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化学进展 2008, Vol. 20 Issue (06): 887-898 前一篇   后一篇

• 综述与评论 •

手性咪唑啉酮类有机催化剂催化的不对称反应*

姚成福 孙彩霞 闫少宇 吴海虹**   

  1. (上海华东师范大学化学系 绿色化学与化工过程绿色化重点实验室 上海 200062)

  • 收稿日期:2007-07-25 修回日期:2007-10-17 出版日期:2008-06-24 发布日期:2008-06-24
  • 通讯作者: 吴海虹
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Chiral Imidazolidinones-catalyzed Asymmetric Reactions

Yao Chengfu; Sun Caixia; Yan Shaoyu; Wu Haihong**

  

  1. (Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Chemistry Department of East China Normal University, Shanghai 200062, China)
  • Received:2007-07-25 Revised:2007-10-17 Online:2008-06-24 Published:2008-06-24
  • Contact: Wu Haihong
近年来，不对称有机催化过程日趋成熟，用于越来越多的实际应用。相对于金属催化过程有机胺催化剂具有许多潜在的优势：相对比较稳定，价格较低，容易得到，没有金属泄露到环境或产品中的风险以及对操作环境要求不高等，有机胺已被证明是实现不对称转化的有效手段。手性咪唑啉酮催化剂是有机胺催化剂中的一种类型。本文总结了手性咪唑啉酮催化剂在Diels-Alder反应、1,3-偶极环加成、Michael反应、Friedel-Crafts烷基化等不对称催化反应中的应用研究进展，并对未来手性咪唑啉酮在工业中的应用作了展望。
关键词： 有机催化, 不对称反应, 手性咪唑啉酮, 亚胺离子, 烯胺, 中间体

Enantioselective organocatalytic processes have developed maturely in recent years with an impressive number of applications now available. Aminocatalysis has proven to be a powerful procedure for the enantioselective transformations owing to their potential advantages over metal-catalyzed processes:usually more stable, less expensive, readily available ,no risk of metal leakage into environment or the product, and can be applied in less demanding reaction conditions. Chiral imidazolidinones is an important sort of aminocatalysis. The paper summarizes the applications and advances of chiral imidazolidinones in asymmetric catalytic reactions, such as Diels-Alder reaction, 1,3-dipolar cycloaddition, Michael reaction, Friedel-Crafts alkylation. Moreover, the future applications of chiral imidazolidinones in the industry manufactures are also prospected.

Key words: organocatalysis, asymmetric reactions, chiral imidazolidinones, iminium ions, enamine, intermediate

中图分类号: 

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