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Progress in Chemistry 2001, Vol. 13 Issue (02): 128- Previous Articles   Next Articles

• Review •

Investigation on the Catalysts and Reaction Process for the Methanol Synthesis at Lower-Temperature in Liquid Phase

Chu Wei;Wu Yutang;Luo Shizhong;Bao Xinhe;Lin Liu   

  1. Chengdu Institute of Organic Chemistry, Chinese Academ y of Sciences, Chengdu 610041, China Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China"
  • Received: Revised: Online: Published:
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The history and development of methanol synthesis at lower temperature in liquid phase(MSLTLP), the research situations,and the present key problems of the technology to be solved are reviewed in this paper. The following topics are especially discussed: the catalyst systems, active sites, reaction pathways and processes, reaction mechanism and catalyst deactivation mechanism , the catalytic recycle and regeneration. Comparing the tradit ional techniques for methanol synthesis, there are a few advantages for the MSLTLP method: the high simple pass conversion (more than 90% ) , the low production cost, the high grade product quality, the mild and temperate reaction conditions. 36 references are cited.

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[ 1 ] Amenokmiya Y. Appl. Catal. , 1987, 30 (1) : 57
[ 2 ] 蔡启瑞, 彭少逸等. 碳一化学中的催化作用. 北京: 化学工业出版社, 1995. 520
[ 3 ] Natta G, Pino P, Pasquon I, et al. Chemicae Industria, 1993,35: 705
[ 4 ] Waugh K C. Catal. Today, 1992, 15: 51
[ 5 ] Hutchings G J , Scurrell M S, et al. Catal. Today, 1992, 15: 23
[ 6 ] Chinchen G C, Waugh K C, et al. Appl. Catal. , 1986, 25: 101
[ 7 ] Kung H H, Catal. Rev. , 1980, 22: 235
[ 8 ] 吴玉塘(Wu Y T) , 罗仕忠(Luo S Z) , 贾朝霞(Jia Z X) 等. 石油化工(Petrochem. Tech. ) , 1993, 22 (1) : 10- 14
[ 9 ] Palekar V M , Tierney J W , Wender I. Appl. Catal. A , 1993,103: 105
[ 10 ] Marchionna M , Laimi M , et al. Chemtech, 1997,April: 27
[ 11 ] 刘兴泉(Liu X Q ) , 吴玉塘(Wu Y T) , 罗仕忠(Luo S Z) 等. 催化学报(Journal of Catalysis) , 1999, 20 (1) : 81
[ 12 ] 王逸凝(Wang Y N ) , 赵玉龙(Zhao Y L ). 天然气化工(Natural Gas Chemical Industry) , 1998, 23 (3) : 47
[ 13 ] Tierney J W , Wender I, Palekar V M. U S 5 385 949, 1995
[ 14 ] Marchionna M , Lami M. EP 0 504 981, 1992
[ 15 ] 吴玉塘, 陈文凯, 罗仕忠等. 中国发明专利, CN 1 136 979A ,1996
[ 16 ] 吴玉塘, 罗仕忠, 刘兴泉等. 中国发明专利, 97 1 076 626, 1997
[ 17 ] 储伟, 何川华, 吴玉塘等. 中国发明专利, 00 1 12 727. 6
[ 18 ] 储伟, 王奎铃, 吴玉塘等. 中国发明专利, 00 1 12 726. 8
[ 19 ] 何川华(He C H) , 储伟(Chu W ) , 罗仕忠(Luo S Z) 等. 天然气化工(Natural Gas Chemical Industry). 2000, 25 (3) : 31- 44
[ 20 ] 王奎铃, 储伟, 何川华等. 石油化工, 2001 年已接收
[ 21 ] Trimm D L , Wainwright M S. Catal. Today, 1990, 6: 261
[ 22 ] Mahajian D, Spienza R S, et al. U S 4 935 395, 1990
[ 23 ] Marchionna M , Lami M , EP 375 071, 1990
[ 24 ] Liu X Q , Wu Y T, et al. Stud. Surf. Sci. Catal. , 1998, 119:557
[ 25 ] 吴玉塘, 罗仕忠, 刘兴泉等. 油气加工, 1999, 9 (1) : 8
[ 26 ] Sugiyama H, Takaashi K, Usaka H, EP 676 239, 1995
[ 27 ] Braca G, Lami M. Marchionna M. J. Mol. Catal. , 1995, 95:19
[ 28 ] Wu Y T, et al. J. Nat. Gas. Chem. , 1990, 8 (2) : 115
[ 29 ] 梁国华(Liang G H). 硕士学位论文(M S Dissertation) , 中国科学院成都有机化学研究所(Chengdu Institute of Organic Chemisty) , 1997
[ 30 ] Liu X Q , Wu Y T, Luo S Z, et al. J. Nat. Gas. Chem. , 1990:8 (2) : 115
[ 31 ] 杨迎春(Yang Y C) , 吴玉塘(Wu Y T). 天然气化工(Natural Gas Tech. ) , 1997, 22 (5) : 39
[ 32 ] 陈文凯(Chen W K). 博士学位论文(Doctoral Dissertation) ,中国科学院成都有机化学研究所(Chengdu Institute of Organic Chemistry) , 1997
[ 33 ] Keim W , Falter W. Catal. Lett. , 1989, 3: 59
[ 34 ] Clarke D B, Bell A T, et al. J. Catal. , 1994, 150: 261
[ 35 ] 杨迎春(Yang Y C). 硕士学位论文(M S Dissertation) , 中国科学院成都有机化学研究所(Chengdu Institute of Organic Chemistry) , 1998
[ 36 ] 吴玉塘等. 中科院“九五" 计划特别支持项目课题进展报告,1998. 12.

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