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曲树璋, 张韬毅, 王伟. 氮配位单茂金属烯烃聚合催化剂[J]. 化学进展, 2019, 31(7): 929-938.
Shuzhang Qu, Taoyi Zhang, Wei Wang. Olefin Polymerization with Nitrogen-Coordinated Half-Metallocene Catalyst Systems[J]. Progress in Chemistry, 2019, 31(7): 929-938.
本文综述了近些年来以含氮基团为阴离子配体的单茂金属化合物作为烯烃精确聚合的催化剂的研究。氮配位单茂金属催化剂在烯烃聚合中显示出独特的特性,特别是对于乙烯的共聚合,不仅能得到Ziegler-Natta催化剂和传统茂金属催化剂不能合成的新的共聚物,还有优于其他单茂金属催化剂的共聚活性。环戊二烯基和含氮阴离子配体的改性是所得催化剂聚合效果的关键。本文涉及了乙烯均聚以及乙烯与α-烯烃(己烯-1、辛烯-1等)、苯乙烯和环烯烃(降冰片烯、四环十二碳烯等)的共聚合。
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Cat. | T (℃) | Al/Ti mol. ratio | Activity[b] | 10-4 | (℃) |
---|---|---|---|---|---|
25[e] | 20 | 200 | 316 | 371.5 | 137.9 |
25[e] | 35 | 200 | 330 | 105.5 | 136.5 |
26[e] | 20 | 200 | 340 | 383.5 | 137.7 |
26[e] | 35 | 200 | 354 | 138.8 | 136.9 |
27[e] | 20 | 200 | 220 | 325.4 | 136.8 |
27[e] | 35 | 200 | 231 | 103.3 | 136.4 |
28 | 20 | 200 | 1852 | 94.1 | 138.9 |
28 | 35 | 200 | 1974 | 70.6 | 138.1 |
28 | 50 | 200 | 1270 | 55.9 | 139.0 |
28 | 35 | 300 | 1692 | 83.5 | 139.5 |
28 | 35 | 400 | 1594 | 68.3 | 140.1 |
29 | 20 | 200 | 1806 | 96.8 | 139.3 |
29 | 35 | 200 | 1924 | 82.1 | 139.0 |
29 | 35 | 300 | 1856 | 58.4 | 137.9 |
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