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化学进展 2016, Vol. 28 Issue (10): 1578-1590 DOI: 10.7536/PC160350 前一篇   

• 综述与评论 •

选择性氧化还原脱硝催化剂

李盼盼1, 于锋1,3,4, 朱明远1, 汤常金2,5, 代斌1*, 董林2,5*   

  1. 1. 石河子大学化学化工学院 新疆兵团化工绿色过程重点实验室 石河子 832003;
    2. 南京大学化学化工学院 介观化学教育部重点实验室 南京 210093;
    3. 新疆建设兵团材料化工工程技术研究中心 石河子 832003;
    4. 材料化工新疆维吾尔自治区重点实验室 石河子 832003;
    5. 江苏省机动车尾气污染控制重点实验室 南京 210093
  • 收稿日期:2016-03-01 修回日期:2016-08-01 出版日期:2016-10-15 发布日期:2016-11-05
  • 通讯作者: 代斌, 董林 E-mail:db_tea@shzu.edu.cn;donglin@nju.edu.cn
  • 基金资助:
    国家高技术研究发展计划（863计划）（No.2015AA03A401），教育部长江学者与创新团队发展计划（No.IRT_15R46）和兵团科技创新团队计划（No.2015BD003）项目资助
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Selective Catalytic Reduction De-NOx Catalysts

Li Panpan1, Yu Feng1,3,4, Zhu Mingyuan1, Tang Changjin2,5, Dai Bin1*, Dong Lin2,5*   

  1. 1. Key Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, School of Chemistry and Chemical Engineering, Shihezi University, Shihezi 832003, China;
    2. Key Laboratory of Mesoscopic Chemistry of Ministry of Education, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093;
    3. Engineering Research Center of Materials-Oriented Chemical Engineering of Xinjiang Production and Construction Corps, Shihezi 832003, China;
    4. Key Laboratory of Materials-Oriented Chemical Engineering of Xinjiang Uygur Autonomous Region, Shihezi 832003, China;
    5. Jiangsu Key Laboratory of Vehicle Emissions Control, Nanjing 210093, China
  • Received:2016-03-01 Revised:2016-08-01 Online:2016-10-15 Published:2016-11-05
  • Supported by:
    The work was supported by the National High Technology Research and Development Program of China (863 program) (No. 2015AA03A401), Program for Changjiang Scholars and Innovative Research Team in University (No. IRT_15R46) and the Program of Science and Technology Innovation Team in Bingtuan (No. 2015BD003).
氮氧化物（NOx）是烟气中的主要污染性气体之一，脱除NOx已经刻不容缓。本文综述了近年来烟气中NOx的脱除方法，分析了以钒基催化剂、铁基催化剂、分子筛催化剂为代表的高温脱硝催化剂，讨论了以贵金属催化剂、锰基催化剂、碳基催化剂为代表的低温脱硝催化剂， 阐述了不同温度下选择性催化还原（SCR）脱硝催化剂的反应机理，展望了脱硝领域的发展前景。
关键词： 氮氧化物, 选择性催化还原, 脱硝催化剂, 反应机理
Nitrogen oxides (NOx) in flue gases is an important source of air pollution. It is urgent to remove the NOx from flue gases. In this review, the removal ways of nitrogen oxides are reviewed in terms of high-temperature and low-temperature selective catalytic reduction (SCR) De-NOx catalysts. We discuss the high-temperature SCR De-NOx catalysts including vanadium-based catalysts, iron-based catalysts and molecular sieve-based catalysts. Then, we highlight the low-temperature SCR De-NOx catalysts such as noble metal-based catalysts, manganese-based catalyst, carbon-based catalysts, etc. We specifically focus on the mechanism studies of SCR De-NOx catalysts. Finally, we summarize the recent advances in denitrification.

Contents
1 Introduction
2 Process arrangement of SCR denitrification
3 SCR catalysts
3.1 High-temperature catalysts
3.2 Low-temperature catalysts
4 Conclusion

Key words: nitrogen oxides, selective catalytic reduction, denitrification catalyst, reaction mechanism

中图分类号: 

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摘要

选择性氧化还原脱硝催化剂