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化学进展 2018, Vol. 30 Issue (9): 1434-1444 DOI: 10.7536/PC171238 前一篇   后一篇

• 综述 •

固体聚合物电解池析氧催化剂

刘亚迪1, 刘锋2, 王诚1*, 赵波2, 王建龙1*   

  1. 1. 清华大学核能与新能源研究院 北京 100084;
    2. 全球能源互联网研究院有限公司 北京 102209
  • 收稿日期:2017-12-26 修回日期:2018-03-26 出版日期:2018-09-15 发布日期:2018-06-28
  • 通讯作者: 王诚, 王建龙 E-mail:wangcheng@tsinghua.edu.cn;wangjl@tsinghua.edu.cn
  • 基金资助:
    国家自然科学基金项目（No.21573122，21773136）、国家重点科研计划（No.2016YFB0101208）和北京市科委项目（No.Z171100002017024）资助
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Oxygen Evolution Catalyst of Solid Polymer Electrolysis

Yadi Liu1, Feng Liu2, Cheng Wang1*, Bo Zhao2, Jianlong Wang1*   

  1. 1. Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084, China;
    2. Global Energy Interconnection Research Institute Co., Ltd., Beijing 102209, China
  • Received:2017-12-26 Revised:2018-03-26 Online:2018-09-15 Published:2018-06-28
  • Supported by:
    The work was supported by the National Natural Science Foundation of China(No. 21573122, 21773136),the National Key Research and Development Program of China (No.2016YFB0101208), and the Beijing Science and Technology Commission Project (No.Z171100002017024).
在固体聚合物电解池电解水制氢过程中，阳极析氧反应是整个电化学反应的速率控制步骤。本文从固体聚合物电解池析氧催化剂的反应机理、催化剂材料以及制备方法等几个方面进行了详细分析。新的检测手段已经开始应用于原子层级的析氧反应机理研究，对析氧反应活性中间产物有了更深刻的认识；通过优化传统的制备工艺，开发新型的制备方法，进一步提高了析氧催化剂的活性或者稳定性。此外，引入高稳定性、低成本、高活性的催化载体，亦可提高催化剂的性能并相应地降低其成本。希望通过本文的综述总结，为今后阳极析氧催化剂的研究指明方向，推动固体聚合物电解池的商业化进程。
关键词： 电解水技术, 固体聚合物电解池, 氧析出反应, 催化剂, 合成方法
In the process of producing hydrogen by water electrolysis with Solid Polymer Electrolyte(SPE), anodic oxygen evolution reaction(OER) is the rate-determining step of the whole electrochemical reaction. The progress of the state-of-the-art for the SPE technology in terms of oxygen evolution reaction(OER) mechanism, catalyst materials and its synthesis method are recommended. It is pointed out that new detection methods can analyze OER reaction mechanism and study the intermediate activity products at atomic level. Optimization of the traditional synthesis method and the development of the new method can improve the catalysts performance. In addition, introducing high stability, low cost and high activity carrier material can also improve the performance of catalyst and reduce its cost accordingly. It is hoped that our paper will give a clear direction for the future research of anode catalysts and promote the commercialization of the SPE electrolysis.
Contents
1 Introduction
2 SPE catalyst
2.1 OER mechanism
2.2 Catalyst materials
2.3 Preparation methods
3 Conclusion and outlook
Key words: electrolysis water technology, solid polymer electrolyte, oxygen evolution reactions, catalyst, synthesis method

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摘要

固体聚合物电解池析氧催化剂