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化学进展 2020, Vol. 32 Issue (12): 1879-1884 DOI: 10.7536/PC200408 前一篇   后一篇

• 综述 •

H型聚合物的合成及性质

白阳1,**(), 阎晓晨1, 刘彩萍1, 姚灏2,**()   

  1. 1 陕西科技大学化学与化工学院 陕西省轻化工助剂重点实验室 西安 710021
    2 中南大学土木工程学院 长沙 410075
  • 收稿日期:2020-04-07 修回日期:2020-05-25 出版日期:2021-10-15 发布日期:2020-10-15
  • 通讯作者: 白阳, 姚灏
  • 作者简介:
    ** Corresponding author e-mail: (Yang Bai); (Hao Yao)
  • 基金资助:
    国家自然科学基金项目(No. 21801162)
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Synthesis and Properties of H-Shaped Polymers

Yang Bai1,**(), Xiaochen Yan1, Caiping Liu1, Hao Yao2,**()   

  1. 1 Shaanxi Key Laboratory of Chemical Additives for Industry, College of Chemistry and Chemical Engineering, Shaanxi University of Science and Technology, Xian 710021, China
    2 School of Civil Engineering, Central South University, Changsha 410075, China
  • Received:2020-04-07 Revised:2020-05-25 Online:2021-10-15 Published:2020-10-15
  • Contact: Yang Bai, Hao Yao
  • Supported by:
    the National Natural Science Foundation of China(No. 21801162)

H型聚合物是一种具有轻度支化拓扑结构的高分子,通常具有不同于线型、星型和超支化聚合物的流变性能、本体和溶液组装性能。由于H型聚合物的合成较为复杂,一直以来,科研工作者的工作重点均集中于如何精确合成与构筑,性能研究较为有限。本文根据H型聚合物构筑段的不同从H型均聚物、二元共聚物、三元共聚物、五元共聚物以及其他H型聚合物的合成及性质方面进行了总结和评述,并在此基础上展望了H型聚合物的研究方向和发展趋势。

关键词： H型聚合物, 支化高分子, H型均聚物, H型二元共聚物, H型三元共聚物, H型五元共聚物

H-shaped polymer is one type of polymer with light branched topological structure, which possesses unique rheological properties, bulk and solution assembly behaviors different from linear, star and hyperbranched polymers. In the recent years, researchers mainly focus on how to accurately construct H-shaped polymers due to their complex synthesis process. However, the literatures on H-shaped polymer and their properties are still limited and no review about them is reported. In this article, the synthesis and properties of H-shaped homopolymers, copolymers, terpolymers, quintopolymers and other H-shaped polymers are summarized according to the different building blocks of H-shaped polymers. On this basis, the research trends are also expected based on the progress of this kind of polymer.

Contents

1 Introduction

2 A2AA2-type homopolymer

3 A2BA2-type copolymer

4 A2BC2- and A(B)CA(B)-type terpolymer

5 A(B)CD(E)-type quintopolymer

6 Other H-shaped polymer

7 Conclusion and outlook

Key words: H-shaped polymer, branched polymer, H-shaped homopolymer, H-shaped copolymer, H-shaped terpolymer, H-shaped quintopolymer
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图1 H型聚合物的分类与结构示意图
Fig.1 The classification and structure of different H-shaped polymers
图2 (a) A2AA2型的H型均聚物的合成方法;(b) 聚合后产生的副产物的结构示意图[9]
Fig.2 (a) Synthesis of A2AA2-typed H-shaped polymer;(b) Illustration of structures of the byproducts[9]
图3 通过改变H型聚合物中的组分配比得到的具有不同形态的聚集体(A: 大复合囊泡, B: 多层囊泡)[18]
Fig.3 Aggregates obtained from the self-assembly of the H-shaped polymers with different chain-length ratio(A: Large-compound vesicles, B: Multilayer vesicles)[18]
图4 H型三元共聚物的自组装及其药物控释性能[41]
Fig.4 Self-assembly and drug controlled release of H-terpolymer[41]
图5 通过一锅双点击化学反应合成A(B)CD(E)型聚合物(PEG)(PMMA)-PtBA-(PCL)(PS)的合成[42]
Fig.5 Synthesis of the A(B)CD(E)-typed polymer(PEG)(PMMA)-PtBA-(PCL)(PS) via one-pot double click reactions[42]
图6 基于主客体识别作用构筑的H型超分子聚合物[49]
Fig.6 H-type supramolecular polymer based on host guest recognition[49]
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[1] 赵雅青,董炎明,李珺,黄剑莹,郑饮健,陈小君. 液晶性树状高分子*[J]. 化学进展, 2005, 17(05): 868-875.
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摘要

H型聚合物的合成及性质