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化学进展 2013, Vol. 25 Issue (12): 2147-2158 DOI: 10.7536/PC130446 前一篇   后一篇

• 综述与评论 •

功能化纳米Fe3O4磁性材料的制备及其对水中重金属离子的去除

谭丽莎, 孙明洋, 胡运俊, 程丽华, 徐新华*   

  1. 浙江大学环境工程系 杭州 310027
  • 收稿日期:2013-04-01 修回日期:2013-06-01 出版日期:2013-12-15 发布日期:2013-09-17
  • 通讯作者: 徐新华 E-mail:xuxinhua@zju.edu.cn
  • 基金资助:

    国家自然科学基金项目（No.21277119）和浙江省公益性技术应用研究计划项目（No.2012C23061）资助

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Heavy Metal Removal from Aqueous Solution by Functional Magnetic Fe3O4 Nanoparticles

Tan Lisha, Sun Mingyang, Hu Yunjun, Cheng Lihua, Xu Xinhua*   

  1. Department of Environmental Engineering, Zhejiang University, Hangzhou 310027, China
  • Received:2013-04-01 Revised:2013-06-01 Online:2013-12-15 Published:2013-09-17

重金属污染是目前最为严峻的环境污染问题之一。利用新颖、高效、易分离再生的功能化磁性纳米材料去除水中的重金属，已越来越受到研究者的关注。本文综述了国内外功能化纳米Fe3O4磁性材料的制备方法及其对水中重金属离子去除的研究进展，重点阐述了针对不同重金属离子去除的纳米Fe3O4磁性材料氨基化（—NH2）、巯基化（—SH）、羧基化（—COOH）及其他功能化的表面修饰材料、修饰方法及其应用，并比较了目前应用于水中重金属离子去除的功能化纳米Fe3O4磁性材料制备方法的优缺点，简要讨论了功能化纳米Fe3O4磁性材料对重金属离子去除的影响因素以及机理。最后，对功能化纳米Fe3O4磁性材料去除水中重金属离子研究的未来发展方向进行了展望。

关键词： Fe3O4, 重金属, 磁性纳米材料, 功能化

Contamination of natural water with heavy metals is a significant global issue. Heavy metals removal from aqueous solution by functional magnetic Fe3O4 nanoparticles, characterized in low cost, high efficiency, easiness of separation and regeneration, has received increasing attention in recent years. In this work, the advances on heavy metals removal by functional magnetic Fe3O4 nanoparticles are reviewed. The surface modification materials, synthesis methods, including amino-functionalization, thiol-functionalization, carboxy-functionalization and other functionalizations, and application of functional magnetic Fe3O4 nanoparticles applied for heavy metals removal are elaborated. The advantages and disadvantages of synthesis of functional magnetic Fe3O4 nanoparticles are further compared, and the influencing factors and mechanisms of heavy metals removal by functional magnetic Fe3O4 nanoparticles are briefly discussed. Finally, the suggestions on further study of heavy metals removal by functional magnetic Fe3O4 nanoparticles are presented.

Contents
1 Introduction
2 Synthesis and application of functional magnetic Fe3O4 nanoparticles for heavy metals removal from wastewater
2.1 Amino-functionalization
2.2 Thiol-functionalization
2.3 Carboxy-functionalization
2.4 Other functionalizations
3 Influencing factors of heavy metals removal by functional magnetic Fe3O4 nanoparticles
3.1 pH
3.2 Natural organic matter
3.3 Ionic strength
3.4 Competitive ions
3.5 Particle size
4 Mechanisms of heavy metals removal by functional magnetic Fe3O4 nanoparticles
5 Outlook

Key words: Fe3O4, heavy metals, magnetic nanoparticle materials, functionalization

中图分类号: 

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