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化学进展 DOI: 10.7536/PC120636 前一篇   后一篇

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NO2在黑碳表面的非均相反应

沈利娟, 张泽锋*   

  1. 南京信息工程大学 中国气象局大气物理与大气环境重点开放实验室 南京 210044
  • 收稿日期:2012-06-01 修回日期:2012-09-01 出版日期:2013-01-24 发布日期:2012-12-27
  • 通讯作者: 张泽锋 E-mail:zhangzf01@vip.163.com
  • 基金资助:

    国家自然科学基金项目(No. 41005071)、江苏省高校自然科学研究重大项目(No. 12KJA170003)、中国气象局大气物理与大气环境重点开放实验室开放基金项目(No. KDW1103)和江苏高校优势学科建设工程项目(PAPD)资助

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Heterogeneous Reactions of NO2 on the Surface of Black Carbon

Shen Lijuan, Zhang Zefeng*   

  1. Key Laboratory for Atmospheric Physics and Environment, CMA, Nanjing University of Information Science and Technology, Nanjing 210044, China
  • Received:2012-06-01 Revised:2012-09-01 Online:2013-01-24 Published:2012-12-27

HONO是大气中OH自由基的重要来源,NO2在黑碳表面可反应生成HONO,因此NO2在黑碳表面的非均相反应引起了人们的关注。目前不同研究小组测量的摄取系数可相差7个数量级,选择不同的摄取系数去评估非均相反应的重要性将得到完全不同的结果。本文在深入分析NO2在黑碳表面反应机理的基础上,从反应体系、黑碳表面性质、反应条件等角度对不同小组测量的摄取系数存在差异的原因进行了分析,为模式中摄取系数的选取提供了依据。

关键词： 反应机理, 摄取系数, 黑碳

HONO is the main source of hydroxyl radical (OH) in the atmosphere, and is formed by the reaction of NO2 on the surface of black carbon. Therefore, the heterogeneous reactions of NO2 on the surface of black carbon have been attracted scientists in the past years. The uptake coefficients varied 7 orders of magnitude in different research groups. For assessing the importance of the heterogeneous reaction, the results are different when selecting different uptake coefficients. On the basis of a deep analysis of the reaction mechanism of NO2 with black carbon, the reasons of the discrepancy in uptake coefficients were analyzed according to reaction system, surface properties of black carbon and reaction condition. The results will provide a basis for the selection of uptake coefficients in the model. Contents
1 Introduction
2 Heterogeneous reaction mechanism of NO2 on the surface of black carbon
2.1 Reactions of NO2 on the surface of black carbon
2.2 Oxidation-reduction reactions of NO2 on the surface of black carbon
3 Uptake coefficients of NO2 on the surface of black carbon
3.1 Effects of the reaction system on uptake coefficients
3.2 Effects of the surface properties of black carbon on uptake coefficients
3.3 Effects of the reaction conditions on uptake coefficients
4 Conclusions and outlook

Key words: reaction mechanism, uptake coefficients, black carbon

中图分类号: 

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摘要

NO2在黑碳表面的非均相反应