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化学进展 2010, Vol. 22 Issue (04): 748-753 前一篇   后一篇

• 综述与评论 •

微生物电解电池制氢*

郭坤1,2;张京京3;李浩然1**;杜竹玮1   

  1. (1. 中国科学院过程工程研究所生化工程国家重点实验室     北京 100190; 2. 中国科学院研究生院    北京 100049; 3.北京科技大学土木与环境工程学院     北京 100083)
  • 收稿日期:2009-04-30 修回日期:2009-05-25 出版日期:2010-04-24 发布日期:2010-03-30
  • 通讯作者: 李浩然 E-mail:hrli@home.ipe.ac.cn
  • 基金资助:

    国家自然科学基金项目;国家高技术研究发展计划(863)基金

Hydrogen Production by Microbial Electrolysis Cells

Guo Kun1,2; Zhang Jingjing3; Li Haoran1**; Du Zhuwei1   

  1. (1. State Key Laboratory of Biochemical Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China; 2. Graduate University of Chinese Academy of Sciences, Beijing 100049, China; 3. School of Civil and Environmental Engineering, University of Science and Technology Beijing, Beijing 100083, China)
  • Received:2009-04-30 Revised:2009-05-25 Online:2010-04-24 Published:2010-03-30
  • Contact: Li Haoran E-mail:hrli@home.ipe.ac.cn
  • Supported by:

    National Natural Science Foundation of China

在微生物燃料电池(MFC)的基础上发展而来的微生物电解电池(MEC)为生物制氢提供了一种全新的方法。本文综述了自2005年MEC发明以来取得的研究进展。简要介绍了MEC制氢的基本原理和系统的评价参数;比较了不同MEC系统结构和电极材料对体系产氢效能的影响;讨论了MEC制氢实际应用中存在问题和限制因素;提出了MEC制氢今后的研究思路和发展趋势;展望了MEC在利用生物质制氢和有机废水资源化利用中的应用前景。

Microbial electrolysis cells (MEC) invented on the basis of Microbial fuel cells (MFC) provide a novel method for biohydrogen production. This paper reviews the research progress of MEC ever since its invention in 2005. The principle of MEC and the evaluating parameters of system are briefly introduced. Hydrogen production performance of MEC at different system architectures and electrode materials are compared. The existing problems and limiting factors of MEC for its practical utilization are discussed and the future research trends, as well as research approaches of MEC are proposed. Finally, the prospective applications of MEC in hydrogen production from biomass and energy recovery from organic wastewater are also stated.

Contents
1 Introduction
2 Principle of MEC
3 Evaluating parameters of MEC
3.1 Hydrogen yield
3.2 Hydrogen recovery
3.3 Energy recovery
4 The architecture of MEC
5 The electrode materials of MEC
5.1 Anodic materials
5.2 Cathodic materials
6 Conclusion and outlook

中图分类号: 

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微生物电解电池制氢*