English
往期目录
新闻公告
More
化学进展 DOI: 10.7536/PC121210 前一篇   后一篇

• 综述与评论 •

溶剂浮选技术的研究现状与展望

毕鹏禹*1, 常林2, 牟瑛琳1, 刘建友1, 吴昱1, 魏芸*2   

  1. 1. 防化研究院 北京 102205;
    2. 化工资源有效利用国家重点实验室 北京 100029
  • 收稿日期:2012-12-01 修回日期:2013-03-01 出版日期:2013-08-25 发布日期:2013-06-13
  • 通讯作者: 毕鹏禹,魏芸 E-mail:bipy1982@163.com;weiyun@mail.buct.edu.cn
下载PDF ( 1015 ) 引用
导出 被引次数 ( 1 )

Recent Progress of Solvent Sublation Technique

Bi Pengyu*1, Chang Lin2, Mu Yinglin1, Liu Jianyou1, Wu Yu1, Wei Yun*2   

  1. 1. Research Institute of Chemical Defense, Beijing 102205, China;
    2. State Key Laboratory of Chemical Resource Engineering, Beijing 100029, China
  • Received:2012-12-01 Revised:2013-03-01 Online:2013-08-25 Published:2013-06-13

溶剂浮选是一种被气泡传质效应强化的液-液萃取技术,具有高分离效率、高富集系数、传质温和、低有机溶剂消耗、操作简单等优点,广泛应用于仪器分析的样品前处理、水体中有机污染物的分离富集、天然产物中活性物质分离等领域。本文比较全面地综述了溶剂浮选技术的通用模式、分离参数、应用现状和理论研究进展;在此基础上,重点介绍了近些年溶剂浮选领域出现的一些新分离模式和应用领域:新的分离模式主要是“双水相浮选”和“气浮络合萃取”,新的应用领域主要是样品前处理技术的新应用以及对天然产物提取液中活性物质的分离富集。

关键词： 溶剂浮选, 分离富集, 前处理技术, 理论模型

Solvent sublation is a special liquid-liquid extraction, which is greatly strengthened by the effect of bubble mass transfer. Solvent sublation has many advantages, such as high separation efficiency, high concentration coefficient, soft separation process, low dosage of organic solvent and simple operation. Thus, this technique has been widely applied in sample pretreatment of instrumental analysis, separation and concentration of organic pollutants in water sample, separation of active components in natural products and so on. The present article mainly reviews the recent progress of theory and application research in solvent sublation. Furthermore, several novel separation modes (aqueous two-phase extraction and flotation complexation extraction) and new application fields (sample pretreatment and separation of active components from extract of natural products) are also introduced in detail. Contents
1 Introduction
2 Basic of solvent sublation
2.1 Technical advantages
2.2 General apparatus
2.3 Separation parameters
3 Applications of solvent sublation
3.1 Removal and recovery of organic pollutants
3.2 Analysis of organic compounds
3.3 Analysis of metal ions
3.4 Separation and concentration of active compo-nents from natural product extract
4 Novel separation mode of solvent sublation
4.1 Aqueous Two-Phase Flotation (ATPF)
4.2 Flotation Complexation Extraction (FCE)
5 Theoretical research of solvent sublation
6 Conclusions and outlook

Key words: solvent sublation, separation and concentration, pretreatment technique, theoretical model

中图分类号: 

()
[1] Bi P Y, Dong H R, Dong J. J. Chromatogr. A, 2010, 1217: 2716-2725
[2] Langmuir I, Schaefer V J. J. Am. Chem. Soc., 1937, 59: 2400-2414
[3] Sebba F. Nature, 1959, 184: 1062-1063
[4] Sebba F. Ion Flotation. New York: American Elsevier, 1962. 112-117
[5] 徐其亨 (Xu Q H). 化学通报 (Chemistry), 1981, 7 (11): 42-47
[6] 朱锡海 (Zhu X H). 分析化学 (Chinese J. Anal. Chem.), 1980, 8 (3): 280-284
[7] Caragay A B, Karger B L. Anal. Chem., 1966, 38: 652-654
[8] Elhanan J, Karger B L. Anal. Chem., 1969, 41: 671-674
[9] Grieves R B, Charewicz W, Brien S M. Anal. Chim. Acta, 1974, 73: 293-300
[10] Walkowiak W, Bhattacharyya D, Grieves R B. Anal. Chem., 1976, 48: 975-979
[11] Kotsuji K, Kameyama Y, Arikawa M, Hayashi S. Bunsenki Kagaku (分析化学), 1977, 26: 475-479
[12] Karger K L. in: Adsorptive bubble separation techniques. Lemlich R (Ed.). New York: Academic Press, 1972. 142
[13] Caballero M, Cela R, Perez-Bustamante J A. Talanta, 1990, 37: 275-300
[14] Lv Y J, Zhu X H. Sep. Purif. Methods, 2001, 30: 157-189
[15] 吕玉娟 (Lv Y J), 朱锡海 (Zhu X H). 化学进展 (Progress in Chemistry), 2001, 13 (6): 441-449
[16] Sparge P E, Pinfold T A. Sep. Sci., 1970, 5: 619-635
[17] Lionel T, Wilson D J. Sep. Sci. Technol., 1981, 16: 907-935
[18] Nolan B T Ⅲ, McTernan W F. Chem. Eng. Commun., 1988, 63: 1-15
[19] Valsaraj K T, Thibodeaux L J. Sep. Sci. Technol., 1991, 26: 37-58
[20] Palagyi S, Braun T. Fresenius J. Anal. Chem., 1993, 345: 415-419
[21] Ososkov V, Kebbekus B, Chen M. Sep. Sci. Technol., 1996, 31: 213-227
[22] Smith J S, Valsaraj K T. Chem. Eng. Prog., 1998, 94 (5): 69-77
[23] Thoma G J, Bowen M L, Hollensworth D. Sep. Purif. Technol., 1999, 16: 101-107
[24] Bryson B G, Valsaraj K J. J. Hazard. Mater., 2001, 82: 65-75
[25] Kim Y S, Choi Y S, Lee W. Bull. Korean Chem. Soc., 2003, 24: 1775-1780
[26] Bi P Y, Dong H R, Wang N N. Chinese Chem. Lett., 2007, 18: 1293-1296
[27] Fortz L K, Carter K N, Wilson D J. Sep. Sci. Technol., 1986, 21: 57-78
[28] 范新美 (Fan X M). 北京化工大学硕士论文 (Master Dissertation of Beijing University of Chemical Technology), 2006
[29] Valsaraj K T, Porter J L, Liljenfeldt E K. Wat. Res., 1986, 20: 1161-1174
[30] Sheiham I, Pinfold T A. Sep. Sci., 1972, 7: 43-52
[31] Kiewiet A T, Steen J M D, Parsons J R. Anal. Chem., 1995, 67: 4409-4415
[32] Lv Y J, Zhu X H. Talanta, 2002, 57: 891-898
[33] Lv Y J, Wang Y, Xiong Y, Zhu X H. Fresenius J. Anal. Chem., 2001, 370: 1071-1076
[34] Womack J A, Lichter J C, Wilson D J. Sep. Sci. Technol., 1982, 17: 897-924
[35] Cheng M H, Huang S D. J. Colloid Interf. Sci., 1988, 126: 346-354
[36] Horng J Y, Huang S D. Environ. Sci. Technol., 1993, 27: 1169-1175
[37] Lv Y J, Liu J Z, Tang J, Wei B, Liu J H. Sep. Sci. Technol., 2005, 40: 1115-1127
[38] Lv Y J, Li J Z, Zhang X L, Tang J, Wei B, Liu J H. J. Colloid Interf. Sci., 2005, 292: 210-218
[39] Lv Y J, Wang Y S, Zhu X H. Sep. Sci. Technol., 2001, 36: 3763-3776
[40] Lv Y J, Wei B, Wang Y, Li J Z. Sep. Sci. Technol., 2007, 42: 1901-1911
[41] Sheu G L, Huang S D. Sep. Sci. Technol., 1987, 22: 2253-2262
[42] Huang J Y, Huang S D. Sep. Sci. Technol., 1991, 26: 59-71
[43] Lv Y J, Zhu X H, Peng Y F. Sep. Sci. Technol., 2003, 38: 1385-1398
[44] Grieves R B, Charewicz W, Brien S M. Anal. Chim. Acta, 1974, 73: 293-300
[45] Huang S D, Valsaraj K T, Wilson K T. Sep. Sci. Technol., 1983, 18: 941-968
[46] Valsaraj K T, Springer C. Sep. Sci. Technol., 1986, 21: 789-807
[47] Valsaraj K T, Thibodeaux L J. Sep. Sci. Technol., 1991, 26: 367-380
[48] Shih K Y, Han W D, Huang S D. Sep. Sci. Technol., 1990, 25: 477-487
[49] Shin H S, Coughlin R W. J. Colloid Interf. Sci., 1990, 138: 105-112
[50] Chiu H L, Huang S D. Sep. Sci. Technol., 1991, 26: 73-83
[51] Ososkov V, Kebbekus B, Chou C C. Sep. Sci. Technol., 1996, 31: 1377-1391
[52] Wang W K, Huang S D. Sep. Sci. Technol., 1988, 23: 375-385
[53] Kabil N A, Ghazy S E. Sep. Sci. Technol., 1994, 29: 2533-2539
[54] Tamamushi K, Wilson D J. Sep. Sci. Technol., 1984, 19: 1013
[55] Chiu H L, Huang S D. Sep. Sci. Tachnol., 1992, 27: 1733-1742
[56] Horng J Y, Huang S D. J. Chinese Chem. Soc., 1995, 42: 25-30
[57] Wilson D J, Valsaraj K T. Colloids Surf., 1983, 8: 203-224
[58] Lv Y J, Liu J H, Tang J, Wei B, Zhang X L. J. Colloid Interf. Sci., 2005, 283: 278-284
[59] Sun X H, Chang Z D, Hu X, Shen S F, Liu H Z. Chinese J. Chem. Eng., 2005, 13: 329-333
[60] Sun X H, Chang Z D, Liu H Z, Wang F L, Zhang Y X. Sep. Sci. Technol., 2005, 40: 927-940
[61] Sun X H, Chang Z D, Shen S F, Liu H Z. Colloids Surf. A: Physicochem. Eng. Aspects, 2006, 286: 8-16
[62] Shen S F, Chang Z D, Sun X H, Liu H Z. Process Biochem., 2006, 41: 571-574
[63] Ma Y C, Chang Z D, Hu X, Yu P H, Wang S J, Lei C, Liu H Z. Sep. Purif. Technol., 2010, 72: 77-84
[64] Bayati F, Shayegan J, Noorjahan A. J. Petro. Sci. Eng., 2012, 80: 26-31
[65] Caballero M, Cela R, Perez-Bustamante J A. Anal. Lett., 1988, 21: 63-76
[66] 陈锋 (Chen F), 张宝砚 (Zhang B Y), 毕诗文 (Bi S W), 王宏光 (Wang H G), 李克轩 (Li K X). 分析化学 (Chinese J. Anal. Chem.), 2006, 34: 213-215
[67] Xi Y L, Dong H R. Anal. Sci., 2007, 23: 295-298
[68] Dong H R, Bi P Y, Xi Y L. J. Chromatogr. Sci., 2008, 46: 622-626
[69] Guo L, Dong H R. Intern. J. Environ. Anal. Chem., 2009, 89: 357-365
[70] Zhu L, Dong H R. Chem. Anal., 2009, 54: 59-67
[71] Wang Y, Xu X H, Han J, Yan Y S. Desalination, 2011, 266: 114-118
[72] 王良 (Wang L), 闫永胜 (Yan Y S), 朱文帅 (Zhu W S), 李华明 (Li H M). 分析化学 (Chinese J. Anal. Chem.), 2009, 37: 72-76
[73] Han J, Wang Y, Yu C L, Li C X, Yan Y S, Liu Y, Wang L. Anal. Chim. Acta, 2011, 685: 138-145
[74] Eugene W B, Daniel M D. Anal. Chim. Acta, 1980, 121: 239-247
[75] Cervera J, Cela R, Perez-Bustamante J A. Analyst, 1982, 105: 1425-1430
[76] Dong H R, Yao X Y. Anal. Lett., 1988, 21: 1065-1073
[77] Dong H R, Yang S, Liu J. Anal. Sci., 1989, 5: 601-604
[78] Liu Z M, Yue X Y. Anal. Lett., 1989, 22: 2353-2358
[79] Kim Y S, Jung Y J, Choi H S. Bull. Korean Chem. Soc., 1998, 19: 50-56
[80] Kim Y S, Jung Y J, Choi H S. Bull. Korean Chem. Soc., 1998, 19: 1036-1042
[81] Kim Y S, Kim K C, Lee C W. Bull. Korea Chem. Soc., 1999, 20: 431-442
[82] Kim Y S, Shin J H, Choi Y S, Lee W, Lee Y I. Microchim. J., 2001, 68: 99-107
[83] Kim Y S, Shin J H, Choi Y S, Lee W, Lee Y I. Bull. Korean Chem. Soc., 2001, 22: 19-24
[84] Kim Y S, Choi Y S, Lee W, Lee Y I. Bull. Korean Chem. Soc., 2001, 22: 821-826
[85] Kim Y S, Choi Y S, Lee W. Bull. Korean Chem. Soc., 2001, 23: 1381-1388
[86] Cheng Q, Dong H R. Microchim. Acta, 2005, 150: 59-65
[87] Kim Y S, In G, Kim M H, Choi J M. Bull. Korean Chem. Soc., 2006, 27: 1757-1762
[88] Akl M A, Mori Y, Sawada K. Anal. Sci., 2006, 22: 1169-1174
[89] 董慧茹 (Dong H R), 王士辉 (Wang S H). 分析化学 (Chinese J. Anal. Chem.), 2004, 32: 503-506
[90] Dong H R, Bi P Y, Wang S H. Anal. Lett., 2005, 38: 257-270
[91] 王玉堂 (Wang Y T), 张佳秋 (Zhang J Q), 于永 (Yu Y), 李娟 (Li J), 丁兰 (Ding L), 张寒琦 (Zhang H Q). 分析化学(Chinese J. Anal. Chem.), 2007, 35: 409-412
[92] Li S R, Dong H R. Chem. Nat. Comp., 2007, 43: 635-636
[93] 唐睿 (Tang R), 佘英哲 (She Y Z), 严志红 (Yan Z H), 温金莲 (Wen J L), 张珍英 (Zhang Z Y). 分析化学 (Chinese J. Anal. Chem.), 2009, 37: 593-596
[94] 戈延茹 (Ge Y R), 潘如 (Pan R), 傅海珍 (Fu H Z), 吴云 (Wu Y), 付文艳 (Fu W Y), 闫永胜 (Yan Y S), 戚雪勇 (Qi X Y). 分析化学 (Chinese J. Anal. Chem.), 2012, 40: 317-320
[95] Dong H R, Liu X Q. Acta Chromatographia, 2008, 20: 147-156
[96] Liu X Q, Guo Z, Qing Y W. Procedia Eng., 2011, 18: 184-187
[97] Bi P Y, Dong H R, Guo Q Z. Sep. Purif. Technol., 2009, 65: 228-231
[98] Bi P Y, Li D Q, Dong H R. Sep. Purif. Technol., 2009, 69: 205-209
[99] 毕鹏禹 (Bi P Y), 董慧茹 (Dong H R), 常林 (Chang L). 分析化学 (Chinese J. Anal. Chem.), 2011, 39: 425-428
[100] Bi P Y, Dong H R, Yuan Y C. Sep. Purif. Technol., 2010, 75: 402-406
[101] Yu P H, Huang K, Zhao J M, Zhang C, Xie K, Deng F L, Liu H Z. Sep. Purif. Technol., 2010, 75: 316-322
[102] Bi P Y, Dong H R, Yu H B, Chang L. Sep. Purif. Technol., 2008, 63: 487-491
[103] 毕鹏禹 (Bi P Y), 董慧茹 (Dong H R), 于宏斌 (Yu H B). 分析化学 (Chinese J. Anal. Chem.), 2008, 36: 1217-1220
[104] 梁擘 (Liang B), 吴兆亮 (Wu Z L), 胡滨 (Hu B), 郑辉杰 (Zheng H J). 分析化学 (Chinese J. Anal. Chem.), 2009, 37: 980-984
[105] Wu Z L, Liang B, Hu B, Zheng H J. Sep. Purif. Technol., 2009, 66: 237-241
[106] Karger B L, Pinfold T A, Palmer S E. Sep. Sci., 1970, 5: 603-617
[107] Spargo P E, Pinfold T A. Sep. Sci., 1970, 5: 619-635
[108] Wilson D J, Valsaraj K T. Sep. Sci. Technol., 1982, 17: 1387-1396
[109] Clake A N, Wilson D J. Foam flotation: theory and applications. New York: Dekker, 1983, Chap. 6
[110] Palagyi S, Braun T. Fresenius J. Anal. Chem., 1993, 346: 905-908
[111] Palagyi S, Braun T. Fresenius J. Anal. Chem., 1994, 348: 211-214
[112] Smith J S, Valsaraj K T, Thibodeaux L J. Ind. Eng. Chem. Res., 1996, 35: 1688-1699
[113] Smith J S, Burns L F, Valsaraj K T, Thibodeaux L J. Ind. Eng. Chem. Res., 1996, 35: 1700-1710
[114] Smith J S, Valsaraj K T. Ind. Eng. Chem. Res., 1997, 36: 903-914
[115] Lv Y J, Zhu X H. Anal. Bioanal. Chem., 2002, 374: 906-914
[116] Lv Y J, Liu J, Xiong J, Zhu X H. J. Colloid Interf. Sci., 2003, 263: 261-269
[117] Bi P Y, Dong H R, Wang N N. Chinese Chem. Lett., 2008, 19: 623-626
[118] Lv Y J, Hong W L, Gao Y, Zhang X L, Li J Z. Chinese J. Chem. Phys., 2006, 19: 159-163
[1] 曹祥康, 孙晓光, 蔡光义, 董泽华. 耐久型超疏水表面:理论模型、制备策略和评价方法[J]. 化学进展, 2021, 33(9): 1525-1537.
[2] 梁阿新, 汤波, 孙立权, 张鑫, 侯慧鹏, 罗爱芹. 用于N-糖肽/糖蛋白分离富集的新型材料[J]. 化学进展, 2019, 31(7): 996-1006.
[3] 陈旭伟, 毛全兴, 王建华*. 离子液体在蛋白质萃取分离中的应用[J]. 化学进展, 2013, 25(05): 661-668.
[4] 方彦彦, 李倩, 王晓琳*. 解读纳滤:一种具有纳米尺度效应的分子分离操作[J]. 化学进展, 2012, 24(05): 863-870.
[5] 郭彦,赵健伟. 有序分子组装膜电极非理想伏安图的理论研究*[J]. 化学进展, 2008, 20(06): 821-827.
[6] 徐溢,张剑,徐平洲,卢倩,曾雪,温志渝. 微流控芯片系统中固液双相分离富集技术[J]. 化学进展, 2007, 19(01): 186-192.
[7] 李平,张建林,王爱勤. 壳聚糖及其衍生物在分析化学中的应用[J]. 化学进展, 2006, 18(04): 467-473.
[8] 张波,刘洪来,胡英. 带同种电荷胶体颗粒间的相互吸引*[J]. 化学进展, 2001, 13(01): 1-.
阅读次数
全文


摘要

溶剂浮选技术的研究现状与展望