Song Jie1|Wu Qihui2**,Dong Quanfeng1**|Zheng Mingsen1|Wu Suntao3|Sun Shigang1. Solid-State Thin Film Li-ion Batteries[J]. Progress in Chemistry, 2007, 19(01): 66-73.
Zhou Henghui,Ci Yunxiang,Liu Changyan. Progress in Studies of the Electrode Materials for Li- Ion Batteries[J]. Progress in Chemistry, 1998, 10(01): 85-.
This paper reviews the relationship between synthesis, structures and properties of intercalation electrodes with layered LixMO2 and spinel LixM2O4 structures (M = Co、Ni、Mn、V ) as cathodes, and graphite, disordered carbon and metal oxide as anodes in Li ion batteries. Emphasisis focused on the structural properties of intercalation electrode materials which are related to the rechargeable capacity and stability during cycling of Li ions. 118 references are given.
Zhang Zhongru,Yang Yang**,Liu Hansan. Progress in Solid-State NMR Strudies of Electrode Materials for Lithium Ion Batteries[J]. Progress in Chemistry, 2003, 15(01): 18-.
Zuo Xiaoxi*,Li Weishan,Liu Jiansheng. Research Progress on Compatibility of Non-aqueous Electrolytes with Electrodes in Li-ion Battery[J]. Progress in Chemistry, 2003, 15(06): 441-.
Zhou Defeng, Zhao Yanling, Hao Jie, Ma Yue,Wang Rongshun*. Studies on Nanometer Anode Materials for Lithium Ion Batteries[J]. Progress in Chemistry, 2003, 15(06): 445-.
Ni Jiangfeng1,2,Zhou Henghui*1,Chen Jitao1,Su Guangyao2. Progress in Solid Electrolyte Interface in Lithium Ion Batteries[J]. Progress in Chemistry, 2004, 16(03): 335-.
Ni Jiangfeng,Su Guangyao*,Zhou Henghui*,Chen Jitao. Study of LiMPO4 as Cathode Material for Lithium Ion Batteries[J]. Progress in Chemistry, 2004, 16(04): 554-.
. Progress in Capacity Fade Mechanism of Lithium Ion Battery[J]. Progress in Chemistry, 2005, 17(01): 1-7.
Capacity fade is an obstacle to commercialize the lithium manganese oxide spinel . Unwanted side reac2 tions due to active material dissolution ,electrolyte decomposition ,passive filmformation ,and other phenomeana occur dur2 ing overcharge of overdischarge and cause the capacity loss or fade in these bateeries. The recent advances in capacity fade mechanisms of the spinel Li2Mn2O are reviewed , and different mechanisms are discussed and summarized. Some methods to reduce capacity fade and the development of the spinel Li2Mn2O are proposed.
. Compositions , Structures and Properties of Polymer Electrolytes for Lithium Ion Battery[J]. Progress in Chemistry, 2005, 17(02): 248-253.
Polymer electrolyte is one of the most important compositions of solid state lithium ion batteries and the conductivity of polymer electrolytes has prodigious effect on the properties of the lithium ionic batteries. The recent progress of the compositions , structures and properties of polymer electrolytes influencing the conductivity of lithium ion batteries is reviewed. Especially the progress in polymer2based alkali metal salt electrolytes and ionomer polymer electrolytes is introduced.
Xue Zhaoming1,2**,Chen Chunhua1. Progress in Studies of Lithium Salts for Li-Ion Battery in Nonaqueous Electrolytes[J]. Progress in Chemistry, 2005, 17(03): 399-405.
Ren Jianguo1**,Wang Ke1,He Xiangming1,Jiang Changyin1,Wan Chunrong1,Pu Weihua2. Studies of Alloy Based Anode Materials for Lithium Ion Batteries[J]. Progress in Chemistry, 2005, 17(04): 597-603.
Shi Zhicong,Yang Yong**. Progress in Polyanion-Type Cathode Materials for Lithium Ion Batteries[J]. Progress in Chemistry, 2005, 17(04): 604-613.
Xiangming He,Weihua Pu,Li Wang,Changyin Jiang,Chunrong Wan. Plastic Crystals: An Effective Ambient Temperature All-Solid-State Electrolyte for Lithium Batteries[J]. Progress in Chemistry, 2006, 18(01): 24-29.
Zhijun Ling,Xiangming He*,Jianjun Li,Changyin Jiang,Chunrong Wan. Recent Advances of All-Solid-State Polymer Electrolyte for Li-Ion Batteries[J]. Progress in Chemistry, 2006, 18(04): 459-466.
Yuhong Chen1,Zhiyuan Tang1**,Xinghe Lu1,2,Caiyuan Tan1. Research of Explosion Mechanism of Lithium-Ion Battery[J]. Progress in Chemistry, 2006, 18(06): 823-831.
Ximin Wang Xianyou Wang Xufang Luo Li Liao . Progress on LiCo1/3Ni1/3Mn1/3O2 as Cathode Materials of Lithium-Ion Battery[J]. Progress in Chemistry, 2006, 18(12): 1720-1724.
Weihua Pu Xiangming He Li Wang Chunrong Wan Changyin Jiang . Recent Progress in LiBOB-based Electrolyte for Lithium Batteries[J]. Progress in Chemistry, 2006, 18(12): 1703-1709.
Haipeng Zhao Xiangming He Changyin Jiang Chunrong Wan . Recent Advance of Tin-Based Alloy Anodes for Lithium Ion Batteries[J]. Progress in Chemistry, 2006, 18(12): 1710-1719.
Li Shiyou1,2*|Ma Peihua1,Teng Xiangguo1,2 |Li Faqiang1 |Ren Qidu1,2. A New Type of Lithium Salt Used as Electrolyte Salt of Lithium Ion Battery–Lithium Bis(oxalate)borate[J]. Progress in Chemistry, 2007, 19(05): 695-699.
Zhao Jishi,Wang Li,He Xiangming*,Jiang Changyin,Wan Chunrong . Transport Properties of Lithium-ion of Electrolyte Used in Lithium-ion Batteries[J]. Progress in Chemistry, 2007, 19(10): 1467-1474.
Tang Aidong,Wang Haiyan,Huang Kelong**,Tan Bin,Wang Xiaoling.. Layered Li-Ni-Co-Mn-O as Cathode Materials for Lithium Ion Battery[J]. Progress in Chemistry, 2007, 19(9): 1313-1321.
Ren Manman|Zhou Zhen**|Gao Xueping| Yan Jie. Core-shell Materials for Lithium Ion Batteries[J]. Progress in Chemistry, 2008, 20(05): 771-777.
Liang Feng** |Dai Yongnian|Yi Huihua|Xiong Xue
gepin yin pengjian zuo. Progress on First Principle Calculations of Cathode in Li-Ion Batteries[J]. Progress in Chemistry, 2008, 20(11): 1827-1833.
. Safety-Enhancing Additives for Lithium Ion Batteries[J]. Progress in Chemistry, 2009, 21(04): 629-636.
Electrolyte plays important roles on the performances of lithium ion batteries (LIB). Much attention has been attracted to the investigation of functional additives to the organic electrolytes in recent years. This paper is intended to review the recent progresses on the study of safety-enhancing additives including flame retardants to the commercially avaliable carbonates-based electrolytes and overcharge protection(such as redox shuttles, potential-sensitive and temperature-sensitive) additives to the electrode as well as to the electrolytes for lithium ion batteries. The research status and the perspectives of each type of the additives are commented after an introduction to their operational mechanisms and electrochemical performances.
Contents 1 Introduction 2 Flame-retardant additives 2.1 Flame-retardant mechanism 2.2 Flame-retardant additives 3 Overcharge protection additives 3.1 Redox shuttle additives 3.2 Potential-sensitive additives 3.3 Temperature-sensitive additives 4 Conclusions
Sun Wanning Ying Jierong Huang Zhenlei Jiang Changyin Wan Chunrong. Organic Sulfide Electrode Materials for Lithium-Ion Batteries[J]. Progress in Chemistry, 2009, 21(09): 1963-1968.
Recent progress in research on organic sulfide electrode materials for lithium-ion batteries, which are new type cathode materials with high specific capacity, including organodisulfide, organomultisulfide and sulfurized polymers, is introduced. Organic sulfides are of electrochemical activity due to the chemical reversibility of S-S oxidation and reduction reactions. In this paper the advantages and shortcomings of the electrode materials are discussed, and their development are also previewed. In addition, improving the specific capacity and cycling stability of the materials should be the research priorities.
Contents 1 Introduction 2 Organodisulfide 2.1 Polydisulfide 2.2 Dithiopolymers 3 Organomultisulfide 4 Sulfurized Polymers 5 Conclusion
Xu Mengqing Xing Lidan Li Weishan. Additives of Interphase Film Formation for Lithium Ion Batteries[J]. Progress in Chemistry, 2009, 21(10): 2017-2027.
The progress on additives of interphase films formed on anode/electrolyte and cathode/electrolyte interphases for lithium ion batteries is reviewed in this paper. On the basis of summarization of the mechanism of SEI film formation on anode surface, the performance of additives is reviewed and evaluated from two different SEI formation mechanisms, modification film mechanism and formation film mechanism, respectively. The drawback and challenge of SEI film formation additives are also illustrated. In addition, the mechanism and the progress of additives on cathode/electrolyte interphase are basically introduced. At the end of the paper, the application of theoretical calculation methods on interphase film is basically reviewed, and the application of theoretical calculation methods on the designation and optimization of new additives is also prospected.
Contents 1 Introduction 2 Progress of formation process and characterization of interphase films 2.1 SEI of anode/electrolyte 2.2 Additives of interphase film formation on cathode/electrolyte 3 The application of theoretical calculation method on interphase film 3.1 The application of theoretical calculation method on the mechanism of interphase film formation 3.2 The application of theoretical calculation method on the mechanism and designation of additives of interphase film formation 4 Conclusion and prospect
Chen Jingbo Zhao Hailei He Jianchao Wang Mengwei. Si-Based Composite Anode Materials for Lithium Ion Batteries[J]. Progress in Chemistry, 2009, 21(10): 2115-2122.
As a kind of promising anode material for lithium ion batteries, silicon-based materials have been attracted much attention. The poor cycling stability due to the huge volume change during lithiation and delithiation and the low initial coulombic efficiency are the critical problems that limit their commercial application. Nanocrystallization, alloying and carbon-coating are effective measures to solve these issues. This article reviews the progress in silicon/compound composites in which TiB2, TiN and TiC act as the matrices, silicon-metal composites including Fe-Si, Cu-Si and Ni-Si, and silicon/carbon composites. In respect of the research on silicon/carbon composites, emphasis is put on the preparation methods like pyrolysis, milling, milling-pyrolysis and chemical polymerization, and the carbon sources such as polypyrrole, polyvinylchloride(PVC), polyacrylonitrile(PAN), resorcinol-formaldehyde resin, citric acid and epoxy resin. In addition, the progress in Si/carbon nanotubes composite materials is also discussed.
Contents 1 Introduction 2 Si-compound composites 3 Si-metal composites 3.1 Si-Fe composites 3.2 Si-Cu composites 3.3 Si-Ni composites 4 Si/C composites 4.1 Si/C composites prepared by pyrolysis 4.2 Si/C composites prepared by ball-milling 4.3 Si/C composites prepared by ball-milling and pyrolysis 4.4 Si/C composites prepared by other methods 4.5 Si/carbon nanotubes 5 Conclusions
Liang Feng Dai Yongnian Yao Yaochun. Template-Directed Method Synthesis of Porous Materials for Lithium-Ion Batteries[J]. Progress in Chemistry, 2009, 21(10): 2060-2066.
Template-direct method provides a new approach of synthesizing porous materials for lithium-ion batteries and has currently become one of the most popular topics in the materials preparation. The latest progress in template-direct method synthesis lithium-ion batteries materials is reviewed in details. The principle, classification and procedure of this method are described. Finally, the characteristics and some questions of porous materials for lithium-ion batteries are discussed. The research trends of this field are brought forward.
Contents 1 Introduction 2 The outline of template-directed method 3 Template-directed method synthesis of cathode materials for lithium-ion batteries 3.1 Template-directed method synthesis of lithium cobalt oxide 3.2 Template-directed method synthesis of lithium manganese oxide 3.3 Template-directed method synthesis of lithium iron phosphate 3.4 Template-directed method synthesis of other cathode materials 4 Template-directed method synthesis of anode materials for lithium-ion batteries 4.1 Template-directed method synthesis of carbon 4.2 Template-directed method synthesis of titanium oxide 4.3 Template-directed method synthesis of tin oxide 4.4 Template-directed method synthesis of other anode materials 5 Conclusion
Yu Feng Zhang Jingjie Wang Changyin Yuan Jing Yang Yanfeng Song Guangzhi. Crystal Structure and Electrochemical Performance of Lithium Ion Battery Cathode Materials[J]. Progress in Chemistry, 2010, 22(01): 9-18.
As the important building blocks of lithium ion battery, cathode materials provide all extracting/inserting Lithium ions. Electrochemical performance of lithium ion battery is affected by the different way of Lithium ion migration in crystal structure of cathode materials. In this paper, the relationship of crystal structure, lithium ion migration way and electrochemical performance are reviewed in detail in terms of crystal structure: one-, two- and three-dimension. These cathode materials are mainly olivine-structured LiFePO4,α-NaFeO2 layered LiMO2 (M=Co, Ni, Mn),monoclinic structured Li1+xV3O8,orthogonal structured Li2MSiO4 (M=Fe, Mn),spinel structured LiMn2O4 and nascion structured Li3V2(PO4)3. Moreover,we discuss the present situation and challenges that remain regarding the lithium ion battery, and highlight ongoing research strategies on cathode materials.
Contents 1 Introduction 2 Lithium ion battery cathode materials 3 One-dimension cathode materials 3.1 Olivine-structured phosphates LiFePO4 3.2 Electrochemical performance ameliorations 4 Two-dimension cathode materials 4.1 α-NaFeO2 layered LiMO2 (M=Co, Ni, Mn) 4.2 Monoclinic structured Li1+xV3O8 4.3 Orthogonal structured Li2MSiO4 (M=Fe, Mn, Co) 5 Three-dimension cathode materials 5.1 Spinel structured LiMn2O4 5.2 NASCION structured Li3V2(PO4)3 6 Conclusion