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化学进展 DOI: 10.7536/PC120621 前一篇   后一篇

• 综述与评论 •

全钒液流电池隔膜的制备与性能

汪南方1,2, 刘素琴*2   

  1. 1. 湖南工程学院化学化工学院 湘潭 411104;
    2. 中南大学化学化工学院 长沙 410083
  • 收稿日期:2012-06-01 修回日期:2012-09-01 出版日期:2013-01-24 发布日期:2012-12-27
  • 通讯作者: 刘素琴 E-mail:sqliu2003@126.com
  • 基金资助:

    国家自然科学基金项目(No.51072234)和国家重点基础研究发展计划(973)项目(No.2010CB227201)资助

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导出 被引次数 ( 19 )

Preparation and Properties of Separation Membranes for Vanadium Redox Flow Battery

Wang Nanfang1,2, Liu Suqin*2   

  1. 1. School of Chemistry and Chemical Engineering, Hunan Institute of Engineering, Xiangtan 411104, China;
    2. School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China
  • Received:2012-06-01 Revised:2012-09-01 Online:2013-01-24 Published:2012-12-27

全钒液流电池作为一种电化学储能装置在电网调峰、山区供电、电动车充电电源、应急电源等方面具有很广阔的应用前景。隔膜是全钒液流电池的关键组件之一,其结构和性能决定电池的效能。隔膜的离子传导率和钒离子的渗透率分别影响电池的电压效率和电流效率。隔膜的化学稳定性决定电池的长期运行的稳定性和使用寿命。本文根据隔膜的类别不同,分别阐述了含氟离子膜、非氟离子膜及多孔膜的制备与上述性能的关系,并展望了隔膜的发展方向。

关键词： 全钒液流电池, 离子交换膜, 钒离子透过率, 水迁移, 化学稳定性

All vanadium redox flow battery (VRB) is accepted as a electrochemical energy storage device for the load levelling and peak shaving of the grid, the power supply for remote area, the charging power source for the electric vehicles, and the uninterruptible power supply. As one of the key components in VRB system, the membrane, in the terms of its structures and properties, is responsible for the efficiencies of the VRB. The ion conductivity and vanadium ions permeation of the membrane affect the voltage efficiency and coulombic efficiency of the battery, respectively. The chemical stability of the membrane determines the long-term performance and lifetime of the battery. This review mainly summarizes the preparation and properties of the fluorinated ionic exchange membranes, the non-fluorinated ionic exchange membranes, and the pore membranes. The promising research strategies are outlook. Contents
1 Introduction
2 Fluorinated ionic exchange membranes
2.1 Nafion membranes
2.2 PVDF grafted membranes
2.3 PTFE grafted membranes
3 Non-fluorinated ionic exchange membranes
3.1 Poly (aryl ether)s membranes
3.2 Other membranes
4 Pore separation membranes
5 Conclusion and outlook

Key words: vanadium redox flow battey, ionic exchange membrane, permeability of vanadium ions, transfer of water, chemical stability

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全钒液流电池隔膜的制备与性能