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化学进展 DOI: 10.7536/PC120937 前一篇   

• 综述与评论 •

石墨烯及其复合材料在水处理中的应用

肖蓝1, 王祎龙2, 于水利1, 唐玉霖*1   

  1. 1. 同济大学环境科学与工程学院 污染控制与资源化研究国家重点实验室 上海 20009;
    2. 同济大学医学院 生物医学工程与纳米科学研究院 上海 200092
  • 收稿日期:2012-09-01 修回日期:2012-10-01 出版日期:2013-02-24 发布日期:2012-12-28
  • 通讯作者: 唐玉霖 E-mail:tangyulin@tongji.edu.com
  • 基金资助:

    国家自然科学基金项目(No. 21007048)和国家科技支撑计划项目(No. 2012BAJ25B06,2012BAF03B06)资助

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Graphene-Containing Composite Materials for Water Treatment

Xiao Lan1, Wang Yilong2, Yu Shuili1, Tang Yulin*1   

  1. 1. College of Environmental Science and Engineering, State Key Laboratory of Control and Resource Reuse, Tongji University, Shanghai 20009;
    2. School of Medicine, The Institute for Biomedical Engineering & Nano Science, Tongji University, Shanghai 200092, China
  • Received:2012-09-01 Revised:2012-10-01 Online:2013-02-24 Published:2012-12-28

石墨烯(graphene,GE)是一种由sp2杂化的碳原子以六边形排列形成的周期性蜂窝状二维碳质新材料,具有比表面积大、电子迁移率高和化学稳定性强等特性。本文重点总结了近年来石墨烯及其复合材料应用于水处理吸附剂及光催化剂两个方面的研究进展。石墨烯及其复合材料对于处理重金属、有机污染物等污染物质的吸附效果好,吸附容量高;与光催化材料结合后,石墨烯由于其独特的物理化学特性有效增强了复合材料的光催化特性。最后对各种石墨烯及其复合材料在水处理中的应用作出了评价,同时对它们在水处理中的应用前景做了展望。

关键词： 石墨烯, 水处理, 复合材料

Graphene is the basic building block of all graphitic forms of carbon, consisting of a single atomic layer of sp2 hybridized carbon atoms arranged in a honeycomb structure. It has many unique properties, including large specific surface area, high electron mobility, good chemical stability and so on. Its synthesis has been investigated in many different fields with potential applications. Importantly, it could be used in pollutants removal in water treatment, which has been drawing more and more attention in recent years. A series of studies have been conducted on graphene-based materials including graphene-based adsorbents and graphene-based photocatalysts. Different kinds of graphene-based adsorbents such as graphene and graphene-containing materials have been gradually applied in the removal of toxic compounds such as heavy metals, dyes, inorganic anions, etc. In addition, graphene-based photocatalysts, including graphene-complex photocatalyst composites, graphene oxide-complex photocatalyst composites and reduced graphene oxide-complex photocatalyst composites are also discussed in pollutants removal and environmental remediation. In the end, the problems in the application of graphene-based materials in water treatment are poited out, then the roles of graphene-based materials in pollutants removal are summarised and prospects for future research in this field are proposed. Contents
1 Introduction
2 Fabrication and properties of graphene
3 Graphene-based adsorbents in water treatment
3.1 Graphene and graphene-containing materials
3.2 Graphene oxide and graphene oxide-containing materials
3.3 Reduced graphene oxide and reduced graphene oxide-containing materials
4 Graphene-based photocatalysts in water treatment
4.1 Graphene-complex photocatalyst composites
4.2 Graphene oxide-complex photocatalyst composites
4.3 Reduced graphene oxide-complex photocatalyst composites
5 Conclusions and outlook

Key words: graphene, water treatment, composites

中图分类号: 

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[1] Geim A K, Novoselov K S. Nat. Mater., 2007, 6: 183-191
[2] Novoselov K S, Geim A K, Morozov S V, Jiang D, Zhang Y, Dubonos S V, Grigorieva I V, Firsov A A. Science, 2004, 306: 666-669
[3] Lee C G, Wei X D, Kysar J W, Hone J. Science, 2008, 321: 385-388
[4] Stoller M D, Park S J, Zhu Y W, An J H, Ruoff R S. Nano Lett., 2008, 8: 3498-3502
[5] Balandin A A, Ghosh S, Bao W Z, Calizo I, Teweldebrhan D, Miao F, Lau C N. Nano Lett., 2008, 8: 902-907
[6] Bolotin K I, Sikes K J, Jiang Z, Klima M, Fudenberg G, Hone J, Kim P, Stormer H L. Solid State Commun., 2008, 146: 351-355
[7] 徐秀娟(Xu X J), 秦金贵(Qin J G), 李振(Li Z). 化学进展(Progress in Chemistry), 2009, 21(12): 2559-2567
[8] Lu K, Zhao G X, Wang X K. Chin. Sci. Bull., 2012, 57: 1223-1234
[9] Liu Y, Liu C Y, Liu Y. Appl. Surf. Sci., 2011, 257: 5513-5518
[10] Hao L Y, Song H J, Zhang L C, Wan X Y, Tang Y R, Lv Y. J. Colloid Interface Sci., 2012, 369: 381-387
[11] Young R J, Kinloch I A, Gong L, Novoselov K S. Compos. Sci. Technol., 2012, 72: 1459-1476
[12] Meyer J C, Geim A K, Katsnelson M I, Novoselov K S, Booth T J, Roth S. Nature, 2007, 446: 60-63
[13] Li X S, Cai W W, An J H, Kim S, Nah J, Yang D X, Piner R, Velamakanni A, Jung I, Tutuc E, Banerjee S K, Colombo L, Ruoff R S. Science, 2009, 324: 1312-1314
[14] Emtsev K V, Bostwick A, Horn K, Jobst J, Kellogg G L, Ley L, McChesney J L, Ohta T, Reshanov S A, Rohrl J, Rotenberg E, Schmid A K, Waldmann D, Weber H B, Seyller T. Nat. Mater., 2009, 8: 203-207
[15] Stankovich S, Piner R D, Nguyen S T, Ruoff R S. Carbon, 2006, 44: 3342-3347
[16] Liu T H, Li Y H, Du Q J, Sun J K, Jiao Y Q, Yang G M, Wang Z H, Xia Y Z, Zhang W, Wang K L, Zhu H W, Wu D H. Colloid Surface B, 2012, 90: 197-203
[17] Wu T, Cai X, Tan S Z, Li H Y, Liu J S, Yang W D. Chem. Eng. J., 2011, 173: 144-149
[18] Park S, Ruoff R S. Nature Nanotechnology, 2009, 4: 217-224
[19] Brodie B C. Philos. Trans. R. Soc. London, 1859, 149: 249-259
[20] Staudenmaier L. Ber. Dtsch. Chem. Ges., 1898, 31: 1481-1487
[21] Hummers W S, Offeman R E. J. Am. Chem. Soc., 1958, 80: 1339-1339
[22] 甘晓初(Gan X C). 中国科学技术大学硕士论文(Master Dissertation of University of Science and Technology of China), 2011
[23] Pasricha R, Gupta S, Srivastava A K. Small, 2009, 5: 2253-2259
[24] Stankovich S, Dikin D A, Dommett G H B, Kohlhaas K M, Zimney E J, Stach E A, Piner R D, Nguyen S T, Ruoff R S. Nature, 2006, 442: 282-286
[25] Seger B, Kamat P V. J. Phys. Chem. C, 2009, 113: 7990-7995
[26] McAllister M J, Li J L, Adamson D H, Schniepp H C, Abdala A A, Liu J, Herrera-Alonso M, Milius D L, Car R, Prud'homme R K, Aksay I A. Chem. Mater., 2007, 19: 4396-4404
[27] Williams G, Seger B, Kamat P V. ACS Nano, 2008, 2: 1487-1491
[28] Murugan A V, Muraliganth T, Manthiram A. Chem. Mater., 2009, 21: 5004-5006
[29] Ramesha G K, Kumara A V, Muralidhara H B, Sampath S. J. Colloid Interface Sci., 2011, 361: 270-277
[30] Pan B, Xing B S. Environ. Sci. Technol., 2008, 42: 9005-9013
[31] Li Y H, Zhang P, Du Q J, Peng X J, Liu T H, Wang Z H, Xia Y Z, Zhang W, Wang K L, Zhu H W, Wu D H. J. Colloid Interface Sci., 2011, 363: 348-354
[32] 吕鹏(Lv P), 冯奕钰(Feng Y Y), 张学全(Zhang X Q), 李瑀(Li Y), 封伟(Feng W). 中国科学: 技术科学(Science China: Technological Sciences), 2010, 40(11): 1247-1256
[33] Song H J, Zhang L C, He C L, Qu Y, Tian Y F, Lv Y. J. Mater. Chem., 2011, 21: 5972-5977
[34] Cheng J S, Du J, Zhu W J. Carbohyd. Polym., 2012, 88: 61-67
[35] Ren Y M, Yan N, Wen Q, Fan Z J, Wei T, Zhang M L, Ma J. Chem. Eng. J., 2011, 175: 1-7
[36] Guo J, Wang R Y, Tjiu W W, Pan J S, Liu T X. J. Hazard. Mater., 2012, 225: 63-73
[37] Hirata M, Gotou T, Horiuchi S, Fujiwara M, Ohba M. Carbon, 2004, 42: 2929-2937
[38] Matsuo Y, Tahara K, Sugie Y. Carbon, 1997, 35: 113-120
[39] Tkalya E, Ghislandi M, Alekseev A, Koning C, Loos J. J. Mater. Chem., 2010, 20: 3035-3039
[40] Xu C, Wang X, Yang L C, Wu Y P. J. Solid State Chem., 2009, 182: 2486-2490
[41] Machida M, Mochimaru T, Tatsumoto H. Carbon, 2006, 44: 2681-2688
[42] Yang S T, Chang Y L, Wang H F, Liu G B, Chen S, Wang Y W, Liu Y F, Cao A N. J. Colloid Interface Sci., 2010, 351: 122-127
[43] Li Y H, Ding J, Luan Z K, Di Z C, Zhu Y F, Xu C L, Wu D H, Wei B Q. Carbon, 2003, 41: 2787-2792
[44] An H K, Park B Y, Kim D S. Water Res., 2001, 35: 3551-3556
[45] Yang S T, Chen S, Chang Y L, Cao A N, Liu Y F, Wang H F. J. Colloid Interface Sci., 2011, 359: 24-29
[46] Sun L, Yu H W, Fugetsu B. J. Hazard. Mater., 2012, 203: 101-110
[47] Gao Y, Li Y, Zhang L, Huang H, Hu J J, Shah S M, Su X G. J. Colloid Interface Sci., 2012, 368: 540-546
[48] Babel S, Kurniawan T A. J. Hazard. Mater., 2003, 97: 219-243
[49] Ngah W S W, Ab Ghani S, Kamari A. Bioresour. Technol., 2005, 96: 443-450
[50] He Y Q, Zhang N N, Wang X D. Chinese Chem. Lett., 2011, 22: 859-862
[51] Liu L, Li C, Bao C L, Jia Q, Xiao P F, Liu X T, Zhang Q P. Talanta, 2012, 93: 350-357
[52] Zhang N N, Qiu H X, Si Y M, Wang W, Gao J P. Carbon, 2011, 49: 827-837
[53] Fan L, Luo C, Li X, Lu F, Qiu H, Sun M. J. Hazard. Mater., 2012, 215/216: 272-279
[54] Fan L, Luo C, Sun M, Li X, Lu F, Qiu H. Bioresour. Technol., 2012, 114: 703-706
[55] Cheng Y, Tan R Q, Wang W Y, Guo Y Q, Cui P, Song W J. J. Mater. Sci., 2010, 45: 5347-5352
[56] Zhang M, Cheng D, He X W, Chen L X, Zhang Y K. Chemistry- an Asian Journal, 2010, 5: 1332-1340
[57] Lu Z Y, Dai J, Song X N, Wang G, Yang W S. Colloids Surf. Physicochem. Eng. Aspects, 2008, 317: 450-456
[58] He F A, Fan J T, Ma D, Zhang L M, Leung C, Chan H L. Carbon, 2010, 48: 3139-3144
[59] Yao Y J, Miao S D, Yu S M, Ma L P, Sun H, Wang S. J. Colloid Interface Sci., 2012, 379: 20-26
[60] Zhang K, Dwivedi V, Chi C, Wu J. J. Hazard. Mater., 2010, 182: 162-168
[61] Hu X G, Mu L, Wen J P, Zhou Q X. J. Hazard. Mater., 2012, 213/214: 387-392
[62] Sreeprasad T S, Maliyekkal S M, Lisha K P, Pradeep T. J. Hazard. Mater., 2011, 186: 921-931
[63] 柏嵩(Bo S), 沈小平(Sheng X P). 化学进展(Progress in Chemistry), 2010, 22 (11): 2107-2117
[64] Wang P F, Ao Y H, Wang C, Hou J, Qian J. J. Hazard. Mater., 2012, 223: 79-83
[65] Min Y L, Zhang K, Zhao W, Zheng F C, Chen Y C, Zhang Y G. Chem. Eng. J., 2012, 193/194: 203-210
[66] Zhang K, Kemp K C, Chandra V. Mater. Lett., 2012, 81: 127-130
[67] Ghasemi S, Setayesh S R, Habibi-Yangjeh A, Hormozi-Nezhad M R, Gholami M R. J. Hazard. Mater., 2012, 199: 170-178
[68] Gao Z Y, Liu J L, Xu F, Wu D P, Wu Z L, Jiang K. Solid State Sci., 2012, 14: 276-280
[69] Zhang X F, Quan X, Chen S, Yu H T. Appl. Catal. B -Environ., 2011, 105: 237-242
[70] Nguyen-Phan T D, Pham V H, Shin E W, Pham H D, Kim S, Chung J S, Kim E J, Hur S H. Chem. Eng. J., 2011, 170: 226-232
[71] Lee Y C, Yang J W. J. Ind. Eng. Chem., 2012, 18: 1178-1185
[72] Jiang G D, Lin Z F, Chen C, Zhu L H, Chang Q, Wang N, Wei W, Tang H Q. Carbon, 2011, 49: 2693-2701
[73] Gao Y Y, Pu X P, Zhang D F, Ding G Q, Shao X, Ma J. Carbon, 2012, 50: 4093-4101
[74] Yoo D H, Cuong T V, Pham V H, Chung J S, Khoa N T, Kim E J, Hahn S H. Curr. Appl. Phys., 2011, 11: 805-808
[75] Khoa N T, Pyun M W, Yoo D H, Kim S W, Leem J Y, Kim E J, Hahn S H. Thin Solid Films, 2012, 520: 5417-5420
[76] Neppolian B, Bruno A, Bianchi C L, Ashokkumar M. Ultrason. Sonochem., 2012, 19: 9-15
[77] Li B X, Liu T X, Wang Y F, Wang Z F. J. Colloid Interface Sci., 2012, 377: 114-121
[78] Wang F, Zhang K. J. Mol. Catal. A: Chem., 2011, 345: 101-107
[79] Nguyen-Phan T D, Pham V H, Kweon H, Chung J S, Kim E J, Hur S H, Shin E W. J. Colloid Interface Sci., 2012, 367: 139-147
[80] Lv T, Pan L K, Liu X J, Lu T, Zhu G, Sun Z. J. Alloy. Compd., 2011, 509: 10086-10091
[81] Zhou X, Shi T J, Zhou H. Appl. Surf. Sci., 2012, 258: 6204-6211
[82] Liu X J, Pan L K, Zhao Q F, Lv T, Zhu G, Chen T Q, Lu T, Sun Z, Sun C Q. Chem. Eng. J., 2012, 183: 238-243
[83] Shi Y H, Feng S H, Cao C S. Mater. Lett., 2000, 44: 215-218
[84] McDowell N A, Knight K S, Lightfoot P. Chem. Eur. J., 2006, 12: 1493-1499
[85] Fu H B, Pan C S, Yao W Q, Zhu Y F. J. Phys. Chem. B, 2005, 109: 22432-22439
[86] Zhang C, Zhu Y F. Chem. Mater., 2005, 17: 3537-3545
[87] Ma D K, Huang S M, Chen W X, Hu S W, Shi F F, Fan K L. J. Phys. Chem. C, 2009, 113: 4369-4374
[88] Ma H, Shen J, Shi M, Lu X, Li Z, Long Y, Li N, Ye M. Appl. Catal. B: Environ., 2012, 121/122: 198-205
[89] Lerf A, He H Y, Forster M, Klinowski J. J. Phys. Chem. B, 1998, 102: 4477-4482
[90] Wang X, Tian H, Yang Y, Wang H, Wang S, Zheng W, Liu Y. J. Alloy. Compd., 2012, 524: 5-12
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