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化学进展 2015, Vol. 27 Issue (6): 625-632 DOI: 10.7536/PC141036 前一篇   后一篇

• 超分子化学专辑 •

基于外壁作用的瓜环基超分子配位聚合物

祝黔江, 薛赛凤, 陶朱*   

  1. 贵州大学 贵州省大环化学及超分子化学重点实验室 贵阳 550025
  • 收稿日期:2014-10-01 修回日期:2014-11-01 出版日期:2015-06-15 发布日期:2015-03-23
  • 通讯作者: 陶朱 E-mail:gzutao@263.net
  • 基金资助:
    国家自然科学基金项目(No.21272045)资助
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Supramolecular Coordination Polymers Based on the Outer-Surface Interaction of Cucurbit [n] urils

Zhu Qianjiang, Xue Saifeng, Tao Zhu*   

  1. Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province, Guizhou University, Guiyang 550025, China
  • Received:2014-10-01 Revised:2014-11-01 Online:2015-06-15 Published:2015-03-23
  • Contact: 10.7536/PC141036 E-mail:gzutao@263.net
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No. 21272045).
利用瓜环外壁的结构导向作用设计并构筑瓜环-金属离子超分子配位聚合物可能成为瓜环配位化学研究的一个新方向。根据瓜环外壁作用类型,研究内容包括:1) 瓜环外壁取代烷基推电子效应对瓜环基超分子配位聚合物形成的促进作用;2) 瓜环外壁与化合物芳环的相互作用对瓜环基超分子配位聚合物形成的促进作用;3) 瓜环外壁与无机阴离子的相互作用对瓜环基超分子配位聚合物形成的促进作用;4) 瓜环外壁取代羟基的配位作用对瓜环基超分子配位聚合物形成的促进作用。这些瓜环基超分子配位聚合物可能具有吸附捕集、分离提纯和分析等功能性质。
关键词： 瓜环外壁作用, 结构导向, 金属-瓜环配位, 配位聚合物, 功能性质
A series of supramolecular polymers based on direct coordination of metal ions to the cucurbit[n] urils with the aid of the outer-surface interactions of cucurbit[n] urils could become a new branch in Q s-based coordination chemistry. According to the characteristics of the outer-surface interactions of cucurbit[n] urils, they can be catalogued in: 1) electrodonating effect of the alkyl-substituted groups on the outer-surface of cucurbit[n] urils; 2) interactions between methine or methylene moieties on the outer-surface of cucurbit[n] urils and aromatic moiety of organic structure directing agents; 3) interactions between methine or methylene moieties on the outer-surface of cucurbit[n] urils as well as ion-dipole interactions between positive portal carbonyl carbon of cucurbit[n] urils and chloride anion from polychlorometallate anions; 4) coordination interaction between hydroxyl groups on the outer-surface of cucurbit[n] urils with metal ions. Based on the characteristics of the supramolecular coordination polymers, they have potential applications in the fields, such as absorption, analysis, separation, isolation, and so on.

Contents
1 Introduction
2 Typical outer-surface interactions of cucurbit[n]urils resulting in the formation of Q[n]s-based coordination polymers
2.1 Electrodonating effect of the alkyl-substituted groups on the outer-surface of cucurbit[n]urils
2.2 π…π stacking between portal carbonyl groups of cucurbit[n]uril as well as C—H…π interaction between methine or methylene moieties on the outer-surface of cucurbit[n]urils and aromatic moiety of organic structure directing agents
2.3 Unusual hydrogen bonding between methine or methylene moieties on the outer-surface of cucurbit[n]urils as well as ion-dipole interactions between positive portal carbonyl carbon of cucurbit[n]urils and chloride anion from polychlorometallate anions
2.4 Coordination interaction between hydroxyl groups on the outer-surface of cucurbit[n]urils with metal ions
3 Potential applications of the supramolecular coordination polymers
4 Conclusion and outlook

Key words: outer-surface interaction of cucurbit[n] urils, structure directing strategies, coordination of cucurbit uril with metal ions, coordination polymers, functional properties

中图分类号: 

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