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化学进展 2019, Vol. 31 Issue (7): 929-938 DOI: 10.7536/PC181205 前一篇   后一篇

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氮配位单茂金属烯烃聚合催化剂

曲树璋, 张韬毅*(), 王伟*()   

  1. 中国石油化工股份有限公司北京化工研究院 北京 100013
  • 收稿日期:2018-12-07 出版日期:2019-07-15 发布日期:2019-04-26
  • 通讯作者: 张韬毅, 王伟

Olefin Polymerization with Nitrogen-Coordinated Half-Metallocene Catalyst Systems

Shuzhang Qu, Taoyi Zhang*(), Wei Wang*()   

  1. Beijing Research Institute of Chemical Industry(BRICI), SINOPec, Beijing 100013, China

本文综述了近些年来以含氮基团为阴离子配体的单茂金属化合物作为烯烃精确聚合的催化剂的研究。氮配位单茂金属催化剂在烯烃聚合中显示出独特的特性,特别是对于乙烯的共聚合,不仅能得到Ziegler-Natta催化剂和传统茂金属催化剂不能合成的新的共聚物,还有优于其他单茂金属催化剂的共聚活性。环戊二烯基和含氮阴离子配体的改性是所得催化剂聚合效果的关键。本文涉及了乙烯均聚以及乙烯与α-烯烃(己烯-1、辛烯-1等)、苯乙烯和环烯烃(降冰片烯、四环十二碳烯等)的共聚合。

The recent study of the half-metallocene compounds ligated with nitrogen-containing groups as catalysts for precise olefin polymerization has been reviewed in this article. Studies have found that these nitrogen-coordinated catalysts exhibit unique properties in the polymerization of olefin monomers, especially for the copolymerization of ethylene. These catalysts can not only obtain new copolymers, which cannot be synthesized by Ziegler-Natta catalysts and traditional metallocene catalysts, but also show the copolymerization activities superior to other half-metallocene catalysts. Modification of both cyclopentadienyl fragments and anionic ancillary donor ligands is the key for the improvement of polymerization behaviors. This article relates to the homopolymerization of ethylene and the copolymerization of ethylene with α-olefins(hexene-1, octene-1, etc.), styrene and cyclic olefins(norbornene, tetracyclododecene, etc).

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图1 胺基配体的单茂金属催化剂
Fig. 1 Half-metallocene with amino ligand
表1 催化剂25~29的乙烯聚合[24][a]
Table 1 Ethylene polymerization by 25~29[24][a]
表2 催化剂25~29的乙烯-己烯-1共聚合[24][a]
Table 2 Ethylene-hexene-1 copolymerization by 25~29[24][a]
表3 催化剂30~39的乙烯聚合[25]
Table 3 Ethylene polymerization of 30~39[25]
图2 亚胺基配体的单茂金属催化剂
Fig. 2 Half-metallocene with ketimide ligand
图3 膦亚胺基配体的单茂金属催化剂
Fig. 3 Half-metallocene with phosphinimide ligand
表4 催化剂97、98的乙烯-辛烯-1共聚合及其与Cp*Ti[NP(tBu)3]Cl2的比较[38][a]
Table 4 Comparison for ethylene-octene-1 copolymerization by 97, 98 and Cp*Ti[NP(tBu)3]C12[38][a]
图4 其他形式的N原子配位的单茂金属催化剂
Fig. 4 Half-metallocene with other types of N-containing ligand
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摘要

氮配位单茂金属烯烃聚合催化剂