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化学进展 DOI: 10.7536/PC220543 前一篇   后一篇

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自修复有机硅材料的制备策略

叶娟1, 林子谦1, 李伟健1, 向洪平1,*, 容敏智2, 章明秋2   

  1. 1.广东工业大学材料与能源学院 广东省功能软凝聚态物质重点实验室 广州 510006;
    2.中山大学化学学院 广东省高性能树脂基复合材料重点实验室 聚合物复合材料及功能材料教育部重点实验室 广州 510275
  • 收稿日期:2022-05-31 修回日期:2022-06-30 出版日期:2022-09-19 发布日期:2022-09-19
  • 基金资助:
    国家自然科学基金项目（No.52033011）和广东省基础与应用基础研究基金项目（No.2022A1515011972）资助; 作者简介：向洪平,博士,2018年以“特聘副教授”入职广东工业大学材料与能源学院,2017年在美国罗格斯大学访问学者,2015年博士毕业于中山大学化学化工学院高分子物理与化学专业; 主要研究方向为可自修复和可塑再生聚合物材料,高性能（水性）光敏树脂等; 在科研上,主持科研课题10余项,其中国家自然科学青年基金项目1项,省部级项目3项,产学研项目7项,以第一或通讯作者发表SCI论文30篇,共申请发明专利10余件,已授权发明专利5件
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Fabrication Strategies to Self-healing Silicone Materials

Juan Ye1, Ziqian Lin1, Weijian Li1, Hongping Xiang1,*, Minzhi Rong2, Mingqiu Zhang2   

  1. 1. Guangdong Provincial Key Laboratory of Functional Soft Condensed Matter, School of Materials and Energy, Guangdong University of Technology, Guangzhou 510006, China;
    2. Key Laboratory for Polymeric Composite and Functional Materials of Ministry of Education, Key Laboratory of High Performance Polymer Based Composites of Guangdong Province, School of Chemistry, Sun Yat-sen University, Guangzhou 510275, China
  • Received:2022-05-31 Revised:2022-06-30 Online:2022-09-19 Published:2022-09-19
  • Contact: *e-mail: xianghongping@gdut.edu.cn
  • Supported by:
    National Natural Science Foundation of China (No.52033011) and Guangdong Basic and Applied Basic Research Foundation (No.2022A1515011972).
近年来,通过仿生生命体自我修复损伤这一现象而研制的自修复材料,可有效延长材料的使用寿命、提高材料的使用安全性、降低资源浪费,具有巨大的发展潜力。其中,自修复有机硅材料因兼具自我修复的功能和有机硅材料优异的性能,已成为当下的研究热点。由于外界刺激条件如紫外光、温度等是材料实现损伤自我修复的外在驱动力,在很大程度上影响着材料的修复效能,且不同的刺激条件具有不同的优缺点和应用领域。因此,本文将基于自修复过程中外界刺激因素的不同,对自修复有机硅材料尤其是近五年来的最新研究成果进行综述,从外援型和本征型自修复有机硅材料两方面入手,以本征型自修复有机硅材料为重点,并对自修复有机硅材料今后的发展进行了分析展望。
关键词： 有机硅材料, 自修复, 刺激-响应因素, 动态非共价键, 动态共价键
In recent years, inspired by the natural phenomenon that the living organism can automatically repair its damaged skin and bone via itself metabolism, researchers have successfully developed self-healing materials that can self-heal their microcracks. The self-healing of materials can effectively extend the service life of materials, improve working stability and thus reduce the waste of resources. Recently, the self-healable silicone materials originated from the synergistic combination of self-healing function and good properties of silicone materials, have become a research focus in functional materials. Furthermore, since the external stimuli such as UV irradiation, temperature and solvent are the external driving force for materials to fulfill self-healability, and affect largely the self-healing efficiency. More importantly, different stimuli have different advantages and disadvantages, and application fields. Therefore, this study aims to summarize and analyze the research progress of external and intrinsic self-healing silicone materials especially in the past five years according to their external stimuli. The intrinsically self-healing silicone materials that contain different dynamic polysiloxane crosslinking networks activated by different external stimuli, are emphatically discussed. Additionally, a brief prospect for the future development of self-healing silicone materials is also provided.
Key words: silicone materials, self-healing, stimulus-response factor, dynamic non-covalent bond, dynamic covalent bond

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[1] 叶娟, 林子谦, 李伟健, 向洪平, 容敏智, 章明秋. 自修复有机硅材料的制备策略[J]. 化学进展, 2023, 35(1): 135-156.
[2] 侯瑞, 李桂群, 张岩, 李明俊, 周桂明, 柴晓明. 基于超分子聚合物的自修复材料[J]. 化学进展, 2019, 31(5): 690-698.
[3] 程龙, 于大江, 尤加健, 龙腾, 陈素素, 周传健. 有机硅自修复材料[J]. 化学进展, 2018, 30(12): 1852-1862.
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自修复有机硅材料的制备策略