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化学进展 2016, Vol. 28 Issue (1): 83-90 DOI: 10.7536/PC150742 前一篇   后一篇

• 综述与评论 •

重金属离子印迹技术

傅骏青1,2, 王晓艳2,3, 李金花2, 陈令新1,2*   

  1. 1. 曲阜师范大学化学与化工学院 山东省生命有机分析重点实验室 曲阜 273165;
    2. 中国科学院烟台海岸带研究所 中国科学院海岸带环境过程与生态修复重点实验室 山东省海岸带环境过程重点实验室 烟台 26400;
    3. 滨州医学院药学院 烟台 264003
  • 收稿日期:2015-07-01 修回日期:2015-08-01 出版日期:2016-01-15 发布日期:2015-12-21
  • 通讯作者: 陈令新 E-mail:lxchen@yic.ac.cn
  • 基金资助:
    国家自然科学基金项目(No.21275158,21477160)资助
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导出 被引次数 ( 28 | 11 )

Ion Imprinting Technology for Heavy Metal Ions

Fu Junqing1,2, Wang Xiaoyan2,3, Li Jinhua2, Chen Lingxin1,2*   

  1. 1. Key Laboratory of Life-Organic Analysis of Shandong Province, College of Chemistry and Chemical Engineering, Qufu Normal University, Qufu 273165, China;
    2. Key Laboratory of Coastal Environmental Processes and Ecological Remediation, Yantai Institute of Coastal Zone Research (YIC), Chinese Academy of Sciences (CAS), Shandong Provincial Key Laboratory of Coastal Environmental Processes, Yantai 26400;
    3. School of Pharmacy, Binzhou Medical University, Yantai 264003, China
  • Received:2015-07-01 Revised:2015-08-01 Online:2016-01-15 Published:2015-12-21
  • Supported by:
    The work was supported by the National Natural Science Foundation of China(No. 21275158, 21477160).
分子印迹技术(molecular imprinting technology,MIT)是指制备对特定目标分子具有专一识别性能的聚合物技术。离子印迹技术(ion imprinting technology,IIT)以离子为模板,通过静电作用、配位作用等与单体结合形成螯合物,聚合后用酸性试剂等将模板离子洗脱,最终制得具有与目标金属离子相对应的三维孔穴结构的印迹材料。作为分子印迹技术的重要分支,离子印迹技术因存在配位作用而具有很多优势,近年来得到了快速的发展。重金属离子是离子印迹领域最典型且最受关注的目标物。本文介绍了离子印迹技术原理、制备及其在金属的痕量和超痕量分析中的优势,针对环境监测中典型重金属污染离子(铅、汞、铜、镉、铬、砷)的印迹聚合物应用进行了简述,并对金属离子印迹技术未来的挑战与发展作出了展望。
关键词： 离子印迹, 特异性识别, 重金属, 配位作用
Molecular imprinting technology(MIT) is known as a technology for creation of tailor-made binding sites with memory of the shape, size and functional groups of the template molecules. Ion imprinting technology is the technology that creating three-dimensional cavity structures in a polymer matrix, i.e., ion imprinting polymers (IIPs) by the copolymerization of functional monomers and cross-linkers in the presence of target ion that act as template molecules based on coordination or electrostatic interactions. After removal of the template ion with acidic reagent, recognition cavities complementary to the template ion were formed in the highly cross-linked polymer matrix. Owing to the special coordination, ion imprinting technology, as an important branch of MIT, obtained the rapid development. Heavy metal ion as the most typical water-soluble ion, has gained increasing concerns. So, effective identification and quantification of heavy metal ions by using ion imprinting polymers are highly crucial. The principles, synthesis strategies of ion imprinting and advantages on analysis of trace and ultra-trace metal are introduced in the review.Then, the applications of ion imprinted polymers for typical heave metal ions from environmental monitoring including lead, mercury, copper, cadmium, chromium and arsenic ions are summarized. Finally, the challenges and possible solution strategies, and future trends are proposed.

Contents
1 Introduction
2 Ion imprinting technology
2.1 Principles of ion imprinting
2.2 Preparation of ion imprinting
2.3 Superiority
3 Typical heave metal ion imprinted polymers and their applications
3.1 Pb-IIPs
3.2 Hg-IIPs and CH3Hg-IIPs
3.3 Cu-IIPs
3.4 Cd-IIPs
3.5 Cr-IIPs
3.6 As-IIPs
4 Conclusion and outlook

Key words: ion imprinting, specific recognition, heave metal, coordination

中图分类号: 

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摘要

重金属离子印迹技术