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化学进展 2018, Vol. 30 Issue (12): 1874-1886 DOI: 10.7536/PC180315 前一篇   后一篇

• 综述 •

智能响应型超浸润材料

屈孟男*, 袁明娟, 何姣, 薛萌辉, 何金梅*   

  1. 西安科技大学化学与化工学院 西安 710054
  • 收稿日期:2018-03-15 修回日期:2018-07-23 出版日期:2018-12-15 发布日期:2018-09-26
  • 通讯作者: 屈孟男, 何金梅 E-mail:mnanqu@gmail.com;jinmhe@gmail.com
  • 基金资助:
    国家自然科学基金项目（No.21473132）资助
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Smart Responsive Superwetting Materials

Mengnan Qu*, Mingjuan Yuan, Jiao He, Menghui Xue, Jinmei He*   

  1. College of Chemistry and Chemical Engineering, Xi'an University of Science and Technology, Xi'an 710054, China
  • Received:2018-03-15 Revised:2018-07-23 Online:2018-12-15 Published:2018-09-26
  • Supported by:
    The work was supported by the National Natural Science Foundation of China(No.21473132).
近年来，超浸润材料由于自身所具备的各种新颖及优异的性能受到越来越多的关注，在实际生活和工业生产领域中都发挥着举足轻重的作用。但是随着制备技术的不断进步和研究的逐渐深入，现有的单一型的超浸润材料已经不能满足现实生活的各项需求。在此基础上，可响应于外部刺激的超浸润材料，即智能响应型超浸润材料应运而生。本文首先介绍了固体表面润湿性的基础理论，然后根据外部刺激的不同，综述了温度响应型、光响应型、pH响应型和电势响应型等智能响应型超浸润材料的研究与进展，以及从微纳米尺度上揭示表面粗糙度对于达到超浸润转换的重要性，并且对各自的润湿性转换机理与性能进行了总结归纳。最后指出了智能响应型材料存在的问题，并对未来的主要研究方向进行展望。
关键词： 超浸润, 响应, 刺激, 温度, 光照, pH, 电势
In recent years, superwetting materials have received increasing attention because of their novelty and excellent performances, including self-cleaning, anti-fouling, anti-corrosion and oil-water separation, and played an important role in the real life and industry production field. However, with the continuous progress of preparation technology and the gradual deepening of research and exploration, the existing single superwetting materials can no longer meet the needs of real life, such as increasing oil spills, controlled release of drugs and microfluidic devices. On this basis, the superwetting materials that are able to respond to external stimuli, that is, the smart responsive superwetting materials come into being. In this review, basic theories and influence factors of solid surface wettability are introduced firstly. Secondly, according to the difference of external stimuli, the research and progress of the smart responsive superwetting materials, including thermoresponsive, photo-responsive, pH-responsive and electricity-responsive are reviewed. Furthermore, the wettability conversion mechanisms and properties of these smart responsive superwetting materials mentioned in the review are introduced. In order to reveal the importance of roughness to the realization of superwetting conversion, we explain it in micro-and nano-scale. Finally, some existing problems are discussed and the future research directions in this field are proposed.
Contents
1 Introduction
2 Wettability of solid surface
3 Single stimuli-responsive materials
3.1 Thermoresponsive materials
3.2 Photo-responsive materials
3.3 pH-responsive materials
3.4 Electricity-responsive materials
3.5 Solvent-responsive materials
3.6 Other responsive materials
4 Dual-and multiresponsive switchable materials
5 Existing problems
6 Conclusion
Key words: superwetting, responsiveness, stimuli, temperature, light, pH, electricity

中图分类号: 

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摘要

智能响应型超浸润材料