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化学进展 2013, Vol. 25 Issue (0203): 276-287 DOI: 10.7536/PC120655 前一篇   后一篇

• 综述与评论 •

热液法制备磁性纳米材料

李亦婧, 朱浩, 侯晨, 江宇, 李彦锋*   

  1. 兰州大学 功能有机分子化学国家重点实验室 化学化工学院 生物化工及环境技术研究所 兰州 730000
  • 收稿日期:2012-06-01 修回日期:2012-11-01 出版日期:2013-02-24 发布日期:2012-12-28
  • 通讯作者: 李彦锋 E-mail:liyf@lzu.edu.cn
  • 基金资助:

    国家自然科学基金项目(No.21074049)和国家基础科学人才培养基金-能力提高项目(No.J1103307)资助

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Hydrothermal & Solvothermal Synthesis of Nanoscale Magnetic Materials

Li Yijing, Zhu Hao, Hou Chen, Jiang Yu, Li Yanfeng*   

  1. State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Institute of Biochemical Engineering & Environmental Technology, Lanzhou University, Lanzhou 730000, China
  • Received:2012-06-01 Revised:2012-11-01 Online:2013-02-24 Published:2012-12-28

磁性纳米材料作为新兴的无机功能材料,因其具有与常规材料不同的特殊性质,如高比表面积、强磁响应性、良好的化学稳定性和生物相容性等,被广泛应用在生物合成、生物分离、生物传感器、免疫测定、有机催化、药物传输、数据存储和环境治理等方面。目前合成磁性纳米材料的方法主要有化学共沉降法、高温热分解法、溶胶-凝胶法及热液法等。由于热液法具有条件简易、成本低廉、反应活性高、产率可观和绿色环保等优势,近年来受到了广泛的关注,并已应用在工业生产中。本文根据磁性材料组成与构成方式的不同,综述了热液法合成磁性纳米材料的研究进展。

关键词： 热液法, 磁性材料, 纳米, 制备

Nanoscale mgnetic materials as a kind of novel functional inorganic materials have been widely employed for biosynthesis, bioseparation, biosensors, immunoassays, organocatalysis, drug delivery, data storage and environmental improvement,due to their special properties such as high specific surface area, strong magnetic responsivity, chemical durability,biocompatibility and so on. So far, various synthetic methods have been devised to fabricate magnetic nanomaterials, including chemical coprecipitation, organometallic pyrolysis, sol-gel techniques, hydrothermal & solothermal synthesis, etc. In recent years, hydrothermal & solvothermal synthesis method has received extensive attention and is widely used in industrial production because of its advantages of simple reaction conditions, low cost, high activity, good yields and green-friendly. This review introduced four kinds of nanoscale magnetic material synthetized by hydrothermal or solvothermal,which are ferrite,composite material,magnetic alloy material,and other magnetic material. 1 Introduction
2 Ferrite
2.1 Unitary ferrite
2.2 Binary ferrite
3 Composite material
3.1 Ferrite/inorganics composite material
3.2 Ferrite/organics composite material
4 Magnetic alloy material
5 Other magnetic material
6 Conclusion and prosperct

Key words: hydrothermal &, solvothermal synthesis, magnetic materials, nanoscale, preparation

中图分类号: 

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[1] Sugimoto T, Matijevic E. J. Colloid. Interface. Sci., 1980, 74: 227-243
[2] 李泉(Li Q), 曾广斌(Zeng G B), 席时权(Xi S Q). 化学通报(Chemistry), 1995, 6: 29-34
[3] 赵强(Zhao Q). 原子与分子物理学报(Journal of Atomic and Molecular Physics), 2005, 22: 89-95
[4] Grutner C, Rudershausen S, Teller J. J. Magn. Magn. Mater., 2001, 225: 1-7
[5] Hu F Q, MacRenaris K W, Waters E A, Schultz-Sikma E A, Eckermann A L, Meade T J. Chem. Commun., 2010, 46: 73-75
[6] Huang X L, Zhuang J, Chen D, Liu H Y, Tang F Q, Yan X Y, Meng X W, Zhang L, Ren L. Langmuir, 2009, 25(19): 11657-11663
[7] 张立德(Zhang L D), 牟季美(Mou J M). 纳米材料和纳米结构(Nanometer materials and nanometer structure). 北京: 科学出版社(Beijing: Science Press), 2002. 20
[8] Sehultz R M, Silberman S, Persky B, Baikowski A S, Cormichael D F. Cancer Res., 1988, 48: 5539-5545
[9] 洪小平(Hong X P), 彭图治(Peng T Z). 分析化学(Chinese Journal of Analytical Chemistry), 2003, 31(7): 789-793
[10] 王胜林(Wang S L), 王强斌(Wang Q B), 古宏晨(Gu H C). 化学世界(Chemical World), 2001(7): 384-386
[11] Arturo M, Lopez Q, Jose R. J. Colloid. Interf. Sci., 1993, 15(8): 446-451
[12] 蒋秉植(Jiang B Z), 杨健美(Jiang J M). 化学进展(Progress in Chemistry), 1997, 9(1): 69-78
[13] Sun Y K, Duan L, Guo Z R. J. Magn. Magn. Mater., 2005, 285: 65-70
[14] Stoeva S I, Huo F, Lee J, Mirkin C A. J. Am. Chem. Soc., 2005, 127(44): 15362-15363
[15] Smolensky E D, Park H Y E, Berquo T S, Pierrea V C. Contrast Media Mol. Imaging, 2011, 6(4): 189-199
[16] Xu X Q, Deng C H, Gao M X, Yu W J, Yang P Y, Zhang X M. Adv. Mater., 2006, 18: 3289-3293
[17] Hao R, Xing R J, Xu Z C, Hou Y L, Gao S, Sun S H. Adv. Mater., 2010, 22: 2729-2742
[18] Hofmann A, Thierbach S, Semisch A, Hartwig A, Taupitz M, Rühl E, Graf C. J. Mater. Chem., 2010, 20: 7842-7853
[19] Feltin N, Peleni M P. Langmuir, 1997, 13: 3927-3933
[20] 丁明(Ding M), 曾桓兴(Zeng H X). 无机材科学报 (Journal of Inorganic Materials), 1998, 13: 619-624
[21] Massart R. IEEE Trans. Magn., 1981, 17: 1247-1250
[22] Sun S H, Zeng H. J. Am. Chem. Soc., 2002, 124: 8204-8205
[23] Sun S H, Zeng H, Robinson D B, Raoux S, Rice P M, Wang S X. J. Am. Chem. Soc., 2004, 126: 273-279
[24] Itoh H, Sugimoto T. J. Colloid Interf. Sci., 2003, 265: 283-295
[25] Cheng F Y, Sua C H, Yang Y S. Biomaterials, 2005, 26(7): 729-738
[26] Fan R, Chen X H, Gui Z, Liu L, Chen Z Y. Mater. Res. Bull., 2001, 36: 197-502
[27] Konishi Y, Nomura T, Mizoe K. Hydrometallurgy, 2004, 74: 57-65
[28] 甘志锋(Gan Z F), 姜继森(Jiang J S). 化学进展(Progress in Chemistry), 2005, 17(6): 978-986
[29] Franger S, Berthet P, Berthon J. J. Solid State Electr., 2004, 8: 218-223
[30] Ge J P, Hu Y X, Biasini M, Dong C, Guo J H, Beyermann W P, Yin Y D. Chem. Eur. J., 2007, 13: 7153-7161
[31] Liang X, Wang X, Zhuang J, Chen Y T, Wang D S, Li Y D. Adv. Funct. Mater., 2006, 16: 1805-1813
[32] Jia X, Chen D R, Jiao X L, Zhai S M. Chem. Commun., 2009, 968-970
[33] Demazeau G. Res. Chem. Intermed., 2011, 37(2/5): 107-123
[34] 施尔畏(Shi E W), 夏长泰(Xia C T), 王步国(Wang B G). 无机材料学报(Journal of Inorganic Materials), 1996, 11(2): 193-206
[35] 王成云(Wang C Y), 苏庆德(Su Q D), 钱逸泰(Qian Y T). 化学研究与应用(Chemical Research and Application), 2001, 13(4): 402-405
[36] Deng H, Li X, Peng Q, Wang X, Chen J, Li Y D. Angew. Chem., 2005, 117: 2842-2845
[37] Wang L Y, Bao J, Wang L, Zhang F, Li Y D. Chem. Eur. J., 2006, 12: 6341-6347
[38] Zhu L P, Xiao H M, Zhang W D, Yang G, Fu S Y. Crystal Growth & Design, 2008, 8: 957-963
[39] Zou G, Xiong K, Jiang C, Li H, Li T, Du J, Qian Y. J. Phys. Chem. B, 2005, 109: 18356-18360
[40] Wang J, Wu Y, Zhu Y. Mater. Chem. Phys., 2007, 106: 1-4
[41] Liu J, Sun Z K, Deng Y H, Zou Y, Li C Y, Guo X H, Xiong L Q, Gao Y, Li F Y, Zhao D Y. Angew. Chem., 2009, 121: 5989-5993
[42] Li X Y, Si Z J, Lei Y Q, Tang J K, Wang S, Su S Q, Song S Y, Zhao L J, Zhang H J. Cryst. Eng. Comm., 2010, 12: 2060-2063
[43] Dong F P, Guo W P, Bae J H, Kim S H, Ha C S. Chem. Eur. J., 2011, 17: 12802-12808
[44] Wang S B, Min Y L, Yu S H. J. Phys. Chem. C, 2007, 111: 3551-3554
[45] Jianmin M, Lian J B, Duan X C, Liu X D, Zheng W J. J. Phys. Chem. C, 2010, 114: 10671-10676
[46] Li X, Yu X, He J H, Xu Z. J. Phys. Chem. C, 2009, 113(7): 2837-2845
[47] Islam Md S, Kusumoto Y, Abdulla-Al-Mamun Md. Mater. Lett., 2012, 66: 165-167
[48] Zhou J, Ma J F, Sun C, Xie L J, Zhao Z Q, Tian H. J. Am. Ceram. Soc., 2005, 88 (12): 3535-3537
[49] Yu B Y, Kwak S Y. Dalton Trans., 2011, 40: 9989-9998
[50] Gu Z J, Xiang X, Fan G L, Li F. J. Phys. Chem. C, 2008, 112: 18459-18466
[51] Wang Y Q, Cheng R M, Wen Z, Zhao L. J. Eur. J. Inorg. Chem., 2011, (19): 2942-2947
[52] Gajovi D? A, Šturm S, Janwar B, Šanti D? A, agar K, eh M. J. Am. Ceram. Soc., 2010, 93: 3173-3179
[53] Liu B, Hu B B, Du Z L. Chem. Commun., 2011, 47: 8166-8168
[54] Drofenik M, Kristl M, nidarši D? A, Han?e D, Lisjak D. J. Am. Ceram. Soc., 2007, 90: 2057-2061
[55] Wang Z F, Guo H S, Yu Y L, He N Y. J. Magn. Magn. Mater., 2006, 302: 397-404
[56] She X P, Wu J L, Ba S, Zhou H. Alloys Compd., 2010, 506: 136-140
[57] Zhou K F, Zhu Y H, Yang X L, Li C Z. New J. Chem., 2010, 34: 2950-2955
[58] Wu H X, Liu G, Wang X, Zhang J M, Chen Y, Shi J L, Yang H, Hu H, Yang S P. Acta Biomaterialia, 2011, 7: 3496-3504
[59] Zhang E L, Tang Y H, Peng K, Guo C, Zhang Y. Solid State Commun., 2008, 148: 496-500
[60] Guo X H, Deng Y H, Gu D, Che R C, Zhao D Y. J. Mater. Chem., 2009, 19: 6706-6712
[61] Zhang L, Chen L, Wan Q H. Chem. Mater., 2008, 20: 3345-3353
[62] Gao G, Wu H X, Zhang Y X, Luo T, Feng L L, Huang P, He M, Cui D X. CrystEngComm, 2011, 13: 4810-4813
[63] Liu B, Zhang W, Yang F K, Feng H L, Yang X L. J. Phys. Chem. C, 2011, 115: 15875-15884
[64] Xu S, Ma W F, You L J, Li J M, Guo J, Hu J J, Wang C C. Langmuir, 2012, 28: 3271-3278
[65] Liao Q L, Tannenbaum R, Wang Z L. J. Phys. Chem. B, 2006, 110: 14262-14265
[66] Zhou X M, Wei X W. Cryst. Growth. Des., 2009, 9: 7-12
[67] Jia J C, Yu J C, Wang Y X, Chan K M. Appl. Mater. Inter., 2010, 2(9): 2579-2584
[68] Liu A P, Chen X Y, Zhang Z J, Jiang Y, Shi C W. Solid State Commun., 2006, 138: 538-541
[69] Chen L Q, Yang X F, Fu X H, Wang C M, Liang C L, Wu M M. Eur. J. Inorg. Chem., 2011, 2098-2102
[70] Gao M R, Lin Z Y, Jiang J, Yao H B, Lu Y M, Gao Q, Yao W T, Yu S H. Chem. Eur. J., 2011, 17: 5068-5075
[71] Ghosh M, Sampathkumaran E V, Rao C N R. Chem. Mater., 2005, 17: 2348-2352
[72] Hu M J, Lu Y, Zhang S, Guo S R, Lin B, Zhang M, Yu S H. J. Am. Chem. Soc., 2008, 130: 11606-11607
[73] Zhang Y J, Yao Q, Zhang Y, Cui T Y, Li D, Liu W, Lawrence W, Zhang Z D. Cryst. Growth Des., 2008, 8: 3206-3212
[74] Alagiri M, Muthamizhchelvan C, Ponnusamy S. Mater. Lett., 2011, 65: 1565-1568
[75] Cheng M Z, Wen M, Zhou S Q, Wu Q S, Sun B L. Inorg. Chem., 2012, 51: 1495-1500
[76] 吴会军(Wu H J), 朱冬生(Zhu D S), 向兰(Xiang L). 化工新型材料(New Chemical Materials), 2005, 33(8): 1-4
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摘要

热液法制备磁性纳米材料