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化学进展 2017, Vol. 29 Issue (1): 7-8 DOI: 10.7536/PC170103 前一篇   后一篇

所属专题： 中国化学印记； 金属有机框架材料

• 中国化学印记 •

三明治结构MOFs催化剂:调控加氢反应选择性

刘鸣华*   

  1. 国家纳米科学中心 北京 100190
  • 出版日期:2017-01-05 发布日期:2017-01-10
  • 通讯作者: 刘鸣华 E-mail:liumh@iccas.ac.cn
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Sandwich MOFs as Catalyst: Regulating Selectivity for Hydrogenation

Minghua Liu*   

  1. National Center for Nanoscience and Technology, Beijing 100190, China
  • Online:2017-01-05 Published:2017-01-10
This 2016 Chinese Chemistry Engram highlights the MOF catalyst for selective hydrogenation. The MOF catalyst is fabricated by sandwiching platinum nanoparticles between an inner core and an outer shell of an MOF with metal nodes of Fe3+, Cr3+ or both (known as MIL-101), which can convert a range of α, β-unsaturated aldehydes with high efficiency and with significantly enhanced selectivity towards unsaturated alcohols.
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[1] Yaghi O M, Li G, Li H. Nature, 1995, 378:703.
[2] Zhao M, Yuan K, Wang Y, Li G, Guo J, Gu L, Hu W, Zhao H, Tang Z. Nature, 2016, 539:76.
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