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化学进展 2013, Vol. 25 Issue (05): 698-706 DOI: 10.7536/PC121002 前一篇   后一篇

所属专题： 电化学有机合成

• 综述与评论 •

石墨烯的边界效应在电化学生物传感器中的应用

宋英攀, 冯苗, 詹红兵*   

  1. 福州大学材料科学与工程学院 福州 350108
  • 收稿日期:2012-09-01 修回日期:2012-12-01 出版日期:2013-05-24 发布日期:2013-04-15
  • 通讯作者: 詹红兵 E-mail:hbzhan@fzu.edu.cn
  • 基金资助:

    国家自然科学基金项目(No. 51172045)、高等学校博士学科点专项科研基金(新教师类)项目( No. 20113514120006)和福建省自然科学基金项目( No. 2012J05113)资助

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导出 被引次数 ( 20 | 3 )

Application of Graphene Edge Effect in Electrochemical Biosensors

Song Yingpan, Feng Miao, Zhan Hongbing*   

  1. College of Materials Science and Engineering, Fuzhou University, Fuzhou 350108, China
  • Received:2012-09-01 Revised:2012-12-01 Online:2013-05-24 Published:2013-04-15

石墨烯是由底面和边界组成的,这种独特的结构赋予石墨烯很多特殊的性质,如边界上的异相电子转移速率、电容量、局域态密度和结构缺陷、功能性基团等均高于石墨烯的底面,这些固有特征对石墨烯的电化学性能有极大的促进作用,是边界效应的具体体现。本文在阐述石墨烯电化学性能边界效应的基础上,对具有不同形貌特征的石墨烯,如石墨烯纳米片、纳米毯、片晶、纳米墙、纳米纤维、纳米带、量子点等在电化学生物传感领域的具体应用进行了综述和展望。

关键词： 石墨烯, 电化学, 生物传感器, 边界效应, 形貌特征

The unique structure of basal planes and edges in graphene endows graphene specific properties, such as the much higher heterogeneous electron transfer rate, capacitance, local density of states and structural defects, functional groups of edges than basal planes. These inherent features of graphene, which have a great role in promoting its electrochemical performance, are the embodiment of the edge effect. This paper introduces the influence of edge effect on the electrochemical performance of graphene, gives a review and prospect of graphene with different morphology characteristics, such as graphene nanoflakes, nanosheets, nanoplatelets, nanowalls, nanofibers, nanoribbons, and quantum dots, applying in the electrochemical biosensing field. Contents
1 Introduction
2 Edge effect of electrochemical performances: from graphite to graphene
2.1 Edge effect of electrochemical performances in graphite
2.2 Edge effect of electrochemical performances in graphene
3 Two- and quasi two-dimensional graphene-based electrochemical biosensors
4 One- and zero-dimensional graphene-based electr-ochemical biosensors
5 Conclusion and prospect

Key words: graphene, electrochemistry, biosensors, edge effect, morphology characteristics

中图分类号: 

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