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化学进展 2016, Vol. 28 Issue (8): 1186-1195 DOI: 10.7536/PC160342 前一篇   后一篇

• 综述与评论 •

氧化石墨烯/金银纳米粒子复合材料的制备及其SERS效应研究

郝锐1,2, 张丛筠1,2*, 卢亚1,2, 张东杰1,2, 郝耀武3, 刘亚青1,2   

  1. 1. 中北大学 纳米功能复合材料山西省重点实验室 太原 030051;
    2. 中北大学材料科学与工程学院 太原 030051;
    3. 德克萨斯大学阿灵顿分校材料科学与工程系 阿灵顿 76019
  • 收稿日期:2016-03-01 修回日期:2016-05-01 出版日期:2016-08-15 发布日期:2016-07-12
  • 通讯作者: 张丛筠 E-mail:z.congyun@nuc.edu.cn;lyq@nuc.edu.cn
  • 基金资助:
    山西省国际科技合作项目（No.2014081006-2）和山西省青年科学基金（No.2015021078）资助
下载PDF ( 973 ) 引用
导出 被引次数 ( 5 | 3 )

Preparation and Surface-Enhanced Raman Scattering Effect of Graphene Oxide/(Au/Ag) Hybrid Materials

Hao Rui1,2, Zhang Congyun1,2*, Lu Ya1,2, Zhang Dongjie1,2, Hao Yaowu3, Liu Yaqing1,2   

  1. 1. Shanxi Province Key Laboratory of Functional Nanocomposites, North University of China, Taiyuan 030051, China;
    2. School of Materials Science and Engineering, North University of China, Taiyuan 030051, China;
    3. Department of Materials Science and Engineering, The University of Texas at Arlington, Arlington 76019, USA
  • Received:2016-03-01 Revised:2016-05-01 Online:2016-08-15 Published:2016-07-12
  • Supported by:
    The work was supported by the International Science and Technology Program of Shanxi Province (No.2014081006-2), and the Natural Science Foundation for Young Scientists of Shanxi Province, China(No.2015021078)
近年来，氧化石墨烯/金银纳米粒子复合材料由于其优异的表面增强拉曼散射（SERS）性能引起了人们极大的关注，在污染物检测、化学传感和癌症诊断等领域具有重要的应用价值。本文综述了氧化石墨烯片层上修饰金银纳米粒子、氧化石墨烯包覆金银纳米粒子、氧化石墨烯附着在金银纳米粒子层三种氧化石墨烯/金银纳米粒子复合材料的制备方法，对其SERS效应进行了详细介绍。SERS研究表明，结合了金银纳米粒子与氧化石墨烯两种材料各自在SERS研究与应用中的优势，氧化石墨烯/金银纳米粒子复合材料的SERS性能比单纯金银纳米粒子更加优异。氧化石墨烯在其中起到了化学增强、分子富集、钝化保护、荧光猝灭的重要作用。氧化石墨烯/金银纳米粒子复合材料在表面增强拉曼光谱中具有广阔的应用前景。
关键词： 金银纳米粒子, 氧化石墨烯, 复合材料, 表面增强拉曼散射
Graphene oxide/(Au/Ag) hybrid materials, which have significant value in pollutant detection, chemical sensing and cancer diagnosis, have received considerable attention for recent years because of their excellent surface-enhanced Raman scattering (SERS) effects. In this review, the synthesis methods and SERS effects of three kind of graphene oxide/(Au/Ag) hybrid materials (graphene oxide decorated with Au/Ag nanoparticles, graphene oxide encapsulated Au/Ag nanoparticles, graphene oxide coated on Au/Ag nanoparticles films) have been summarized in detail. SERS studies show that by combining with the respective advantages of Au/Ag nanoparticles and graphene oxide on the research and application of SERS, graphene oxide/(Au/Ag) hybrid materials have more excellent SERS effect than pure Au/Ag nanoparticles. Graphene oxide plays an important role in chemical enhancement, molecule enrichment, surface passivation and fluorescence quencher. Graphene oxide/(Au/Ag) hybrid materials have broad application prospects in SERS.

Contents
1 Introduction
2 Preparation of graphene oxide/(Au/Ag) hybrid materials
2.1 Graphene oxide decorated with Au/Ag nanoparticles
2.2 Graphene oxide encapsulated Au/Ag nanoparticles
2.3 Graphene oxide coated on Au/Ag nanoparticles films
3 SERS effect of graphene oxide/(Au/Ag) hybrid materials
3.1 SERS effect of different structure of graphene oxide/(Au/Ag) hybrid materials
3.2 The practical SERS application of graphene oxide/(Au/Ag) hybrid materials
4 Conclusion

Key words: Au and Ag nanoparticles, graphene oxide, hybrid materials, surface-enhanced Raman scattering (SERS)

中图分类号: 

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