J A, Scomans G M. J. Electrochem. Soc., 1987, 134: 2970-2981
[44] Kliskic M, Radosevic J, Aljinovic L J. J. Appl. Electrochem., 1994, 5: 814-818
[45] Gorbunova K M, Adzhemyan T A. Compt. Rend. Acad. Sci. USSR, 1934, 1: 564-567
[46] Diggle J W, Despic A R, Bockris J O M. J. Electrochem. Soc., 1969, 116: 1503-1514
[47] Li Q F, Bjerrum N J. J. Power Sources, 2002, 110: 1-10
[48] Grjotheim K, Matiasovsky K. Acta Chem. Scand., 1980, 34: 666-670
[49] Fellner P, Chrenkova-Paucirova M, Matiasovsky K. Surface Tech., 1981, 14: 101-108
[50] Austin L W, Vucich M G, Smith E J. Electrochem. Tech., 1963, 14: 267-272
[51] Hayashi T. Proceedings of the 1st International Symposium on Molten Salt Chem. Techn., Kyoto, 1983. 53
[52] Stafford G R. J. Electrochem. Soc., 1989, 136: 635-639
[53] Carpio R A, King L A. J. Electrochem. Soc., 1981, 128: 1510-1517
[54] Li Q F, Hjuler H A, Berg R W, Bjerrum N J. J. Electrochem. Soc., 1990, 137: 2794-2798
[55] Tran T T, Obrovac M N. J. Electrochem. Soc., 2011, 158 (12): A1411-A1416
[56] 赵宇光(Zhao Y G). CN101764253A, 2010
[57] Shao H B, Wang J M, Zhang Z. Materials Chemistry and Physics, 2002, 77: 305-309
[58] 陈祝平(Chen Z P). 特种电镀技术(Special Plating Technology). 北京: 化学工业出版社(Beijing: Chemical Industry Press), 2004. 78-102
[59] 郭粤湘(Guo Y X). 新技术新工艺(New Technology & New Process), 1990, 1: 40-41
[60] Vestergaard B, Bjerrum N J, Petrushina I, Hiuler H A, Berg R W, Begtrup M. J. Electrochem. Soc., 1993, 140: 3108-3113
[61] 岳竞慧(Yue J H), 高利珍(Gao L Z), 岳秀萍(Yue X P), 赵宇光(Zhao Y G). 能源与节能(Energy and Energy Conservation), 2011, 2: 68-70
[62] 陈昕(Chen X), 司士辉(Si S H), 张漪丽(Zhang Y L). 应用化学(Chinese Journal of Applied Chemistry), 2004, 21(6): 613-616
[63] Kazuhiro N, Eishi E, Kenichi T. US 5554458, 1996
[64] Atsushi O. US 7524587, 2010
[65] Giner J, Holleck G L. J. Electrochem. Soc., 1972, 119: 1158-1165
[66] Weaving J S, Orchard S W. J. Power Sources, 1991, 36: 537-546
[67] Greenberg J. US P3635765, 1972
[68] Buzzeli D. US P3650834, 1972
[69] Reddy L, Porubszky I, Molnar I. J. Power Sources, 1974, 5: 559-564
[70] Knutz B C, Hjuler H A, Berg R W, Bjerrum N J. J. Electrochem. Soc., 1993, 140: 3374-3379
[71] Knutz B C, Hjuler H A, Berg R W, Bjerrum N J. J. Electrochem. Soc., 1993, 140: 3380-3390
[72] Berretoni M, Tossici R, Zamponi S, Marassi R, Mamantov G. J. Electrochem. Soc., 1993, 140: 969-974
[73] Koura N. J. Electrochem. Soc., 1980, 127: 1529-1531
[74] Koura N, Inoue T. Denki Kagaku, 1981, 49: 113-118
[75] Takhashi S, Koura N. J. Electroanal. Chem., 1985, 188: 245-255
[76] Takami N, Koura N. Electrochim. Acta, 1988, 33: 69-74
[77] Takami N, Koura N. J. Electrochem. Soc., 1993, 140: 928-932
[78] Li Q F, Hjuler H A, Berg R W, Bjerrum N J. J. Electrochem. Soc., 1990, 137(2): 593-598
[79] Li Q F, Hjuler H A, Berg R W, Bjerrum N J. J. Electrochem. Soc., 1991, 138(3): 763-766
[80] 赵宇光(Zhao Y G), 黄兆丰(Huang Z F). CN 101764258A, 2010
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室温铝二次电池及其关键材料