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化学进展 2013, Vol. 25 Issue (07): 1102-1112 DOI: 10.7536/PC121119 前一篇   后一篇

• 综述与评论 •

全钒氧化还原液流电池电解液

王刚1, 陈金伟1, 汪雪芹1, 田晶1, 刘效疆2, 王瑞林1*   

  1. 1. 四川大学材料科学与工程学院 成都 610065;
    2. 中国工程物理研究院电子工程研究所 绵阳 621900
  • 收稿日期:2012-11-01 修回日期:2012-12-01 出版日期:2013-07-25 发布日期:2013-04-16
  • 通讯作者: 王瑞林 E-mail:rlwang26@yahoo.com.cn
  • 基金资助:

    高等学校博士学科点专项科研基金项目(No. 20110181110003)、四川省科技厅科技支撑项目(No.2013FZ0034)、成都市科技局攻关计划项目(No. 10GGYB380GX-023,10GGYB828GX-023)和中物院-川大联合创新基金项目(No. XTCX2011001)资助

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Electrolyte for All-Vanadium Redox Flow Battery

Wang Gang1, Chen Jinwei1, Wang Xueqin1, Tian Jing1, Liu Xiaojiang2, Wang Ruilin1*   

  1. 1. College of Materials Science and Engineering, Sichuan University, Chengdu 610065, China;
    2. Institute of Electronics Engineering, China Academy of Engineering Physics, Mianyang 621900, China
  • Received:2012-11-01 Revised:2012-12-01 Online:2013-07-25 Published:2013-04-16

近年来,全钒氧化还原液流电池(VRFB)作为一种新型的储能电池备受关注。作为VRFB的核心材料,电解液的制备及优化一直都是研究的热点。高浓度和高稳定性电解液的制备是钒电池的关键技术之一。电解液性能的提高有助于加速VRFB的商业化进程。本文综述了VRFB电解液的研究进展,重点介绍了电解液的制备方法和影响电解液稳定性的因素,简述了电解液中钒离子浓度的分析方法和钒离子的存在形式,最后对电解液的进一步研究和应用前景进行了展望。

关键词： 全钒氧化还原液流电池, 电解液, 制备, 浓度分析, 稳定性, 钒离子存在形式

In recent years, all-vanadium redox flow battery (VRFB) has been paid much attention as a new type of battery for energy storage. Researchers have been focusing much on production and optimization of vanadium electrolyte solutions used for the key materials in VRFB. Production of high concentration and stability electrolyte is one of key technologies referring to VRFB. Commercialization process can be accelerated with the performance improvement of vanadium electrolyte solutions. The research progress in VRFB electrolyte solutions is summarized in this paper. The preparation methods and influence factors of stability on vanadium electrolyte solutions are mainly introduced, and concentration analysis methods and existence forms of vanadium ions in vanadium electrolyte solutions are also discussed. Moreover, further research and prospects on vanadium electrolyte solutions are presented. Contents
1 Introduction
2 Production of vanadium electrolyte solutions
2.1 Chemical synthesis methods
2.2 Electrolytic synthesis methods
3 Concentration analysis of vanadium electrolyte solutions
4 Research on stability of vanadium ions in vanadium electrolyte solutions
4.1 Supporting electrolyte solutions
4.2 Temperature
4.3 Additives
5 Research on existence forms of vanadium ions in vanadium electrolyte solutions
6 Outlook

Key words: all-vanadium redox flow battery, electrolyte solutions, sythesis methods, concentration analysis, stability, existence forms of vanadium ions

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摘要

全钒氧化还原液流电池电解液