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化学进展 2017, Vol. 29 Issue (4): 400-411 DOI: 10.7536/PC161213 前一篇   后一篇

• 综述 •

体异质结型聚合物太阳能电池中的微观形貌调控方法

康建喜1,2,3, 王世荣1,2,3, 孙孟娜1,2,3, 刘红丽1,2,3, 李祥高1,2,3*   

  1. 1. 天津大学化工学院 天津 300350;
    2. 天津化学化工协同创新中心 天津 300072;
    3. 天津市功能精细化学品技术工程中心 天津 300072
  • 收稿日期:2016-12-08 修回日期:2017-01-12 出版日期:2017-04-15 发布日期:2017-03-31
  • 通讯作者: 李祥高,e-mail:lixianggao@tju.edu.cn E-mail:lixianggao@tju.edu.cn
  • 基金资助:
    国家自然科学基金项目（No.21676188）和天津市自然科学基金项目（No.16JCZDJC37100）资助
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Regulation Methods for Micro-Morphology of Bulk Heterojunction Polymer Solar Cells

Jianxi Kang1,2,3, Shirong Wang1,2,3, Mengna Sun1,2,3, Hongli Liu1,2,3, Xianggao Li1,2,3*   

  1. 1. School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China;
    2. Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300072, China;
    3. Tianjin Engineering Center of Functional Fine Chemicals, Tianjin 300072, China
  • Received:2016-12-08 Revised:2017-01-12 Online:2017-04-15 Published:2017-03-31
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No.21676188) and the Natural Science Foundation of Tianjin (No.16JCZDJC37100).
体异质结型聚合物太阳能电池因具有成本低、质量轻、制备工艺简单和柔韧性好等优点，成为光伏技术领域的研究热点，其能量转化效率超过11%。体异质结层作为体异质结型聚合物太阳能电池的核心，其微观形貌影响体异质结型聚合物太阳能电池的开路电压、填充因子和短路电流，进而影响其能量转化效率。因此如何有效调控体异质结的微观形貌是提高体异质结型聚合物太阳能电池能量转换效率的关键问题之一。本文系统介绍了体异质结的形成过程，总结和论述近年发展的体异质结的微观形貌调控方法，以期为体异质结型聚合物太阳能电池的制备提供指导和借鉴。
关键词： 体异质结, 能量转换效率, 太阳能电池, 微观形貌
Bulk heterojunction polymer solar cells have become one of the research hotspots in the field of photovoltaic technology due to their low production cost, light weight, simple preparation process, good flexibility and so on. Bulk heterojunction polymer solar cells have achieved energy conversion efficiency of more than 11%. The bulk heterojunction layer is the key point of the bulk heterojunction polymer solar cells and its micro-morphology has an influence on the energy conversion efficiency by affecting the open-circuit voltage, fill factor and short-circuit current of the bulk heterojunction polymer solar cells. So how to effectively control the micro-morphology of the bulk heterojunction is one of the key issues for improving the energy conversion efficiency of bulk heterojunction polymer solar cells. In this paper, the formation process of bulk heterojunction is introduced, and the micro-morphology control methods of bulk heterojunction developed in recent years are systematically summarized and discussed to provide guidance and reference for the preparation of the bulk heterojunction polymer solar cells.

Contents
1 Introduction
2 The formation process of organic bulk heterojunction
3 Regulation for micro-morphology of bulk heterojunction
3.1 Regulation for micro-morphology of bulk heterojunction by solvent-induced
3.2 Regulation for micro-morphology of bulk heterojunction by thermal annealing
3.3 Regulation for micro-morphology of bulk heterojunction by the ratio of donor and acceptor
4 Conclusion

Key words: bulk heterojunction, energy conversion efficiency, solar cells, micro-morphology

中图分类号: 

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